A water-stable Ni(ii) diphosphonate exhibiting water vapor adsorption and water-assisted high proton conductivity

2019 ◽  
Vol 43 (2) ◽  
pp. 807-812 ◽  
Author(s):  
Hailong Xu ◽  
Lu Feng ◽  
Wentao Huang ◽  
Qiaoyun Wang ◽  
Hong Zhou
Keyword(s):  
Thermal Properties ◽  
Water Vapor ◽  
Proton Conductivity ◽  
Proton Conduction ◽  
Water Vapor Adsorption ◽  
Water Stability ◽  
High Proton Conductivity ◽  
Vapor Adsorption ◽  
High Proton

A new nickel phosphonate has been synthesized, and its thermal properties, water stability, water vapor adsorption and proton conduction have been investigated.

scholarly journals Twist and sliding dynamics between interpenetrated frames in Ti-MOF revealing high proton conductivity

2020 ◽  
Vol 11 (15) ◽  
pp. 3978-3985 ◽  
Author(s):  
Jing Cao ◽  
Wenjie Ma ◽  
Kangjie Lyu ◽  
Lin Zhuang ◽  
Hengjiang Cong ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Sliding Dynamics

Twist and sliding dynamics observed in a titanium catecholate MOF induced by imidazole for efficient proton conduction.

Assembly of three coordination polymers based on a sulfonic–carboxylic ligand showing high proton conductivity

2015 ◽  
Vol 44 (3) ◽  
pp. 948-954 ◽  
Author(s):  
Shu-Na Zhao ◽  
Xue-Zhi Song ◽  
Min Zhu ◽  
Xing Meng ◽  
Lan-Lan Wu ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Coordination Polymers ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Conduction Behavior

Three MOFs with different structures all exhibit proton conduction behavior, especially for the Cu compound with a proton conductivity of 3.46 × 10−3 S cm−1 at 368 K and 95% RH.

A rare 4-connected neb-type 3D chiral polyoxometalate framework based on {KNb24O72} clusters

2020 ◽  
Vol 7 (20) ◽  
pp. 3919-3924
Author(s):  
Zeng-Kui Zhu ◽  
Li-Dan Lin ◽  
Jing Zhang ◽  
Xin-Xiong Li ◽  
Yan-Qiong Sun ◽  
...  
Keyword(s):  
Water Vapor ◽  
High Water ◽  
Proton Conduction ◽  
Water Vapor Adsorption ◽  
Adsorption Properties ◽  
Vapor Adsorption

A rare 3D porous chiral polyoxoniobate framework has been constructed from two types of isomeric {Cu(en)2KNb24O72} clusters with a 4-connected neb-type topology. This compound exhibits proton conduction and high water vapor adsorption properties.

Dual-cubic-cage based lanthanide sulfate–carboxylpyrazolate frameworks with high hydrolytic stability and remarkable proton conduction

2019 ◽  
Vol 55 (17) ◽  
pp. 2497-2500 ◽  
Author(s):  
Liang He ◽  
Jayanta Kumar Nath ◽  
Er-Xia Chen ◽  
Heng-Dong Lai ◽  
Shan-Lin Huang ◽  
...  
Keyword(s):  
Relative Humidity ◽  
Proton Conductivity ◽  
Hydrolytic Stability ◽  
Hydrothermal Condition ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton

Lanthanide sulfate–carboxylpyrazolate nets, which have double cuboid cavities, encapsulated single-ion hydrates, tolerance in water for 6 months and even under a 200 °C hydrothermal condition tested for 3 days, and high proton-conductivity of over 10−3 S cm−1 at 25 °C and at 97% relative humidity are reported.

Purely inorganic frameworks based on polyoxometalate clusters with abundant phosphate groups: single-crystal to single-crystal structural transformation and remarkable proton conduction

2020 ◽  
Vol 56 (3) ◽  
pp. 391-394 ◽  
Author(s):  
Shan Zhang ◽  
Ying Lu ◽  
Xiu-Wei Sun ◽  
Zhuo Li ◽  
Tian-Yi Dang ◽  
...  
Keyword(s):  
Single Crystal ◽  
Proton Conductivity ◽  
Structural Transformation ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Crystal Structural ◽  
Inorganic Framework ◽  
Phosphate Groups ◽  
New Framework

A pure-inorganic framework 1 underwent a SCSC transformation to form a new framework 1′, which has high proton conductivity.

scholarly journals Preparation of a Composite Material AC/Cu-BTC with Improved Water Stability and n-Hexane Vapor Adsorption

2019 ◽  
Vol 2019 ◽  
pp. 1-9 ◽  
Author(s):  
Manlin Li ◽  
Weiqiu Huang ◽  
Bo Tang ◽  
Fujiao Song ◽  
Aihua Lv ◽  
...  
Keyword(s):  
Composite Material ◽  
Water Vapor ◽  
Active Sites ◽  
Water Vapor Adsorption ◽  
Water Molecules ◽  
Water Stability ◽  
Ambient Conditions ◽  
Hexane Vapor ◽  
Vapor Adsorption ◽  
Organic Linker

The Cu-BTC, a widely studied metal-organic framework (MOF), has been applied in various fields such as gas adsorption, separation, storage, and catalysis. However, the Cu-BTC collapses due to the replacement of the organic linker by water molecules under humid conditions, which limits its practical application in industries. In consideration of the undesirable water effect on the framework stability of Cu-BTC, a stable activated carbon (AC) was incorporated into it by the in situ method to yield a composite material AC/Cu-BTC with high water stability. XRD and SEM patterns proved that the AC7%/Cu-BTC successfully retains its crystal structure after being exposed to water molecules. The adsorption amount of n-hexane vapor of the AC7%/Cu-BTC after water vapor adsorption-thermal desorption is 307% of that of the Cu-BTC. The addition of the AC changes the adsorption active sites and reduces the strong affinity of the Cu-BTC to water molecules, resulting in the AC7%/Cu-BTC having a much lower adsorption rate for water vapor than the Cu-BTC. Therefore, the AC7%/Cu-BTC can be protected from a large amount of water molecules and avoid structural collapse caused by the disconnection between the copper center and the organic linker. The composite displays a potential value for stable applications of MOF-based materials under ambient conditions.

A stable porphyrinic metal–organic framework pore-functionalized by high-density carboxylic groups for proton conduction

2017 ◽  
Vol 5 (28) ◽  
pp. 14525-14529 ◽  
Author(s):  
Hao Wu ◽  
Fan Yang ◽  
Xiu-Liang Lv ◽  
Bin Wang ◽  
Yong-Zheng Zhang ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Framework ◽  
Proton Conduction ◽  
High Density ◽  
Carboxylic Group ◽  
High Proton Conductivity ◽  
High Proton ◽  
Carboxylic Groups ◽  
Metal Organic ◽  
Organic Framework

A highly stable porphyrinic MOF with free-carboxylic group functionalized pore surfaces exhibits a high proton conductivity of 3.9 × 10−2 S cm−1 at 80 °C and 97% RH, which is comparable to most of the reported proton conductive MOFs.

PbX2(OOCMMIm) (X = Cl, Br): photoluminescent organic–inorganic hybrid lead halide compounds with high proton conductivity

2019 ◽  
Vol 48 (20) ◽  
pp. 6690-6694 ◽  
Author(s):  
Liao-Kuo Gong ◽  
Ke-Zhao Du ◽  
Xiao-Ying Huang
Keyword(s):  
Proton Conductivity ◽  
Proton Conduction ◽  
Photoluminescence Properties ◽  
High Proton Conductivity ◽  
Inorganic Hybrid ◽  
High Proton ◽  
Lead Halide

Differences in electronegativity and hydrophilicity of halogens result in various proton conduction and photoluminescence properties in [PbX2(OOCMMIm)].

Robust multifunctional Zr-based metal–organic polyhedra for high proton conductivity and selective CO2 capture

2018 ◽  
Vol 6 (17) ◽  
pp. 7724-7730 ◽  
Author(s):  
Wen-Hao Xing ◽  
Hai-Yang Li ◽  
Xi-Yan Dong ◽  
Shuang-Quan Zang
Keyword(s):  
Hydrogen Bonding ◽  
Proton Conductivity ◽  
Co2 Capture ◽  
Proton Conduction ◽  
High Proton Conductivity ◽  
High Proton ◽  
Metal Organic ◽  
Hydrogen Bonding Networks

A new stable Zr-based MOP is successfully constructed. Unique cavity and 2D hydrogen-bonding networks endow the MOP with highly selective CO2 capture and excellent proton conduction.

Inorganic open framework based on lanthanide ions and polyoxometalates with high proton conductivity

2018 ◽  
Vol 5 (5) ◽  
pp. 1213-1217 ◽  
Author(s):  
Jia-Xuan Wang ◽  
Yi-Di Wang ◽  
Mei-Jie Wei ◽  
Hua-Qiao Tan ◽  
Yong-Hui Wang ◽  
...  
Keyword(s):  
Fuel Cell ◽  
Proton Conductivity ◽  
Cost Effective ◽  
Lanthanide Ions ◽  
Water Stability ◽  
High Proton Conductivity ◽  
Open Framework ◽  
Cell Technology ◽  
High Proton ◽  
Conducting Materials

The development of new proton-conducting materials that are cost effective and have high proton conductivity and water stability is very important in fuel cell technology.

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