Design and synthesis of hierarchical NiCo2S4@NiMoO4core/shell nanospheres for high-performance supercapacitors

2015 ◽  
Vol 39 (11) ◽  
pp. 8430-8438 ◽  
Author(s):  
Mingming Yao ◽  
Zhonghua Hu ◽  
Yafei Liu ◽  
Peipei Liu
Keyword(s):  
Specific Capacitance ◽  
Hydrothermal Method ◽  
Current Density ◽  
Electrode Material ◽  
High Performance ◽  
Three Dimensional ◽  
High Specific Capacitance ◽  
Core Shell ◽  
Design And Synthesis ◽  
A Current

A novel electrode material of three-dimensional hierarchical NiCo2S4@NiMoO4core/shell nanospheres was synthesized by a facile two-step hydrothermal method. These hierarchical NiCo2S4@NiMoO4core/shell nanospheres exhibit a high specific capacitance of 1714 F g−1at a current density of 1 A g−1, which indicated the excellent electrochemistry performance.

Synthesis of vertical aligned TiO2@polyaniline core–shell nanorods for high-performance supercapacitors

RSC Advances ◽  
2015 ◽  
Vol 5 (3) ◽  
pp. 1680-1683 ◽  
Author(s):  
Li Zhang ◽  
Lei Chen ◽  
Bin Qi ◽  
Guocheng Yang ◽  
Jian Gong
Keyword(s):  
Specific Capacitance ◽  
Current Density ◽  
High Performance ◽  
High Specific Capacitance ◽  
Core Shell ◽  
Simple Method ◽  
Polyaniline Nanorods ◽  
A Current

Ordered TiO2@polyaniline nanorods exhibiting high specific capacitance were prepared by a simple method. The specific capacitance retention of the product is over 85% after 1000 charge and discharge cycles at a current density of 10 A g−1.

Hierarchical Dendritic Polypyrrole with High Specific Capacitance for High-performance Supercapacitor Electrode Materials

2017 ◽  
Vol 20 (4) ◽  
pp. 197-204
Author(s):  
Weiliang Chen ◽  
Shuhua Pang ◽  
Zheng Liu ◽  
Zhewei Yang ◽  
Xin Fan ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Current Density ◽  
High Performance ◽  
Electrode Materials ◽  
High Specific Capacitance ◽  
Chemical Oxidation ◽  
Channel Structure ◽  
Supercapacitor Electrode ◽  
Infrared Spectrometer ◽  
A Current

Polypyrrole with hierarchical dendritic structures assembled with cauliflower-like structure of nanospheres, was synthesized by chemical oxidation polymerization. The structure of polyryrrole was characterized by Fourier transform infrared spectrometer and scanning electron microscopy. The electrochemical performance was performed on CHI660 electrochemical workstation. The results show that oxalic acid has a significant effect on morphology of PPy products. The hierarchical dendritic PPyOA(3) electrodes possess a large specific capacitance as high as 744 F/g at a current density of 0.2 A/g and could achieve a higher specific capacitance of 362 F/g even at a current density of 5.0 A/g. Moreover, the dendritic PPy products produce a large surface area on the electrode through the formation of the channel structure with their assembled cauliflower-like morphology, which facilitates the charge/electron transfer relative to the spherical PPy electrode. The spherical dendritic PPyOA(3) electrode has 58% retention of initial specific capacitance after 260 cycles. The as-prepared dendritic polypyrrole with high performance is a promsing electrode material for supercapacitor.

Rationally designed nanosheet-based CoMoO4–NiMoO4 nanotubes for high-performance electrochemical electrodes

RSC Advances ◽  
2016 ◽  
Vol 6 (13) ◽  
pp. 10520-10526 ◽  
Author(s):  
Qing Yang ◽  
Shuang-Yan Lin
Keyword(s):  
Specific Capacitance ◽  
Hydrothermal Treatment ◽  
Current Density ◽  
High Performance ◽  
High Specific Capacitance ◽  
Electrochemical Electrodes ◽  
Ultrathin Nanosheet ◽  
A Current

Ultrathin nanosheet-based CoMoO4–NiMoO4 nanotubes were designed and synthesized by a hydrothermal treatment, which demonstrated a high specific capacitance of 751 F g−1 at a current density of 1 A g−1 and the excellent cycling ability.

One-Step Hydrothermal Preparation of 1D α-MoO3 Nanobelt Electrode Material for Supercapacitor

NANO ◽  
2019 ◽  
Vol 14 (07) ◽  
pp. 1950085 ◽  
Author(s):  
Puhong Wen ◽  
Jingjing Guo ◽  
Lijun Ren ◽  
Chuanchuan Wang ◽  
Yuzhu Lan ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Current Density ◽  
Electrode Material ◽  
High Specific Capacitance ◽  
Raw Material ◽  
Hydrothermal Preparation ◽  
Ammonium Heptamolybdate ◽  
One Step ◽  
A Current

1D [Formula: see text]-MoO3 nanobelts were prepared using ammonium heptamolybdate tetrahydrate [(NH[Formula: see text]Mo7O[Formula: see text]H2O] as raw material by one-step hydrothermal method without template or guide agent at 180∘C. The layered [Formula: see text]-MoO3 nanobelt electrode has favorable electrochemical performance, and displays a fairly high specific capacitance, which can be up to 445[Formula: see text]F/g at a current density of 0.5[Formula: see text]A/g.

ZnO@Ni–Co–S Core–Shell Nanorods-Decorated Carbon Fibers as Advanced Electrodes for High-Performance Supercapacitors

NANO ◽  
2018 ◽  
Vol 13 (12) ◽  
pp. 1850148 ◽  
Author(s):  
Yanwei Sui ◽  
Man Zhang ◽  
Haihua Hu ◽  
Yuanming Zhang ◽  
Jiqiu Qi ◽  
...  
Keyword(s):  
Current Density ◽  
High Performance ◽  
Zno Nanorods ◽  
Three Dimensional ◽  
Interfacial Area ◽  
Core Shell ◽  
Fast Diffusion ◽  
Potentiostatic Electrodeposition ◽  
One Step ◽  
A Current

The interconnected three-dimensional Ni–Co–S nanosheets were successfully deposited on ZnO nanorods by a one-step potentiostatic electrodeposition. The Ni–Co–S nanosheets provide a large electrode/electrolyte interfacial area which has adequate electroactive sites for redox reactions. Electrochemical characterization of the ZnO@Ni–Co–S core–shell nanorods presents high specifc capacitance (1302.5[Formula: see text]F/g and 1085[Formula: see text]F/g at a current density of 1 A/g and 20 A/g), excellent rate capabilities (83.3% retention at 20[Formula: see text]A/g) and great cycling stability (65% retention after 5000 cycles at a current density of 30[Formula: see text]A/g). The outstanding electrochemical performance of the as-prepared electrode material also can be ascribed to these reasons that the special structure improved electrical conductivity and allowed the fast diffusion of electrolyte ions.

Hybrid MnO2@NiCo2O4 nanosheets for high performance asymmetric supercapacitors

2018 ◽  
Vol 5 (6) ◽  
pp. 1378-1385 ◽  
Author(s):  
Depeng Zhao ◽  
Xiang Wu ◽  
Chuanfei Guo
Keyword(s):  
Specific Capacitance ◽  
Current Density ◽  
High Performance ◽  
High Specific Capacitance ◽  
Ni Foam ◽  
Asymmetric Supercapacitors ◽  
Hydrothermal Approach ◽  
Nico2o4 Nanosheets ◽  
A Current

In this work, hybrid MnO2@NiCo2O4 nanosheets grown on Ni foam have been synthesized through a facile hydrothermal approach. The MnO2@NiCo2O4 electrode delivers a high specific capacitance of 3086 mF cm−2 at a current density of 2 mA cm−2.

scholarly journals Fabrication of Hierarchical NiMoO4/NiMoO4 Nanoflowers on Highly Conductive Flexible Nickel Foam Substrate as a Capacitive Electrode Material for Supercapacitors with Enhanced Electrochemical Performance

Energies ◽  
2019 ◽  
Vol 12 (6) ◽  
pp. 1143 ◽  
Author(s):  
Anil Yedluri ◽  
Tarugu Anitha ◽  
Hee-Je Kim
Keyword(s):  
Energy Density ◽  
Electrochemical Performance ◽  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance ◽  
High Energy ◽  
High Energy Density ◽  
Charge Discharge

Hierarchical NiMoO4/NiMoO4 nanoflowers were fabricated on highly conductive flexible nickel foam (NF) substrates using a facile hydrothermal method to achieve rapid charge-discharge ability, high energy density, long cycling lifespan, and higher flexibility for high-performance supercapacitor electrode materials. The synthesized composite electrode material, NF/NiMoO4/NiMoO4 with a nanoball-like NF/NiMoO4 structure on a NiMoO4 surface over a NF substrate, formed a three-dimensional interconnected porous network for high-performance electrodes. The novel NF/NiMoO4/NiMoO4 nanoflowers not only enhanced the large surface area and increased the electrochemical activity, but also provided an enhanced rapid ion diffusion path and reduced the charge transfer resistance of the entire electrode effectively. The NF/NiMoO4/NiMoO4 composite exhibited significantly improved supercapacitor performance in terms of a sustained cycling life, high specific capacitance, rapid charge-discharge capability, high energy density, and good rate capability. Electrochemical analysis of the NF/NiMoO4/NiMoO4 nanoflowers fabricated on the NF substrate revealed ultra-high electrochemical performance with a high specific capacitance of 2121 F g−1 at 12 mA g−1 in a 3 M KOH electrolyte and 98.7% capacitance retention after 3000 cycles at 14 mA g−1. This performance was superior to the NF/NiMoO4 nanoball electrode (1672 F g−1 at 12 mA g−1 and capacitance retention 93.4% cycles). Most importantly, the SC (NF/NiMoO4/NiMoO4) device displayed a maximum energy density of 47.13 W h kg−1, which was significantly higher than that of NF/NiMoO4 (37.1 W h kg−1). Overall, the NF/NiMoO4/NiMoO4 composite is a suitable material for supercapacitor applications.

Integration of mesoporous nickel cobalt oxide nanosheets with ultrathin layer carbon wrapped TiO2 nanotube arrays for high-performance supercapacitors

2016 ◽  
Vol 40 (8) ◽  
pp. 6881-6889 ◽  
Author(s):  
Cuiping Yu ◽  
Yan Wang ◽  
Jianfang Zhang ◽  
Xia Shu ◽  
Jiewu Cui ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
Cobalt Oxide ◽  
Current Density ◽  
High Performance ◽  
Tio2 Nanotube Arrays ◽  
Nanotube Arrays ◽  
Nickel Cobalt ◽  
Nickel Cobalt Oxide ◽  
A Current ◽  
Ultrathin Layer

Novel nanocomposite NiCo2O4/C-TNAs were synthesized for high-performance supercapacitors with a specific capacitance of 934.9 F g−1 at a current density of 2 A g−1.

Flower-like ZnO@MnCo2O4 nanosheet structures on nickel foam as novel electrode material for high-performance supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (105) ◽  
pp. 102961-102967 ◽  
Author(s):  
Chandu V. V. M. Gopi ◽  
Mallineni Venkata-Haritha ◽  
Soo-Kyoung Kim ◽  
Kandasamy Prabakar ◽  
Hee-Je Kim
Keyword(s):  
Specific Capacitance ◽  
Electrode Material ◽  
High Performance ◽  
Nickel Foam ◽  
High Specific Capacitance

The flower-like ZnO@MnCo2O4 nanosheet electrode exhibited high specific capacitance than dandelion-like MnCo2O4.

Hierarchical core/shell structures of ZnO nanorod@CoMoO4 nanoplates used as a high-performance electrode for supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 3020-3024 ◽  
Author(s):  
Yunjiu Cao ◽  
Lei An ◽  
Lijun Liao ◽  
Xijian Liu ◽  
Tao Ji ◽  
...  
Keyword(s):  
Specific Capacitance ◽  
High Performance ◽  
High Specific Capacitance ◽  
Cycling Stability ◽  
Shell Structures ◽  
Core Shell ◽  
Zno Nanorod ◽  
Good Cycling Stability

ZnO@CoMoO4 core/shell structures as an electrode for supercapacitors exhibited a high specific capacitance of 1.52 F cm−2 (1169 F g−1) at 2 mA cm−2 and a good cycling stability of 109% of the initial specific capacitance after 5000 cycles.

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