scholarly journals Anomalous effect of the aging degree on the ionic permeability of silica shells

RSC Advances ◽  
2018 ◽  
Vol 8 (67) ◽  
pp. 38499-38505 ◽  
Author(s):  
Shenghua Wang ◽  
Chaoran Li ◽  
Zhijie Chen ◽  
Zhijie Zhu ◽  
Qishan Zhu ◽  
...  

We discovered an anomalous effect of the aging degree on the ionic permeability of colloidal silica.

2000 ◽  
Vol 628 ◽  
Author(s):  
Guang-Way Jang ◽  
Ren-Jye Wu ◽  
Yuung-Ching Sheen ◽  
Ya-Hui Lin ◽  
Chi-Jung Chang

This work successfully prepared an UV curable organic-inorganic hybrid material consisting of organic modified colloidal silica. Applications of UV curable organic-inorganic hybrid materials include abrasion resistant coatings, photo-patternable thin films and waveguides. Colloidal silica containing reactive functional groups were also prepared by reacting organic silane and tetraethyl orthosilicate (TEOS) using sol-gel process. In addition, the efficiency of grafting organic moiety onto silica nanoparticles was investigated by applying TGA and FTIR techniques. Experimental results indicated a strong interdependence between surface modification efficiency and solution pH. Acrylate-SiO2 hybrid formation could result in a shifting of thermal degradation temperature of organic component from about 200°C to near 400°C. In addition, the stability of organic modified colloidal silica in UV curable formula and the physical properties of resulting coatings were discussed. Furthermore, the morphology of organic modified colloidal silica was investigated by performing TEM and SEM studies‥


2006 ◽  
Vol 60 (4) ◽  
pp. 537-544 ◽  
Author(s):  
Mitsuru Ishii ◽  
Toshio Kakui ◽  
Masao Ishiguro ◽  
Sayaka Sato
Keyword(s):  

2020 ◽  
Author(s):  
Feng He ◽  
Kaiwei Zhang ◽  
Guma Yeli ◽  
Yang Tong ◽  
Daixiu Wei ◽  
...  

1987 ◽  
Vol 52 (3) ◽  
pp. 572-581 ◽  
Author(s):  
Miroslav M. Kopečni ◽  
Slobodan K. Milonjic ◽  
Wladyslaw Rudzinski ◽  
Jacek Jagiello

Adsorption isotherms of three adsorbates on the solid beads obtained from colloidal silica were determined by means of gas chromatography at low surface coverages, when lateral interactions between the adsorbed molecules are negligible. The influence of thermal pretreatment on the adsorption properties of the solids was investigated in the temperature range from 343 to 423 K, while the solids were heated between 523 K and 1 223 K. The thermodynamic parameters of adsorption have been determined and used to discuss the adsorbate-adsorbent interactions.


Author(s):  
Corson L. Cramer ◽  
Beth Armstrong ◽  
Artem A. Trofimov ◽  
Peter Wang ◽  
Derek Siddel ◽  
...  

2008 ◽  
Vol 37 (5-6) ◽  
pp. 223-226 ◽  
Author(s):  
X. Li ◽  
H. L. Cao ◽  
S. Gao ◽  
F. Y. Pan ◽  
L. Q. Weng ◽  
...  

1998 ◽  
Vol 12 (29n31) ◽  
pp. 3216-3219 ◽  
Author(s):  
M. Ausloos ◽  
S. Dorbolo

A logarithmic behavior is hidden in the linear temperature regime of the electrical resistivity R(T) of some YBCO sample below 2T c where "pairs" break apart, fluctuations occur and "a gap is opening". An anomalous effect also occurs near 200 K in the normal state Hall coefficient. In a simulation of oxygen diffusion in planar 123 YBCO, an anomalous behavior is found in the oxygen-vacancy motion near such a temperature. We claim that the behavior of the specific heat above and near the critical temperature should be reexamined in order to show the influence and implications of fluctuations and dimensionality on the nature of the phase transition and on the true onset temperature.


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