Hybrid MnO2@NiCo2O4 nanosheets for high performance asymmetric supercapacitors

2018 ◽  
Vol 5 (6) ◽  
pp. 1378-1385 ◽  
Author(s):  
Depeng Zhao ◽  
Xiang Wu ◽  
Chuanfei Guo

In this work, hybrid MnO2@NiCo2O4 nanosheets grown on Ni foam have been synthesized through a facile hydrothermal approach. The MnO2@NiCo2O4 electrode delivers a high specific capacitance of 3086 mF cm−2 at a current density of 2 mA cm−2.

2017 ◽  
Vol 20 (4) ◽  
pp. 197-204
Author(s):  
Weiliang Chen ◽  
Shuhua Pang ◽  
Zheng Liu ◽  
Zhewei Yang ◽  
Xin Fan ◽  
...  

Polypyrrole with hierarchical dendritic structures assembled with cauliflower-like structure of nanospheres, was synthesized by chemical oxidation polymerization. The structure of polyryrrole was characterized by Fourier transform infrared spectrometer and scanning electron microscopy. The electrochemical performance was performed on CHI660 electrochemical workstation. The results show that oxalic acid has a significant effect on morphology of PPy products. The hierarchical dendritic PPyOA(3) electrodes possess a large specific capacitance as high as 744 F/g at a current density of 0.2 A/g and could achieve a higher specific capacitance of 362 F/g even at a current density of 5.0 A/g. Moreover, the dendritic PPy products produce a large surface area on the electrode through the formation of the channel structure with their assembled cauliflower-like morphology, which facilitates the charge/electron transfer relative to the spherical PPy electrode. The spherical dendritic PPyOA(3) electrode has 58% retention of initial specific capacitance after 260 cycles. The as-prepared dendritic polypyrrole with high performance is a promsing electrode material for supercapacitor.


2014 ◽  
Vol 2 (39) ◽  
pp. 16723-16730 ◽  
Author(s):  
Arvinder Singh ◽  
Alexander J. Roberts ◽  
Robert C. T. Slade ◽  
Amreesh Chandra

A high-performance asymmetric supercapacitor was fabricated using MWCNTs/NiS composite and GNPs as electrodes, exhibiting high specific capacitance of ∼181 F g−1 at 1 A g−1 current density and excellent cyclic stability with 92% retention after 1000 cycles at 2 A g−1 current density.


RSC Advances ◽  
2016 ◽  
Vol 6 (13) ◽  
pp. 10520-10526 ◽  
Author(s):  
Qing Yang ◽  
Shuang-Yan Lin

Ultrathin nanosheet-based CoMoO4–NiMoO4 nanotubes were designed and synthesized by a hydrothermal treatment, which demonstrated a high specific capacitance of 751 F g−1 at a current density of 1 A g−1 and the excellent cycling ability.


RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 1680-1683 ◽  
Author(s):  
Li Zhang ◽  
Lei Chen ◽  
Bin Qi ◽  
Guocheng Yang ◽  
Jian Gong

Ordered TiO2@polyaniline nanorods exhibiting high specific capacitance were prepared by a simple method. The specific capacitance retention of the product is over 85% after 1000 charge and discharge cycles at a current density of 10 A g−1.


RSC Advances ◽  
2018 ◽  
Vol 8 (55) ◽  
pp. 31594-31602 ◽  
Author(s):  
Xiaobo Chen ◽  
Xiao Liu ◽  
Yongxu Liu ◽  
Yameng Zhu ◽  
Guoce Zhuang ◽  
...  

CoMn2O4@Co3O4 core/shell arrays on Ni foam exhibit outstanding electrochemical performance for asymmetric supercapacitors with respect to high specific capacitance and high cycling stability.


2015 ◽  
Vol 39 (11) ◽  
pp. 8430-8438 ◽  
Author(s):  
Mingming Yao ◽  
Zhonghua Hu ◽  
Yafei Liu ◽  
Peipei Liu

A novel electrode material of three-dimensional hierarchical NiCo2S4@NiMoO4core/shell nanospheres was synthesized by a facile two-step hydrothermal method. These hierarchical NiCo2S4@NiMoO4core/shell nanospheres exhibit a high specific capacitance of 1714 F g−1at a current density of 1 A g−1, which indicated the excellent electrochemistry performance.


RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 48341-48353 ◽  
Author(s):  
Xia Yang ◽  
Yuying Yang ◽  
Quancai Zhang ◽  
Xiaotong Wang ◽  
Yufeng An ◽  
...  

1-Hydroxyanthraquinone (HAQ) is selected to functionalize the dissected carbon nanotubes (rDCNTs) with reduced graphene oxide layers through non-covalent modification. The composite achieves high specific capacitance and ultrahigh rate capability.


2016 ◽  
Vol 40 (8) ◽  
pp. 6881-6889 ◽  
Author(s):  
Cuiping Yu ◽  
Yan Wang ◽  
Jianfang Zhang ◽  
Xia Shu ◽  
Jiewu Cui ◽  
...  

Novel nanocomposite NiCo2O4/C-TNAs were synthesized for high-performance supercapacitors with a specific capacitance of 934.9 F g−1 at a current density of 2 A g−1.


2012 ◽  
Vol 20 ◽  
pp. 53-60 ◽  
Author(s):  
Zan Wang ◽  
Xin Wang ◽  
Yun Xiao Zhao ◽  
Cui Mei Zhao ◽  
Wei Tao Zheng

Nanostructured MnOx/Ni (OH)2 composites have been electrodeposited on Ni foam for synthesis of a binder-free electrode for electrochemical capacitors with high specific capacitance and stable electrochemical properties. The microstructure, morphology and chemical composition were characterized by X-ray diffraction, scanning electron microscopy and X-ray photoelectron spectroscopy. Cyclic voltammetry and galvanostatic charge/discharge measurements were applied to investigate the electrochemical capacitance of the electrode active materials. The results indicated that MnOx acted as a template for growth of Ni (OH)2 with an inter-connected 3D porous network nanostructure. A maximum capacitance value of 2334 F/g at current density of 5 A/g in 1 M KOH electrolyte was achieved, much higher than that of pure Ni (OH)2 and MnOx (992 and 179 F/g, respectively). Moreover, in the charge/discharge process at even larger current density of 20 A/g, the electrode could maintain 82.8 % of the initial specific capacitance after 500 cycles, higher than that of pure Ni (OH)2 (only 46.6% remains). The enhanced capacitance performance was attributed to the synergic effect between the respective single oxides.


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