Photoredox catalysis over graphene aerogel-supported composites

2018 ◽  
Vol 6 (11) ◽  
pp. 4590-4604 ◽  
Author(s):  
Kang-Qiang Lu ◽  
Xin Xin ◽  
Nan Zhang ◽  
Zi-Rong Tang ◽  
Yi-Jun Xu

Three-dimensional (3D) graphene aerogels, by virtue of their unique physicochemical properties, which result from the intrinsic properties of graphene and 3D porous structure characteristics, have attracted ever-increasing research interest in the field of photocatalysis for the sake of efficient utilization of solar energy.

RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43116-43126 ◽  
Author(s):  
Yisi Liu ◽  
Wenzhang Li ◽  
Jie Li ◽  
Haibo Shen ◽  
Yaomin Li ◽  
...  

In this work, we demonstrate a facile strategy to synthesize a novel three-dimensional (3D) graphene aerogel-supported and graphene quantum dots-modified γ-MnOOH nanotubes as a highly efficient electrocatalyst.


2021 ◽  
pp. 2140016
Author(s):  
Lei Zhang ◽  
Jianhua Chen ◽  
Dongxiao Fu ◽  
Feipeng Lu ◽  
Yanlan Wang ◽  
...  

Copper azide (CA), a high energy primary explosive, had been investigated with various supporter materials to reduce its sensitivity characteristics. However, effective supporter had not been designed to fully reduce CAs sensitivity characteristics. Hence, we presented a three-dimensional (3D) graphene aerogel-supported CA (CA-GAs) strategy to meet those needs. CA-GAs was prepared using 3D GA as the framework to uniformly grip CA. The SEM and XRD measurements revealed that CA nanoparticles were fully dispersed on GAs, the in-situ azidation reaction of Cu precursor and CAs crystalline structure were not affected by GAs. DSC further verified the thermal stability of CA-GAs. Moreover, electrostatic ignition experiment was employed to investigate CA-GAs’ ignition time, input energy, and electrical ignition performance. Those results showed that CA-GAs could be reliably detonated by a 3.5 [Formula: see text] SCB, the average electric ignition voltage, ignition time, and input energy of CA-GAs were 19.125 V, 21 [Formula: see text]s, and 0.56 mJ, respectively. All these results illustrated that GAs was an effective supporter for the stabilization of CA.


RSC Advances ◽  
2018 ◽  
Vol 8 (19) ◽  
pp. 10277-10283 ◽  
Author(s):  
P. Sun ◽  
Y. L. Gao ◽  
C. Xu ◽  
Y. F. Lian

3D graphene aerogel fabricated via chemical reduction followed by freeze-drying treatment was used as SPE sorbent to extract OPPs from water sample.


RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 69973-69976 ◽  
Author(s):  
Xuan Zhang ◽  
Nan Hao ◽  
Xiaoya Dong ◽  
Saibo Chen ◽  
Zhou Zhou ◽  
...  

Pt nanoparticle-decorated nitrogen-doped 3D graphene aerogel (PtNPs/3DNGA) composites were prepared through a one-pot hydrothermal approach and show superior catalytic activity in methanol oxidation.


2019 ◽  
Vol 6 (10) ◽  
pp. 2698-2706 ◽  
Author(s):  
Liang‐ai Huang ◽  
Zhishun He ◽  
Jianfeng Guo ◽  
Shi‐en Pei ◽  
Haibo Shao ◽  
...  

2015 ◽  
Vol 3 (26) ◽  
pp. 13691-13698 ◽  
Author(s):  
Bo Wang ◽  
Songmei Li ◽  
Xiaoyu Wu ◽  
Wenming Tian ◽  
Jianhua Liu ◽  
...  

Interconnected ultrathin mesoporous NiMoO4 nanosheets with a network-like porous structure supported on a 3D graphene network for highly reversible lithium storage.


RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 94723-94730 ◽  
Author(s):  
Wei Ha ◽  
Jing Yu ◽  
Juan Chen ◽  
Yan-ping Shi

A three-dimensional self-assembly strategy for constructing graphene oxide hybrid supramolecular hydrogel with regular porous structure was developed.


2021 ◽  
Vol 22 (7) ◽  
pp. 3391
Author(s):  
Sylwia Grabska-Zielińska ◽  
Alina Sionkowska ◽  
Ewa Olewnik-Kruszkowska ◽  
Katarzyna Reczyńska ◽  
Elżbieta Pamuła

The aim of this work was to compare physicochemical properties of three dimensional scaffolds based on silk fibroin, collagen and chitosan blends, cross-linked with dialdehyde starch (DAS) and dialdehyde chitosan (DAC). DAS was commercially available, while DAC was obtained by one-step synthesis. Structure and physicochemical properties of the materials were characterized using Fourier transfer infrared spectroscopy with attenuated total reflectance device (FTIR-ATR), swelling behavior and water content measurements, porosity and density observations, scanning electron microscopy imaging (SEM), mechanical properties evaluation and thermogravimetric analysis. Metabolic activity with AlamarBlue assay and live/dead fluorescence staining were performed to evaluate the cytocompatibility of the obtained materials with MG-63 osteoblast-like cells. The results showed that the properties of the scaffolds based on silk fibroin, collagen and chitosan can be modified by chemical cross-linking with DAS and DAC. It was found that DAS and DAC have different influence on the properties of biopolymeric scaffolds. Materials cross-linked with DAS were characterized by higher swelling ability (~4000% for DAS cross-linked materials; ~2500% for DAC cross-linked materials), they had lower density (Coll/CTS/30SF scaffold cross-linked with DAS: 21.8 ± 2.4 g/cm3; cross-linked with DAC: 14.6 ± 0.7 g/cm3) and lower mechanical properties (maximum deformation for DAC cross-linked scaffolds was about 69%; for DAS cross-linked scaffolds it was in the range of 12.67 ± 1.51% and 19.83 ± 1.30%) in comparison to materials cross-linked with DAC. Additionally, scaffolds cross-linked with DAS exhibited higher biocompatibility than those cross-linked with DAC. However, the obtained results showed that both types of scaffolds can provide the support required in regenerative medicine and tissue engineering. The scaffolds presented in the present work can be potentially used in bone tissue engineering to facilitate healing of small bone defects.


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