Biomimetic high-intensity superhydrophobic metal rubber with anti-corrosion property for industrial oil–water separation

2019 ◽  
Vol 43 (4) ◽  
pp. 1894-1899 ◽  
Author(s):  
Zhiying Ren ◽  
Gang Wen ◽  
Zhiguang Guo
Keyword(s):  
Chemical Etching ◽  
Scale Up ◽  
Water Repellency ◽  
Corrosion Property ◽  
Water Separation ◽  
Industrial Oil ◽  
Mechanical Durability ◽  
Metal Rubber ◽  
Oil Water Separation ◽  
Oil Water

In this work, a superhydrophobic metal rubber with excellent water repellency, mechanical durability, corrosion resistance and oil/water separation properties was prepared by a facile and scale-up chemical etching method and a straightforward modification.

scholarly journals Carbon Nanotubes and Polydopamine Modified Poly(dimethylsiloxane) Sponges for Efficient Oil–Water Separation

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2431
Author(s):  
Wen Zhang ◽  
Juanjuan Wang ◽  
Xue Han ◽  
Lele Li ◽  
Enping Liu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Large Scale ◽  
Absorption Capacity ◽  
Potential Candidate ◽  
Hard Template ◽  
Water Separation ◽  
Industrial Oil ◽  
The Matrix ◽  
Oil Water Separation ◽  
Oil Water

In this paper, effective separation of oil from both immiscible oil–water mixtures and oil-in-water (O/W) emulsions are achieved by using poly(dimethylsiloxane)-based (PDMS-based) composite sponges. A modified hard template method using citric acid monohydrate as the hard template and dissolving it in ethanol is proposed to prepare PDMS sponge composited with carbon nanotubes (CNTs) both in the matrix and the surface. The introduction of CNTs endows the composite sponge with enhanced comprehensive properties including hydrophobicity, absorption capacity, and mechanical strength than the pure PDMS. We demonstrate the successful application of CNT-PDMS composite in efficient removal of oil from immiscible oil–water mixtures within not only a bath absorption, but also continuous separation for both static and turbulent flow conditions. This notable characteristic of the CNT-PDMS sponge enables it as a potential candidate for large-scale industrial oil–water separation. Furthermore, a polydopamine (PDA) modified CNT-PDMS is developed here, which firstly realizes the separation of O/W emulsion without continuous squeezing of the sponge. The combined superhydrophilic and superoleophilic property of PDA/CNT-PDMS is assumed to be critical in the spontaneously demulsification process.

scholarly journals Surface Engineering of Ceramic Nanomaterials for Separation of Oil/Water Mixtures

2020 ◽  
Vol 8 ◽  
Author(s):  
Usama Zulfiqar ◽  
Andrew G. Thomas ◽  
Allan Matthews ◽  
David J. Lewis
Keyword(s):  
Surface Engineering ◽  
Oil Spills ◽  
Chemical Interaction ◽  
Low Cost ◽  
Water Mixture ◽  
Water Separation ◽  
Manufacturing Operations ◽  
Industrial Oil ◽  
Oil Water Separation ◽  
Oil Water

Oil/water mixtures are a potentially major source of environmental pollution if efficient separation technology is not employed during processing. A large volume of oil/water mixtures is produced via many manufacturing operations in food, petrochemical, mining, and metal industries and can be exposed to water sources on a regular basis. To date, several techniques are used in practice to deal with industrial oil/water mixtures and oil spills such as in situ burning of oil, bioremediation, and solidifiers, which change the physical shape of oil as a result of chemical interaction. Physical separation of oil/water mixtures is in industrial practice; however, the existing technologies to do so often require either dissipation of large amounts of energy (such as in cyclones and hydrocyclones) or large residence times or inventories of fluids (such as in decanters). Recently, materials with selective wettability have gained attention for application in separation of oil/water mixtures and surfactant stabilized emulsions. For example, a superhydrophobic material is selectively wettable toward oil while having a poor affinity for the aqueous phase; therefore, a superhydrophobic porous material can easily adsorb the oil while completely rejecting the water from an oil/water mixture, thus physically separating the two components. The ease of separation, low cost, and low-energy requirements are some of the other advantages offered by these materials over existing practices of oil/water separation. The present review aims to focus on the surface engineering aspects to achieve selectively wettability in materials and its their relationship with the separation of oil/water mixtures with particular focus on emulsions, on factors contributing to their stability, and on how wettability can be helpful in their separation. Finally, the challenges in application of superwettable materials will be highlighted, and potential solutions to improve the application of these materials will be put forward.

scholarly journals Fabricated of Superhydrophobic Silanized Melamine Sponge with Photochromic Properties for Efficiency Oil/Water Separation

2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  
Keyword(s):  
Large Scale ◽  
Separation Efficiency ◽  
Low Cost ◽  
Water Repellency ◽  
Dip Coating ◽  
Absorption Capacity ◽  
Photochromic Properties ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.

scholarly journals Facile Fabrication of Magnetic, Durable and Superhydrophobic Cotton for Efficient Oil/Water Separation

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 442 ◽  
Author(s):  
Mingguang Yu ◽  
Qing Wang ◽  
Wenxin Yang ◽  
Yonghang Xu ◽  
Min Zhang ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Water Repellency ◽  
Cotton Fabrics ◽  
Ammonia Solution ◽  
Hot Water ◽  
Water Contact ◽  
Water Separation ◽  
Efficient Strategy ◽  
Oil Water Separation ◽  
Oil Water

In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe3O4 magnetic nanoparticles was prepared via the in situ coprecipitation of Fe2+/Fe3+ ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The as-prepared cotton demonstrated excellent superhydrophobicity with a water contact angle of 155.6° ± 1.2° and good magnetic responsiveness. Under the control of the external magnetic field, the cotton fabrics could be easily controlled to absorb the oil from water as oil absorbents, showing high oil/water separation efficiency, even in hot water. Moreover, the cotton demonstrated remarkable mechanical durable properties, being strongly friction-resistant against sandpaper and finger wipe, while maintaining its water repellency. This study developed a novel and efficient strategy for the construction of magnetic, durable, and superhydrophobic biomass-based adsorbent for oil/water separation, which can be easily scaled up for practical oil absorption.

A superhydrophobic and elastic melamine sponge for oil/water separation

2019 ◽  
Vol 43 (16) ◽  
pp. 6343-6349 ◽  
Author(s):  
Ying Zhang ◽  
Qian Zhang ◽  
Ruiyang Zhang ◽  
Shuaizhuo Liu ◽  
Ying Zhou
Keyword(s):  
Organic Solvents ◽  
Water Separation ◽  
Industrial Oil ◽  
Oil Water Separation ◽  
Oil Water ◽  
Great Harm

The leakage of industrial oil and organic solvents can wreak great harm to the environment and ecology.

Fabrication of superoleophobic cotton fabric for multi-purpose applications

2019 ◽  
Vol 377 (2150) ◽  
pp. 20190129 ◽  
Author(s):  
Balraj K. Tudu ◽  
Aditya Kumar ◽  
Bharat Bhushan
Keyword(s):  
Cotton Fabric ◽  
Water Separation ◽  
Practical Applications ◽  
Wetting Properties ◽  
Stain Resistance ◽  
Mechanical Durability ◽  
Oil Water Separation ◽  
Oil Water ◽  
Self Cleaning ◽  
Liquid Repellency

Superoleophobicity is of interest for practical applications such as liquid repellency, self-cleaning, stain resistance, anti-bacterial properties and oil–water separation. In this work, the superoleophobic coating on cotton fabric was applied by simple immersion in TiO 2 nanoparticles, perfluorodecyltriethoxysilane and tertraethylorthosilicate solution. Its anti-wetting properties, surface morphology and functionality were characterized. The coated cotton fabric shows superoleophobicity with oil (surface tension more than 27 mN m −1 ) contact angle of 152° and tilt angle of 6°. Furthermore, the superoleophobic cotton fabric was demonstrated to exhibit self-cleaning, stain resistance, mechanical durability, chemical stability, thermal stability, anti-bacterial properties and oil–water separation capabilities. This article is part of the theme issue ‘Bioinspired materials and surfaces for green science and technology (part 2)’.

scholarly journals Efficient Oil/Water Separation Membrane Derived from Super-Flexible and Superhydrophilic Core–Shell Organic/Inorganic Nanofibrous Architectures

Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 974 ◽  
Author(s):  
Zhi Liu ◽  
Detao Qin ◽  
Jianghui Zhao ◽  
Quan Feng ◽  
Zhengtao Li ◽  
...  
Keyword(s):  
Separation Efficiency ◽  
Scale Up ◽  
Core Shell ◽  
Water Separation ◽  
Membrane Performance ◽  
Novel Approach ◽  
Separation Membrane ◽  
Oil Water Separation ◽  
Oil Water ◽  
Nanofibrous Membranes

To address the worldwide oil and water separation issue, a novel approach was inspired by natural phenomena to synthesize superhydrophilic and underwater superoleophobic organic/inorganic nanofibrous membranes via a scale up fabrication approach. The synthesized membranes possess a delicate organic core of PVDF-HFP and an inorganic shell of a CuO nanosheet structure, which endows super-flexible properties owing to the merits of PVDF-HFP backbones, and superhydrophilic functions contributed by the extremely rough surface of a CuO nanosheet anchored on flexible PVDF-HFP. Such an organic core and inorganic shell architecture not only functionalizes membrane performance in terms of antifouling, high flux, and low energy consumption, but also extends the lifespan by enhancing its mechanical strength and alkaline resistance to broaden its applicability. The resultant membrane exhibits good oil/water separation efficiency higher than 99.7%, as well as excellent anti-fouling properties for various oil/water mixtures. Considering the intrinsic structural innovation and its integrated advantages, this core–shell nanofibrous membrane is believed to be promising for oil/water separation, and this facile approach is also easy for scaled up manufacturing of functional organic/inorganic nanofibrous membranes with insightful benefits for industrial wastewater treatment, sensors, energy production, and many other related areas.

Core–sheath structured electrospun nanofibrous membranes for oil–water separation

RSC Advances ◽  
2016 ◽  
Vol 6 (48) ◽  
pp. 41861-41870 ◽  
Author(s):  
Wenjing Ma ◽  
Qilu Zhang ◽  
Sangram Keshari Samal ◽  
Fang Wang ◽  
Buhong Gao ◽  
...  
Keyword(s):  
Oil Spill ◽  
Cost Effective ◽  
Polluted Water ◽  
Water Separation ◽  
Highly Efficient ◽  
Industrial Oil ◽  
Oil Water Separation ◽  
Oil Water ◽  
Nanofibrous Membranes

In recent years, both the increasing frequency of oil spill accidents and the urgency to deal seriously with industrial oil-polluted water, encouraged material scientists to design highly efficient, cost effective oil–water separation technologies.

Facile fabrication of superhydrophobic filter paper with improved durability and water repellency

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Lizheng Sha ◽  
Chao Ma ◽  
Huifang Zhao ◽  
Supeng Qiu ◽  
Zhongyu Yan ◽  
...  
Keyword(s):  
Filter Paper ◽  
Separation Efficiency ◽  
Cellulose Nanofibrils ◽  
Water Repellency ◽  
Step Method ◽  
Water Contact ◽  
Water Separation ◽  
Oil Water Separation ◽  
Oil Water ◽  
Self Cleaning

Abstract Superhydrophobic surfaces have high potential in self-cleaning and oil-water separation applications. We developed a three-step method for the preparation of superhydrophobic filter paper. It involved citric acid (CA) pretreatment to activate cellulose fibers, coating with cellulose nanofibrils/functionalized silica (CNFs/m-SiO2) slurry to increase surface roughness, and grafting of hexadecyltrimethoxysilane (HDTMS) to enhance water resistance. The water contact angle (WCA) and siding angle (SA) of the prepared filter paper reached 151.5° and 7.5°, respectively. The results showed that, compared to the coated filter paper without the added CNFs, the coated paper with CNFs had higher retention of m-SiO2, thus roughness required for superhydrophobic surface was achieved. Further test under frequent abrasion and acid or alkali conditions showed that CA pretreatment improved the durability of superhydrophobic filter paper due to chemical crosslinking between the modified substrate and m-SiO2. Besides, the prepared superhydrophobic filter paper had outstanding self-cleaning property and high oil-water separation efficiency for various oil-water mixtures. Therefore, it is expected to be used for the treatment of oily wastewater.

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