Nitrogen-doped hollow carbon hemispheres as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline medium

2014 ◽  
Vol 2 (3) ◽  
pp. 605-609 ◽  
Author(s):  
Chuanlong Han ◽  
Jing Wang ◽  
Yutong Gong ◽  
Xuan Xu ◽  
Haoran Li ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Alkaline Medium ◽  
Reduction Reaction ◽  
Nitrogen Doped ◽  
Metal Free ◽  
Hollow Carbon

scholarly journals N8− Polynitrogen Stabilized on Nitrogen-Doped Carbon Nanotubes as an Efficient Electrocatalyst for Oxygen Reduction Reaction

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 864 ◽  
Author(s):  
Zhenhua Yao ◽  
Ruiyang Fan ◽  
Wangyang Ji ◽  
Tingxuan Yan ◽  
Maocong Hu
Keyword(s):  
Carbon Nanotubes ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Rotating Disk ◽  
Reduction Reaction ◽  
Rotating Disk Electrode ◽  
Nitrogen Doped ◽  
Metal Free ◽  
Temperature Programmed ◽  
Nitrogen Doped Carbon

In this work, non-traditional metal-free polynitrogen chain N8− deposited on a nitrogen-doped carbon nanotubes (PN-NCNT) catalyst was successfully synthesized by a facile cyclic voltammetry (CV) approach, which was further tested in an oxygen reduction reaction (ORR). The formation of PN on NCNT was confirmed by attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) and Raman spectroscopy. Partial positive charge of carbon within NCNT facilitated electron transfer and accordingly induced the formation of more PN species compared to CNT substrate as determined by temperature-programmed decomposition (TPD). Rotating disk electrode (RDE) measurements suggested that a higher current density was achieved over PN-NCNT than that on PN-CNT catalyst, which can be attributed to formation of the larger amount of N8− on NCNT. Kinetic study suggested a four-electron pathway mechanism over PN-NCNT. Moreover, it showed long stability and good methanol tolerance, which indicates its great potential application. This work provides insights on designing and synthesizing non-traditional metal-free catalysts for ORR in fuel cells.

Nitrogen doped amorphous carbon as metal free electrocatalyst for oxygen reduction reaction

2017 ◽  
Vol 42 (2) ◽  
pp. 876-885 ◽  
Author(s):  
Linmin Cao ◽  
Zhipeng Lin ◽  
Jilin Huang ◽  
Xiang Yu ◽  
Xiaoxian Wu ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Amorphous Carbon ◽  
Reduction Reaction ◽  
Nitrogen Doped ◽  
Metal Free

scholarly journals Shale-oil-based nitrogen-doped porous carbon as efficient metal-free electrocatalyst for oxygen reduction reaction

2020 ◽  
Vol 146 ◽  
pp. 106131
Author(s):  
Xiaobo Chen ◽  
Zhiqiang Li ◽  
Rumeng Qin ◽  
Shengjie Shan ◽  
Yibin Liu ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Porous Carbon ◽  
Reduction Reaction ◽  
Shale Oil ◽  
Nitrogen Doped ◽  
Metal Free

scholarly journals Noble-Metal-Free Iron Nitride/Nitrogen-Doped Graphene Composite for the Oxygen Reduction Reaction

ACS Omega ◽  
2019 ◽  
Vol 4 (1) ◽  
pp. 130-139 ◽  
Author(s):  
Tamás Varga ◽  
Lívia Vásárhelyi ◽  
Gergő Ballai ◽  
Henrik Haspel ◽  
Albert Oszkó ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Noble Metal ◽  
Reduction Reaction ◽  
Iron Nitride ◽  
Nitrogen Doped ◽  
Metal Free ◽  
Graphene Composite ◽  
Nitrogen Doped Graphene ◽  
Doped Graphene

Forming a B B bond in boron carbon nitride composite: A way for metal free electrocatalyst for oxygen reduction reaction in alkaline medium

2019 ◽  
Vol 378 ◽  
pp. 104-112 ◽  
Author(s):  
Phiralang Marbaniang ◽  
Sagar Ingavale ◽  
Divya Catherin ◽  
Niranjan Ramgir ◽  
Anita Swami ◽  
...  
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Alkaline Medium ◽  
Carbon Nitride ◽  
Reduction Reaction ◽  
Metal Free ◽  
Boron Carbon Nitride ◽  
Boron Carbon

N-Doped holey carbon materials derived from a metal-free macrocycle cucurbit[6]uril assembly as an efficient electrocatalyst for the oxygen reduction reaction

2019 ◽  
Vol 55 (92) ◽  
pp. 13832-13835 ◽  
Author(s):  
Dongshuang Wu ◽  
Minna Cao ◽  
Hanhui You ◽  
Chuan Zhao ◽  
Rong Cao
Keyword(s):  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Self Assembly ◽  
Carbon Materials ◽  
Reduction Reaction ◽  
Nitrogen Doped ◽  
Metal Free

The first example of the preparation of nitrogen-doped holey carbon (NHC) with abundant in-plane holes derived from a rigid macrocycle cucurbit[6]uril self-assembly is reported.

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