1D N-doped hierarchically porous hollow carbon tubes derived from a supramolecular template as metal-free electrocatalysts for a highly efficient oxygen reduction reaction

2018 ◽  
Vol 6 (15) ◽  
pp. 6212-6219 ◽  
Author(s):  
Lei Zhao ◽  
Xu-Lei Sui ◽  
Qing-Yan Zhou ◽  
Jia-Zhan Li ◽  
Jing-Jia Zhang ◽  
...  

1D hollow nitrogen-doped carbon tubes (h-NCTs) were fabricated through a supramolecular template-derived approach and employed as the structure-guiding template, porogen and nitrogen source for in situ N-doping.

RSC Advances ◽  
2018 ◽  
Vol 8 (44) ◽  
pp. 25051-25056 ◽  
Author(s):  
Yanhong Yin ◽  
Hengbo Zhang ◽  
Rongzhen Gao ◽  
Aili Wang ◽  
Xinxin Mao ◽  
...  

In this work, a Co–N doped carbon nanotube (CNT) catalyst was fabricated via a simple pyrolysis approach.


RSC Advances ◽  
2021 ◽  
Vol 11 (47) ◽  
pp. 29555-29563
Author(s):  
Songlin Zhao ◽  
Fushan Chen ◽  
Qunfeng Zhang ◽  
Lingtao Meng

Nitrogen-doped porous carbon materials have high potential in metal-free electrocatalysts, which is essential for several renewable energy conversion systems.


Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 864 ◽  
Author(s):  
Zhenhua Yao ◽  
Ruiyang Fan ◽  
Wangyang Ji ◽  
Tingxuan Yan ◽  
Maocong Hu

In this work, non-traditional metal-free polynitrogen chain N8− deposited on a nitrogen-doped carbon nanotubes (PN-NCNT) catalyst was successfully synthesized by a facile cyclic voltammetry (CV) approach, which was further tested in an oxygen reduction reaction (ORR). The formation of PN on NCNT was confirmed by attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) and Raman spectroscopy. Partial positive charge of carbon within NCNT facilitated electron transfer and accordingly induced the formation of more PN species compared to CNT substrate as determined by temperature-programmed decomposition (TPD). Rotating disk electrode (RDE) measurements suggested that a higher current density was achieved over PN-NCNT than that on PN-CNT catalyst, which can be attributed to formation of the larger amount of N8− on NCNT. Kinetic study suggested a four-electron pathway mechanism over PN-NCNT. Moreover, it showed long stability and good methanol tolerance, which indicates its great potential application. This work provides insights on designing and synthesizing non-traditional metal-free catalysts for ORR in fuel cells.


2014 ◽  
Vol 7 (1) ◽  
pp. 442-450 ◽  
Author(s):  
Peng Zhang ◽  
Fang Sun ◽  
Zhonghua Xiang ◽  
Zhigang Shen ◽  
Jimmy Yun ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document