scholarly journals Superior adsorption of 3D nanoporous architectures for Ni(ii) ions adsorption using polyvinyl alcohol as cross-linking agent and adsorption conveyor

RSC Advances ◽  
2018 ◽  
Vol 8 (15) ◽  
pp. 7899-7903 ◽  
Author(s):  
Haibo Wang ◽  
Wei Wang ◽  
Yufen Zhao ◽  
Zhiwei Xu ◽  
Lei Chen ◽  
...  

In this study, we report a large-scale and low cost approach for the synthesis of three-dimensional (3D) polyvinyl alcohol/carbon nanotubes nanoporous architecture using self-assembly method.

NANO ◽  
2018 ◽  
Vol 13 (12) ◽  
pp. 1850146 ◽  
Author(s):  
Yi Li ◽  
Jun Chen ◽  
Xiao Han ◽  
Yinghui Li ◽  
Ziqiang Zhang ◽  
...  

The rapid development of smart textiles requires the large-scale fabrication of conductive fibers. In this study, we develop a simple, scalable and low-cost capillary-driven self-assembly method to prepare conductive fibers with uniform morphology, high conductivity and good mechanical strength. Fiber-shaped flexible and stretchable conductors are obtained by coating highly conductive and flexible silver nanowires (Ag NWs) on the surfaces of yarn and PDMS fibers through evaporation-induced flow and capillary-driven self-assembly, which is proven by the in situ optical microscopic observation. The density of Ag NWs and linear resistance of the conductive fibers could be regulated by tuning the assembly cycles. A linear resistance of 1.4[Formula: see text][Formula: see text]/cm could be achieved for the Ag NWs-coated nylon, which increases only 8% after 200 bending cycle, demonstrating high flexibility and mechanical stability. The flexible and stretchable conductive fibers have great potential for the application in wearable devices.


2019 ◽  
Vol 4 (3) ◽  
pp. 580-585 ◽  
Author(s):  
Bineh G. Ndefru ◽  
Bryan S. Ringstrand ◽  
Sokhna I.-Y. Diouf ◽  
Sönke Seifert ◽  
Juan H. Leal ◽  
...  

Combining bottom-up self-assembly with top-down 3D photoprinting affords a low cost approach for the introduction of nanoscale features into a build with low resolution features.


2005 ◽  
Vol 4 (1) ◽  
pp. 81-91 ◽  
Author(s):  
Martin Nilsson Jacobi ◽  
Steen Rasmussen ◽  
Kolbjørn Tunstrøm

This paper is a discussion on how reaction kinetics and three-dimensional (3D) lattice simulations can be used to elucidate the dynamical properties of micelles as a possible minimal protocell container. We start with a general discussion on the role of molecular self-assembly in prebiotic and contemporary biological systems. A simple reaction kinetic model of a micellation process of amphiphilic molecules in water is then presented and solved analytically. Amphiphilic molecules are polymers with hydrophobic (water-fearing), e.g. hydrocarbon tail groups, and hydrophilic (water-loving) head groups, e.g. fatty acids. By making a few simplifying assumptions an analytical expression for the size distribution of the resulting micelles can be derived. The main part of the paper presents and discusses a lattice gas technique for a more detailed 3D simulation of molecular self-assembly of amphiphilic polymers in aqueous environments. Water molecules, hydrocarbon tail groups and hydrophilic head groups are explicitly represented on a three-dimensional discrete lattice. Molecules move on the lattice proportional to their continuous momentum. Collision rules preserve momentum and kinetic energy. Potential energy from molecular interactions are also included explicitly. The non-trivial thermodynamics of large-scale and long-time dynamics are studied. In this paper we specifically demonstrate how, from a random initial distribution, micelles are formed and grow until they destabilize and can divide. Eventually a steady state of growing and dividing micelles is formed. Towards the end of the paper we discuss the relevance of the presented results to the design of a minimal artificial protocell.


2017 ◽  
Vol 5 (38) ◽  
pp. 20277-20288 ◽  
Author(s):  
Yong Li ◽  
Zhaozhu Zhang ◽  
Mengke Wang ◽  
Xuehu Men ◽  
Qunji Xue

Repairable and antifouling coatings were prepared via self-assembly method without destroying the intrinsic properties of substrates, which aims to tackle low transparency and poor durability problems of current coatings.


2020 ◽  
Author(s):  
Filip Bošković ◽  
Alexander Ohmann ◽  
Ulrich F. Keyser ◽  
Kaikai Chen

AbstractThree-dimensional (3D) DNA nanostructures built via DNA self-assembly have established recent applications in multiplexed biosensing and storing digital information. However, a key challenge is that 3D DNA structures are not easily copied which is of vital importance for their large-scale production and for access to desired molecules by target-specific amplification. Here, we build 3D DNA structural barcodes and demonstrate the copying and random access of the barcodes from a library of molecules using a modified polymerase chain reaction (PCR). The 3D barcodes were assembled by annealing a single-stranded DNA scaffold with complementary short oligonucleotides containing 3D protrusions at defined locations. DNA nicks in these structures are ligated to facilitate barcode copying using PCR. To randomly access a target from a library of barcodes, we employ a non-complementary end in the DNA construct that serves as a barcode-specific primer template. Readout of the 3D DNA structural barcodes was performed with nanopore measurements. Our study provides a roadmap for convenient production of large quantities of self-assembled 3D DNA nanostructures. In addition, this strategy offers access to specific targets, a crucial capability for multiplexed single-molecule sensing and for DNA data storage.


Author(s):  
C. Altuntas

<p><strong>Abstract.</strong> Image based dense point cloud creation is easy and low-cost application for three dimensional digitization of small and large scale objects and surfaces. It is especially attractive method for cultural heritage documentation. Reprojection error on conjugate keypoints indicates accuracy of the model and keypoint localisation in this method. In addition, sequential registration of the images from large scale historical buildings creates big cumulative registration error. Thus, accuracy of the model should be increased with the control points or loop close imaging. The registration of point point cloud model into the georeference system is performed using control points. In this study historical Sultan Selim Mosque that was built in sixteen century by Great Architect Sinan was modelled via photogrammetric dense point cloud. The reprojection error and number of keypoints were evaluated for different base/length ratio. In addition, georeferencing accuracy was evaluated with many configuration of control points with loop and without loop closure imaging.</p>


Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 2867
Author(s):  
Myoung Jun Park ◽  
Grace M. Nisola ◽  
Dong Han Seo ◽  
Chen Wang ◽  
Sherub Phuntsho ◽  
...  

Graphene oxide (GO) nanosheets were utilized as a selective layer on a highly porous polyvinyl alcohol (PVA) nanofiber support via a pressure-assisted self-assembly technique to synthesize composite nanofiltration membranes. The GO layer was rendered stable by cross-linking the nanosheets (GO-to-GO) and by linking them onto the support surface (GO-to-PVA) using glutaraldehyde (GA). The amounts of GO and GA deposited on the PVA substrate were varied to determine the optimum nanofiltration membrane both in terms of water flux and salt rejection performances. The successful GA cross-linking of GO interlayers and GO-PVA via acetalization was confirmed by FTIR and XPS analyses, which corroborated with other characterization results from contact angle and zeta potential measurements. Morphologies of the most effective membrane (CGOPVA-50) featured a defect-free GA cross-linked GO layer with a thickness of ~67 nm. The best solute rejections of the CGOPVA-50 membrane were 91.01% for Na2SO4 (20 mM), 98.12% for Eosin Y (10 mg/L), 76.92% for Methylene blue (10 mg/L), and 49.62% for NaCl (20 mM). These findings may provide one of the promising approaches in synthesizing mechanically stable GO-based thin-film composite membranes that are effective for solute separation via nanofiltration.


2020 ◽  
Vol 9 (3) ◽  
pp. 109-118
Author(s):  
Lei Zhao ◽  
Greg You

Brown coal is young, shallowly deposited, and widely distributed in the world. It is a fuel commonly used to generate electricity. This paper first reviews the resources and characteristics of brown coal in Victoria, Australia, and its exploitation and contribution to the economy or power supply in Victoria. Due to the shallow depth of the brown coal seam, e.g. very favorable stripping ratio, open pit mining is the only mining method used to extract the coal at low cost for power generators. With the large-scale mining operations, cases of batter failure were not rare in the area. From the comprehensive review of past failures, overburden batter tends to fail by circular sliding, coal batter tends to fail by block sliding after the overburden is stripped due to a weak water-bearing layer underneath the coal seam and tension cracks developed at the rear of the batter, and batter failure is typically coincided with peak raining seasons. Secondly, the paper reviews the case study of Maddingley Brown Coal (MBC) Open Cut Mine batter stability, including geology, hydrogeology, and hydro-mechanically coupled numerical modelling. The modelling employs three-dimensional finite element method to simulate the MBC northern batter where cracks were observed in November 2013. The comprehensive simulation covers an overburden batter, a brown coal batter, two rainfall models, and a buttressed batter. The simulated results agree well with observed data, and it is found that the rainfall at the intensity of 21mm substantially lowered the factor of safety of the coal batter.


2010 ◽  
Vol 109 (1) ◽  
pp. 25-30 ◽  
Author(s):  
S A Manafi ◽  
M H Amin ◽  
M R Rahimipour ◽  
E Salahi ◽  
A Kazemzadeh

RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 9963-9969 ◽  
Author(s):  
Zhe Wang ◽  
Min Xue ◽  
Herong Zhang ◽  
Zihui Meng ◽  
Kenneth J. Shea ◽  
...  

A simple and low-cost humidity sensor based on self-assembled three dimensional nanohydrogel colloidal array was prepared for humidity sensing.


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