3D graphene oxide supramolecular hybrid hydrogel with well-ordered interior microstructure prepared by a host–guest inclusion-induced self-assembly strategy

RSC Advances ◽  
2016 ◽  
Vol 6 (97) ◽  
pp. 94723-94730 ◽  
Author(s):  
Wei Ha ◽  
Jing Yu ◽  
Juan Chen ◽  
Yan-ping Shi

A three-dimensional self-assembly strategy for constructing graphene oxide hybrid supramolecular hydrogel with regular porous structure was developed.

Nanoscale ◽  
2019 ◽  
Vol 11 (28) ◽  
pp. 13318-13329 ◽  
Author(s):  
Paolo Passaretti ◽  
Yiwei Sun ◽  
Inam Khan ◽  
Kieran Chan ◽  
Rania Sabo ◽  
...  

An alternative self-assembly strategy based on low-interactions for the fabrication of graphene-based sponges, using M13 bacteriophage as a cross-linking agent.


2021 ◽  
Vol 9 (14) ◽  
pp. 3200-3209
Author(s):  
Wei Ha ◽  
Xiao-Bo Zhao ◽  
Wei-Hua Zhao ◽  
Jiang-Jiang Tang ◽  
Yan-Ping Shi

An ingeniously designed podophyllotoxin nanoprodrug was synthesized and offered an effective platform for co-delivery of multiple therapeutic agents for drug combination via the hierarchical self-assembly strategy.


Micromachines ◽  
2019 ◽  
Vol 11 (1) ◽  
pp. 13 ◽  
Author(s):  
Bin Zhang ◽  
Jaehyun Lee ◽  
Mincheol Kim ◽  
Naeeung Lee ◽  
Hyungdong Lee ◽  
...  

The macroscopic assembly of two-dimensional materials into a laminar structure has received considerable attention because it improves both the mechanical and chemical properties of the original materials. However, conventional manufacturing methods have certain limitations in that they require a high temperature process, use toxic solvents, and are considerably time consuming. Here, we present a new system for the self-assembly of layer-by-layer (LBL) graphene oxide (GO) via an electrohydrodynamic (EHD) jet printing technique. During printing, the orientation of GO flakes can be controlled by the velocity distribution of liquid jet and electric field-induced alignment spontaneously. Closely-packed GO patterns with an ordered laminar structure can be rapidly realized using an interfacial assembly process on the substrates. The surface roughness and electrical conductivity of the LBL structure were significantly improved compared with conventional dispensing methods. We further applied this technique to fabricate a reduced graphene oxide (r-GO)-based supercapacitor and a three-dimensional (3D) metallic grid hybrid ammonia sensor. We present the EHD-assisted assembly of laminar r-GO structures as a new platform for preparing high-performance energy storage devices and sensors.


2015 ◽  
Vol 3 (4) ◽  
pp. 1540-1548 ◽  
Author(s):  
Sheng Zhu ◽  
Hui Zhang ◽  
Ping Chen ◽  
Lin-Hui Nie ◽  
Chuan-Hao Li ◽  
...  

A facile protocol for the self-assembly of the rGO/β-MnO2 hybrid hydrogel with ultrafine structure and precise control of mass-loading for high performance supercapacitors is reported.


2019 ◽  
Vol 19 (11) ◽  
pp. 7404-7409 ◽  
Author(s):  
Aihua Jing ◽  
Gaofeng Liang ◽  
Hao Shi ◽  
Yixin Yuan ◽  
Quanxing Zhan ◽  
...  

Three-dimensional (3D) graphene with high specific surface area, excellent conductivity and designed porosity is essential for many practical applications. Herein, holey graphene oxide with nano pores was facilely prepared via a convenient mild defect-etching reaction and then fabricated to 3D nanostructures via a reduction method. Based on the 3D architectures, a novel enzymatic hydrogen peroxide sensor was successfully fabricated. Transmission electron microscopy (TEM), scanning electron microscopy (SEM), fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) were used to characterize the 3D holey graphene oxide architectures (3DHGO). Cyclic voltammetry (CV) was used to evaluate the electrochemical performance of 3DHGO at glassy carbon electrode (GCE). Excellent electrocatalytic activity to the reduction of H2O2 was observed, and a linear range of 5.0×10-8~5.0×10-5 M with a detection limit of 3.8×10-9 M was obtained. These results indicated that 3DHGO have potential as electrochemical biosensors.


2019 ◽  
Vol 6 (9) ◽  
pp. 2528-2538
Author(s):  
Mengxia Li ◽  
Ying Dai ◽  
Xinmei Pei ◽  
Wen Chen

A three-dimensional HrGO with a hierarchically porous structure was successfully synthesized as a sulfur-hosting material with high sulfur loading for high-performance lithium–sulfur batteries.


Nanoscale ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 7347-7357 ◽  
Author(s):  
Lei Wang ◽  
Zhennan Huang ◽  
Bo Wang ◽  
Hao Luo ◽  
Meng Cheng ◽  
...  

Titanium-based metal–organic frameworks have been used as an in situ etching template for the self-assembly of graphene oxide to construct NaTi2(PO4)3-rGO composite.


NANO ◽  
2020 ◽  
Vol 15 (05) ◽  
pp. 2050059
Author(s):  
Yan Liu ◽  
Xiaojun Zhang ◽  
Meiyan Yang ◽  
Bowen Guo ◽  
Jixiang Guo ◽  
...  

Sulfur oxides are air pollutants derived mainly from the combustion of gasoline. Reducing the sulfur content of fluid catalytic cracking (FCC) gasoline is of key importance for the prevention and control of atmospheric pollution. We describe herein the fabrication and characterization of a porous, three-dimensional (3D) graphene oxide-supported zinc oxide (GO/ZnO) scaffold as an adsorbent for desulfurization with various model compounds and real FCC gasoline. The uniform and stable dispersion of ZnO nanoparticles on the surface of GO facilitates the specific binding of sulfides. Moreover, GO synergistically adsorbs aryl sulfides via [Formula: see text]–[Formula: see text] stacking interactions. The GO/ZnO nanosheets were further self-assembled into a 3D porous scaffold that effectively trapped sulfides and inhibited desorption. These scaffolds exhibited excellent desulfurization performance with maximum sulfur capacity up to 29.73[Formula: see text]mg S/g. This work provides a novel perspective on the fabrication of high-efficiency adsorbents for gasoline pretreatment.


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