scholarly journals Trimerisation of carbon suboxide at a di-titanium centre to form a pyrone ring system

2018 ◽  
Vol 9 (22) ◽  
pp. 5008-5014 ◽  
Author(s):  
Nikolaos Tsoureas ◽  
Jennifer C. Green ◽  
F. Geoffrey N. Cloke ◽  
Horst Puschmann ◽  
S. Mark Roe ◽  
...  

Bis(pentalene)dititanium Ti2(μ:η5,η5-Pn†)2 trimerises carbon suboxide (OCCCO) to form [{Ti2(μ:η5,η5-Pn†)2}{μ-C9O6}], which contains a 4-pyrone core, via the monoadduct [Ti2(μ:η5,η5-Pn†)2 (η2-C3O2)].

2017 ◽  
Vol 53 (54) ◽  
pp. 7447-7450 ◽  
Author(s):  
Hidetoshi Noda ◽  
Yasuko Asada ◽  
Masakatsu Shibasaki ◽  
Naoya Kumagai

Dehydrative coupling of sulfoximines and carboxylic acids is rendered catalytic by a heterocyclic catalyst featuring the B3NO2 ring system.


2017 ◽  
Vol 15 (48) ◽  
pp. 10172-10183 ◽  
Author(s):  
Carl Jacky Saint-Louis ◽  
Renée N. Shavnore ◽  
Caleb D. C. McClinton ◽  
Julie A. Wilson ◽  
Lacey L. Magill ◽  
...  

Methods to tune the luminescence wavelength and the quantum yields by controlling the power and location of electron-donor and acceptor substituents on the ring system.


2016 ◽  
Vol 14 (21) ◽  
pp. 4875-4884 ◽  
Author(s):  
Eduardo Hernández-Vázquez ◽  
Luis D. Miranda

A multicomponent three-step synthesis of pyrazino[1-2b]isoquinolines is described. A preliminary cytotoxic screening against cancer cell lines was performed.


2018 ◽  
Vol 54 (32) ◽  
pp. 4009-4012 ◽  
Author(s):  
Xiaoxi Zhou ◽  
Fanping Huang ◽  
Chun Tang ◽  
Qingde Zhuo ◽  
Zhixin Chen ◽  
...  

The first successful chemical synthesis and characterization of a bicyclic pyrido[1,2-α]azepine ring system.


2015 ◽  
Vol 13 (38) ◽  
pp. 9834-9843 ◽  
Author(s):  
Anushree Kamath ◽  
Charles-Henry Fabritius ◽  
Christian Philouze ◽  
Philippe Delair
Keyword(s):  

A new approach to the 8b-azaacenaphthylene ring system is described featuring several stereoselective transformations.


2019 ◽  
Vol 6 (5) ◽  
pp. 591-596 ◽  
Author(s):  
Hongxin Liu ◽  
Haibo Tan ◽  
Wenxuan Wang ◽  
Wenge Zhang ◽  
Yuchan Chen ◽  
...  

(±)-Cytorhizophin A and cytorhizophin B (2), novel benzophenone-hemiterpene conjugated hetero-dimers featuring an unprecedented 6/7/6/7 tetracyclic fused ring system.


RSC Advances ◽  
2015 ◽  
Vol 5 (38) ◽  
pp. 30046-30052 ◽  
Author(s):  
Chao Wang ◽  
Chuang-Jun Li ◽  
Jie Ma ◽  
Jing-Zhi Yang ◽  
Xiao-Guang Chen ◽  
...  

Tripterlides A–F are new abietane derivatives, obtained from Tripterygium wilfordii. 1–4 are novel 14(13 → 12),18(4 → 3)-diabeo-abietanoids possessing a 6/6/5 tricyclic ring system.


2018 ◽  
Vol 16 (4) ◽  
pp. 652-656 ◽  
Author(s):  
Pratik Kumar ◽  
Omar Zainul ◽  
Scott T. Laughlin

Cyclic enamines are important synthons for many synthetic and pharmacological targets. We report a method for the synthesis of cyclic enamines with exocyclic double bonds and four- to seven-membered rings that permits usage of common N-protecting groups and tolerates functionality round the ring system.


2018 ◽  
Vol 35 (6) ◽  
pp. 532-558 ◽  
Author(s):  
Kimberly R. Klas ◽  
Hikaru Kato ◽  
Jens C. Frisvad ◽  
Fengan Yu ◽  
Sean A. Newmister ◽  
...  

Various fungi of the generaAspergillus,Penicillium, andMalbrancheaproduce prenylated indole alkaloids possessing a bicyclo[2.2.2]diazaoctane ring system.


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