Enhanced intramolecular charge transfer of unfused electron acceptors for efficient organic solar cells

2019 ◽  
Vol 3 (3) ◽  
pp. 513-519 ◽  
Author(s):  
Ran Qin ◽  
Weitao Yang ◽  
Shuixing Li ◽  
Tsz-Ki Lau ◽  
Zhipeng Yu ◽  
...  

The mediation of non-covalent interactions allowed unfused structures to exhibit a nearly planar configuration with strong charge-transfer effects, thereby ensuring efficient organic solar cells.

2018 ◽  
Vol 54 (3) ◽  
pp. 303-306 ◽  
Author(s):  
Junhui Miao ◽  
Bin Meng ◽  
Jun Liu ◽  
Lixiang Wang

The use of an A–D–A′–D–A strategy to develop small molecule acceptors with broad absorption spectra through suppressing the intramolecular charge transfer effect is studied.


Polymer ◽  
2015 ◽  
Vol 76 ◽  
pp. 220-229 ◽  
Author(s):  
Fei Li ◽  
Noel M. Dawson ◽  
Ying-Bing Jiang ◽  
Kevin J. Malloy ◽  
Yang Qin

2007 ◽  
Vol 17 (11) ◽  
pp. 1055-1062 ◽  
Author(s):  
Peter J. Skabara ◽  
Rory Berridge ◽  
Igor M. Serebryakov ◽  
Alexander L. Kanibolotsky ◽  
Lyudmila Kanibolotskaya ◽  
...  

Author(s):  
Weihua Tang ◽  
Amjad Ali ◽  
Muhammad Imran Rafiq ◽  
Baojing Zhou

The acceptor-donor-acceptor structured fused-ring electron acceptors (FREAs) are the utmost efficient electron acceptors used in organic solar cells (OSCs). Typically, several efficient electronic transitions contribute to the absorption spectra of...


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1200
Author(s):  
Ken-ichi Nakayama ◽  
Tatsuya Okura ◽  
Yuki Okuda ◽  
Jun Matsui ◽  
Akito Masuhara ◽  
...  

Conjugated donor–acceptor molecules with intramolecular charge transfer absorption are employed for single-component organic solar cells. Among the five types of donor–acceptor molecules, the strong push–pull structure of DTDCPB resulted in solar cells with high JSC, an internal quantum efficiency exceeding 20%, and high VOC exceeding 1 V with little photon energy loss around 0.7 eV. The exciton binding energy (EBE), which is a key factor in enhancing the photocurrent in the single-component device, was determined by quantum chemical calculation. The relationship between the photoexcited state and the device performance suggests that the strong internal charge transfer is effective for reducing the EBE. Furthermore, molecular packing in the film is shown to influence photogeneration in the film bulk.


2021 ◽  
Vol 93 ◽  
pp. 106132
Author(s):  
Bi-Shan Lu ◽  
Yamin Zhang ◽  
Teng-Yue Hu ◽  
Yi-Fan Ma ◽  
Yan-Nan Zhu ◽  
...  

2018 ◽  
Vol 29 (2) ◽  
pp. 325-327 ◽  
Author(s):  
Changshi Yu ◽  
Yunhua Xu ◽  
Shijie Liang ◽  
Xudong Jiang ◽  
Guitao Feng ◽  
...  

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