A 3D molecular cantilever based on interfacial self-assembly and the cobra-like actuation of long-chain imidazolium ionic liquids

Nanoscale ◽  
2019 ◽  
Vol 11 (15) ◽  
pp. 7277-7286 ◽  
Author(s):  
Jia Yu ◽  
Yanlei Wang ◽  
Cuifang Zhao ◽  
Shimou Chen ◽  
Suojiang Zhang

Based on the controllable interfacial self-assembly of monolayer long-chain ionic liquids on carbon nanotubes, a 3D molecular cantilever with a cobra-like actuation mechanism is designed.

Author(s):  
Takuzo Aida ◽  
Takanori Fukushima

This review article focuses on our recent studies on novel soft materials consisting of carbon nanotubes. Single-walled carbon nanotubes, when suspended in imidazolium ion-based ionic liquids and ground in an agate mortar, form physical gels (bucky gels), where heavily entangled bundles of carbon nanotubes are exfoliated to give highly dispersed, much finer bundles. By using bucky gels, the first printable actuators that operate in air for a long time without any external electrolyte are developed. Furthermore, the use of polymerizable ionic liquids as the gelling media results in the formation of electroconductive polymer/nanotube composites with enhanced mechanical properties. The article also highlights a new family of nanotubular graphite, via self-assembly of amphiphilic hexabenzocoronene (HBC) derivatives. The nanotubes consist of a graphitic wall composed of a great number of π-stacked HBC units and are electroconductive upon oxidation. The use of amphiphilic HBCs with functional groups results in the formation of nanotubes with various interesting properties.


2018 ◽  
Vol 42 (9) ◽  
pp. 7105-7118 ◽  
Author(s):  
Somenath Panda ◽  
Kaushik Kundu ◽  
Anusha Basaiahgari ◽  
Akhil Pratap Singh ◽  
Sanjib Senapati ◽  
...  

The self-assembly of long-chain choline carboxylates accompanied by their interaction with BSA protein were investigated with focus on environmental sustainability.


2018 ◽  
Vol 273 ◽  
pp. 955-965 ◽  
Author(s):  
Takushi Sugino ◽  
Yoshiyuki Shibata ◽  
Kenji Kiyohara ◽  
Kinji Asaka

2011 ◽  
Vol 11 (5) ◽  
pp. 1974-1988 ◽  
Author(s):  
Xinjiao Wang ◽  
Carola S. Vogel ◽  
Frank W. Heinemann ◽  
Peter Wasserscheid ◽  
Karsten Meyer

2009 ◽  
Vol 336 (2) ◽  
pp. 793-802 ◽  
Author(s):  
Natalia A. Smirnova ◽  
Alexandr A. Vanin ◽  
Evgenia A. Safonova ◽  
Igor B. Pukinsky ◽  
Yuri A. Anufrikov ◽  
...  

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