Efficient formation of oil-in-oil Pickering emulsions with narrow size distributions by using electric fields

Soft Matter ◽  
2018 ◽  
Vol 14 (24) ◽  
pp. 5140-5149 ◽  
Author(s):  
Z. Rozynek ◽  
R. Bielas ◽  
A. Józefczak

We propose a new bulk approach to fabricating Pickering emulsions. We used electric fields not only to facilitate coalescence but also to manipulate surface particles and to induce droplet rotation, each contributed to formation of stable particle-covered droplets.

Soft Matter ◽  
2019 ◽  
Vol 15 (7) ◽  
pp. 1692-1692
Author(s):  
Z. Rozynek ◽  
R. Bielas ◽  
A. Józefczak

Correction for ‘Efficient formation of oil-in-oil Pickering emulsions with narrow size distributions by using electric fields’ by Z. Rozynek et al., Soft Matter, 2018, 14, 5140–5149.


2020 ◽  
Vol 20 (5) ◽  
pp. 3181-3190 ◽  
Author(s):  
Joseph R. Toth III ◽  
Siddharth Rajupet ◽  
Henry Squire ◽  
Blaire Volbers ◽  
Jùn Zhou ◽  
...  

Abstract. Large amounts of dust are lofted into the atmosphere from arid regions of the world before being transported up to thousands of kilometers. This atmospheric dust interacts with solar radiation and causes changes in the climate, with larger-sized particles having a heating effect, and smaller-sized particles having a cooling effect. Previous studies on the long-range transport of dust have found larger particles than expected, without a model to explain their transport. Here, we investigate the effect of electric fields on lofted airborne dust by blowing sand through a vertically oriented electric field, and characterizing the size distribution as a function of height. We also model this system, considering the gravitational, drag, and electrostatic forces on particles, to understand the effects of the electric field. Our results indicate that electric fields keep particles suspended at higher elevations and enrich the concentration of larger particles at higher elevations. We extend our model from the small-scale system to long-range atmospheric dust transport to develop insights into the effects of electric fields on size distributions of lofted dust in the atmosphere. We show that the presence of electric fields and the resulting electrostatic force on charged particles can help explain the transport of unexpectedly large particles and cause the size distribution to become more uniform as a function of elevation. Thus, our experimental and modeling results indicate that electrostatic forces may in some cases be relevant regarding the effect of atmospheric dust on the climate.


2019 ◽  
Author(s):  
Joseph R. Toth III ◽  
Siddharth Rajupet ◽  
Henry Squire ◽  
Blaire Volbers ◽  
Jùn Zhou ◽  
...  

Abstract. Large amounts of dust are lofted into the atmosphere from arid regions of the world before being transported up to thousands of kilometers. This atmospheric dust interacts with solar radiation causing changes in the climate, with larger-sized particles having a heating effect, and smaller-sized particles having a cooling effect. Previous studies on the long-range transport of dust have found larger particles than expected, without a model to explain their transport. Here, we investigate the effect of electric fields on lofted airborne dust by blowing sand through a vertically-oriented electric field, and characterizing the size distribution as a function of height. We also model this system, considering the gravitational, drag, and electrostatic forces on particles, to understand the effects of the electric field. Our results indicate that electric fields keep particles suspended at higher elevations and enrich the concentration of larger particles at higher elevations. We extend our model from the small-scale system to long-range atmospheric dust transport to develop insights on the effects of electric fields on size distributions of lofted dust in the atmosphere. We show that the presence of electric fields and the resulting electrostatic force on particles can help explain the transport of unexpectedly larger particles and cause the size distribution to become more uniform as a function of elevation. Thus, our experimental and modelling results indicate that electrostatic forces should be considered when determining the effect of atmospheric dust on the climate.


2010 ◽  
Vol 31 (5) ◽  
pp. 850-859 ◽  
Author(s):  
Kyuho Hwang ◽  
Pushpendra Singh ◽  
Nadine Aubry

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4783
Author(s):  
Rafał Bielas ◽  
Arkadiusz Józefczak

Pickering emulsions (particle-stabilized emulsions) are usually considered because of their unique properties compared to surfactant-stabilized emulsions including better stability against emulsion aging. However, the interesting feature of particle-stabilized emulsions could be revealed during their magnetic heating. When magnetic particles constitute a shell around droplets and the sample is placed in an alternating magnetic field, a temperature increase appears due to energy dissipation from magnetic relaxation and hysteresis within magnetic particles. We hypothesize that the solidity of the magnetic particle shell around droplets can influence the process of heat transfer from inside the droplet to the surrounding medium. In this way, particle-stabilized emulsions can be considered as materials with changeable heat transfer. We investigated macroscopically heating and cooling of oil-in-oil magnetic Pickering emulsions with merely packed particle layers and these with a stable particle shell. The change in stability of the shell was obtained here by using the coalescence of droplets under the electric field. The results from calorimetric measurements show that the presence of a stable particle shell caused a slower temperature decrease in samples, especially for lower intensities of the magnetic field. The retarded heat transfer from magnetic Pickering droplets can be utilized in further potential applications where delayed heat transfer is desirable.


2016 ◽  
Vol 88 (11) ◽  
pp. 1815-1826 ◽  
Author(s):  
Lena Hohl ◽  
Susanne Röhl ◽  
Dmitrij Stehl ◽  
Regine von Klitzing ◽  
Matthias Kraume

Author(s):  
R. R. Dils ◽  
P. S. Follansbee

Electric fields have been applied across oxides growing on a high temperature alloy and control of the oxidation of the material has been demonstrated. At present, three-fold increases in the oxidation rate have been measured in accelerating fields and the oxidation process has been completely stopped in a retarding field.The experiments have been conducted with an iron-base alloy, Pe 25Cr 5A1 0.1Y, although, in principle, any alloy capable of forming an adherent aluminum oxide layer during oxidation can be used. A specimen is polished and oxidized to produce a thin, uniform insulating layer on one surface. Three platinum electrodes are sputtered on the oxide surface and the specimen is reoxidized.


Author(s):  
Teruo Someya ◽  
Jinzo Kobayashi

Recent progress in the electron-mirror microscopy (EMM), e.g., an improvement of its resolving power together with an increase of the magnification makes it useful for investigating the ferroelectric domain physics. English has recently observed the domain texture in the surface layer of BaTiO3. The present authors ) have developed a theory by which one can evaluate small one-dimensional electric fields and/or topographic step heights in the crystal surfaces from their EMM pictures. This theory was applied to a quantitative study of the surface pattern of BaTiO3).


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