Controlled synthesis of Ni(OH)2/Ni3S2hybrid nanosheet arrays as highly active and stable electrocatalysts for water splitting

2018 ◽  
Vol 6 (16) ◽  
pp. 6938-6946 ◽  
Author(s):  
Xiaoqiang Du ◽  
Zhi Yang ◽  
Yu Li ◽  
Yaqiong Gong ◽  
Min Zhao
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Controlled Synthesis ◽  
Highly Active ◽  
Nanosheet Arrays ◽  
A Current

Using Ni(OH)2/Ni3S2-12h as a bifunctional water splitting catalyst, with an overpotential of ∼340 mV, which is obtained at a very low cell voltage of 1.57 V with a current density of 10 mA cm−2in 1.0 M KOH.

An advanced and highly efficient Ce assisted NiFe-LDH electrocatalyst for overall water splitting

2020 ◽  
Vol 4 (1) ◽  
pp. 312-323 ◽  
Author(s):  
Harsharaj S. Jadhav ◽  
Animesh Roy ◽  
Bezawit Z. Desalegan ◽  
Jeong Gil Seo
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Room Temperature ◽  
Cell Voltage ◽  
Highly Efficient ◽  
Overall Water Splitting ◽  
A Cell ◽  
A Current

A room-temperature synthesized NiFeCe2 electrocatalyst delivered a current density of 10 mA cm−2 at a cell voltage of 1.59 V when used as the electrolyzer.

Construction of a MnCo2O4@NiyMx (S and P) crosslinked network for efficient electrocatalytic water splitting

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7293-7302 ◽  
Author(s):  
Xiaoqiang Du ◽  
Jianpeng Fu ◽  
Xiaoshuang Zhang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
A Current

Using MnCo2O4@Ni3S2 as a bifunctional water splitting catalyst, an overpotential of ∼370 mV is obtained at a very low cell voltage of 1.60 V with a current density of 10 mA cm−2 in 1.0 M KOH.

Controllable synthesis of Cu–Ni–M (M = S, P and Se) hybrid nanoarrays for efficient water splitting reaction

2021 ◽  
Author(s):  
Nannan Chen ◽  
Yanhong Wang ◽  
Xiaoqiang Du ◽  
Xiaoshuang Zhang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Controllable Synthesis ◽  
A Cell ◽  
A Current

The results demonstrate that Cu–Ni–S/NF//Cu–Ni–P/NF pairs show superior water splitting performance with only requiring a cell voltage of 1.50 V to achieve a current density of 20 mA cm−2.

Design and synthesis of integrally structured Ni3N nanosheets/carbon microfibers/Ni3N nanosheets for efficient full water splitting catalysis

2017 ◽  
Vol 5 (19) ◽  
pp. 9377-9390 ◽  
Author(s):  
Tingting Liu ◽  
Mian Li ◽  
Chuanlai Jiao ◽  
Mehboob Hassan ◽  
Xiangjie Bo ◽  
...  
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Electrolysis Cell ◽  
Design And Synthesis ◽  
A Cell ◽  
Carbon Microfibers ◽  
A Current

A (−) Ni3N/CMFs/Ni3N‖Ni3N/CMFs/Ni3N (+) electrolysis cell requires a cell voltage of only 1.65 V to achieve a current density of 20 mA cm−2.

Controllable synthesis of NiO/Ni3S2 hybrid arrays as efficient electrocatalysts for water splitting

2018 ◽  
Vol 42 (22) ◽  
pp. 18201-18207 ◽  
Author(s):  
Xiaoqiang Du ◽  
Qibin Wang ◽  
Xiaoshuang Zhang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Controllable Synthesis ◽  
A Cell ◽  
A Current

NiO/Ni3S2 affords a current density of 10 mA cm−2 in 1.0 M KOH at a cell voltage of 1.59 V, i.e., comparable to the commercial 20 wt% IrO2/C–40 wt% Pt/C couple (1.55 V at 10 mA cm−2).

Cu–Co–M arrays on Ni foam as monolithic structured catalysts for water splitting: effects of co-doped S-P

2019 ◽  
Vol 48 (4) ◽  
pp. 1322-1331 ◽  
Author(s):  
Xiaoqiang Du ◽  
Qizhao Shao ◽  
Xiaoshuang Zhang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Ni Foam ◽  
Structured Catalysts ◽  
A Current ◽  
Co Doped

Using Cu–Co–P-S as a bifunctional water-splitting catalyst, overpotential of ∼320 mV is obtained at a very low cell voltage of 1.55 V with a current density of 20 mA cm−2 in 1.0 M KOH.

Photothermal coupling electrolysis on Ni–W–B toward practical overall water splitting

2019 ◽  
Vol 7 (20) ◽  
pp. 12440-12445 ◽  
Author(s):  
Weiju Hao ◽  
Renbing Wu ◽  
Hongyuan Yang ◽  
Yanhui Guo
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
Photothermal Effect ◽  
Carbon Cloth ◽  
Cell Temperature ◽  
Overall Water Splitting ◽  
A Current

An overall water splitting device assembled using a photothermal effect coupled Ni–W–B/carbon cloth electrode could deliver a current density of 25 mA cm−2 at an ultralow cell voltage of 1.524 V without heating the whole system, which is comparable to its performance at an elevated cell temperature of 50 °C.

Oxide/sulfide-based hybrid arrays as robust electrocatalysts for water splitting

2018 ◽  
Vol 47 (30) ◽  
pp. 10273-10280 ◽  
Author(s):  
Xiaoqiang Du ◽  
Qibin Wang ◽  
Yu Li ◽  
Xiaoshuang Zhang
Keyword(s):  
Water Splitting ◽  
Current Density ◽  
Cell Voltage ◽  
A Cell ◽  
A Current

NiCo2O4/Ni3S2 affords a current density of 10 mA cm−2 in 1.0 M KOH at a cell voltage of 1.58 V, i.e., comparable to that of the commercial 20 wt% IrO2/C–40 wt% Pt/C couple (1.52 V at 10 mA cm−2).

3D hierarchical Co3O4@Co3S4 nanoarrays as anode and cathode materials for oxygen evolution reaction and hydrogen evolution reaction

2018 ◽  
Vol 47 (45) ◽  
pp. 16305-16312 ◽  
Author(s):  
Xiaoqiang Du ◽  
Hui Su ◽  
Xiaoshuang Zhang
Keyword(s):  
Hydrogen Evolution ◽  
Water Splitting ◽  
Oxygen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Current Density ◽  
Cathode Materials ◽  
Oxygen Evolution Reaction ◽  
Cell Voltage ◽  
A Current

Using Co3O4@Co3S4-24 h as a bifunctional water splitting catalyst, an overpotential of ∼300 mV is obtained at a very low cell voltage of 1.53 V with a current density of 10 mA cm−2 in 1.0 M KOH.

scholarly journals Electrodeposition of Pt-Decorated Ni(OH)2/CeO2 Hybrid as Superior Bifunctional Electrocatalyst for Water Splitting

Research ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Huanhuan Liu ◽  
Zhenhua Yan ◽  
Xiang Chen ◽  
Jinhan Li ◽  
Le Zhang ◽  
...  
Keyword(s):  
Water Splitting ◽  
Cell Voltage ◽  
Water Electrolysis ◽  
Active Species ◽  
Water Dissociation ◽  
Electronic Interaction ◽  
Bifunctional Electrocatalyst ◽  
Highly Active ◽  
A Cell ◽  
Promising Application

The facile synthesis of highly active and stable bifunctional electrocatalysts to catalyze water splitting is attractive but challenging. Herein, we report the electrodeposition of Pt-decorated Ni(OH)2/CeO2 (PNC) hybrid as an efficient and robust bifunctional electrocatalyst. The graphite-supported PNC catalyst delivers superior hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) activities over the benchmark Pt/C and RuO2, respectively. For overall water electrolysis, the PNC hybrid only requires a cell voltage of 1.45 V at 10 mA cm−2 and sustains over 85 h at 1000 mA cm−2. The remarkable HER/OER performances are attributed to the superhydrophilicity and multiple effects of PNC, in which Ni(OH)2 and CeO2 accelerate HER on Pt due to promoted water dissociation and strong electronic interaction, while the electron-pulling Ce cations facilitate the generation of high-valence Ni OER-active species. These results suggest the promising application of PNC for H2 production from water electrolysis.

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