Excellent photocatalytic degradation and disinfection performance of a novel bifunctional Ag@AgSCN nanostructure with exposed {−112} facets

2018 ◽  
Vol 42 (14) ◽  
pp. 11811-11818 ◽  
Author(s):  
Xinfu Zhao ◽  
Xibin Yi ◽  
Shuo Tian ◽  
Jian Zhang

A novel bifunctional Ag@AgSCN nanostructure with excellent photocatalytic degradation and antimicrobial performance has been successfully prepared by a simple precipitation method.

2021 ◽  
Author(s):  
Balamurugan Arumugam ◽  
Balamurugan Muthukutty ◽  
Shen-Ming Chen ◽  
Baishnisha Amanulla ◽  
Sayee Kannan Ramaraj

Sustainable one-pot precipitation method was applied for synthesizing strontium phosphate nanoparticles (SrPO NPs) and utilized as effective charge separation photocatalyst for degradation of oncogenic napthylamine derivative (Congo red). Significant photocatalytic...


2021 ◽  
Vol 02 (01) ◽  
Author(s):  
Mohamad Alif Hakimi Hamdan ◽  
◽  
Nur Hanis Hayati Hairom ◽  
Nurhafisza Zaiton ◽  
Zawati Harun ◽  
...  

Thiophene is one of the sulfur compounds in the petroleum fraction that can be harmful to living things and lead to a critical effect on the ecosystem. Photocatalytic degradation is one of the promising methods in treating wastewater as it can mineralization of pollutants into carbon dioxide and water. Other than that, this method is non-toxic and relatively low cost. The production of hydroxyl radicals playing a vital role in the degradation of organic pollutants. It has been claimed that the usage of zinc oxide (ZnO) nanoparticles could give an excellent degradation process as this photocatalyst have high photosensitivity, low cost and chemically stable. However, the preparation method of ZnO nanoparticles will affect the agglomeration, particle size, shape and morphology of particles and lead to influence the photocatalytic activity in degrading thiophene. Therefore, this study focused on the effectiveness of ZnO nanoparticles in the presence of fibrous nanosilica (KCC-1) and polyethylene glycol (PEG) as the capping agent to degrade synthetic thiophene. ZnO/KCC-1 had been synthesized via the precipitation method and characterized by using Fourier Transform Infrared (FTIR). The chemical bond and nature of the photocatalyst from the FTIR results proved that the synthesis process to produce the ZnO/KCC-1 was succeed. The large surface area of KCC-1 increases the effectiveness of ZnO which is supported by the experimental data. Accordingly, the optimum condition for photocatalytic degradation of thiophene is under pH 7 by using ZnO/KCC-1 as photocatalyst. Hence, it is believed that this research could be implemented to remove the thiophene in petroleum fraction from the actual industrial effluents and this can preserve nature in the future.


2021 ◽  
Author(s):  
EASWARAN G ◽  
VIJAYAN M ◽  
SIVAKUMAR K

Abstract In this report, the biomass derived silicon dioxide (SiO2) nanoparticles composite with titanium dioxide (TiO2) semiconductors used as efficient photocatalyst for degradation of Rhodamine B (RhB) dye molecules under UV-visible light irradiation is proclaimed. At first SiO2 derived from Arundo donax L. ash and TiO2 synthesized using titanium (IV) isopropoxide by co-precipitation method and then their different compositions prepared by wet impregnation method were exampled to various optical and atomic level fundamental studies. The amorphous and crystalline nature of SiO2 and TiO2 ratify from XRD and here it is found that the crystalline nature decreased in their compositions as compared to TiO2. 293 nm UV photons harvesting SiO2 observed which could be due to more impurity states presence on surface is further accomplished red shift after composition with TiO2 lead to moving photons harvesting nature towards visible region. The band gap increases in SiO2/TiO2 composites as for TiO2 composition is rapport well with the aforementioned redshift value. Out of all samples the low recombination rate is procured in 50 wt% SiO2/50 wt% TiO2 composite sample. The separated ~ 100–200 nm sized TiO2 nanoparticle and aggregated tiny SiO2 nanoparticles availability in composite sample is authentically substantiated from electron microscopic studies. The presence of Si, O and Ti elements in composite samples probed by XPS. Following the fundamental studies, the photocatalytic degradation ability of the as-prepared samples has been scrutinized against the degradation of Rh B dye in which the pronounced photocatalytic degradation efficiency 93.7% is successfully achieved on 50 wt% SiO2/50 wt% TiO2 nanocomposite photocatalyst.


2015 ◽  
Vol 11 (9) ◽  
pp. 3950-3958 ◽  
Author(s):  
Chandrakant Vedu Nandre ◽  
C.P. Sawant

In the present study photocatalytic degradation of hazardous water soluble alizarin red dye by using Fe-Co nanoparticles  has been investigated. Fe-Co nanoparticles was synthesized by chemical co-precipitation method and characterized by TEM, SEM, EDAX and XRD. The photocatalytic degradation have been studied with the help of variety of parameters such as catalytic dose, dye concentration, pH, contact time and most important chemical oxygen demand. It was observed that The photocatalytic degradation of alizarin red dye by using Fe-Co nanoparticles was an effective ,economic, ecofriendly and faster mode of removing dye from an aqueous solution. The optimum condition for the degradation of the dye was 50 mg/L,pH 8.0, catalyst dose 60 mg/L and contact time 60 minutes. The kinetic studies also have been studied.


RSC Advances ◽  
2019 ◽  
Vol 9 (13) ◽  
pp. 7338-7348 ◽  
Author(s):  
Yajun Zheng ◽  
Liyun Cao ◽  
Gaoxuan Xing ◽  
Zongquan Bai ◽  
Jianfeng Huang ◽  
...  

Flower-like MgO microparticles with excellent photocatalytic performance in degradation of various organic dyes were synthesized by a facile precipitation method via the reaction between Mg2+ and CO32− at 70 °C.


RSC Advances ◽  
2017 ◽  
Vol 7 (42) ◽  
pp. 26179-26184 ◽  
Author(s):  
Yanyan Hao ◽  
Liyun Zhang ◽  
Ying Zhang ◽  
Lin Zhao ◽  
Bingsen Zhang

Pearl necklace-like ZnO–ZnWO4 heterojunctions with enhanced photocatalytic degradation of Rhodamine B were successfully synthesized by precipitation method followed by calcination.


2021 ◽  
Author(s):  
Liang Huang ◽  
Xianghui Jin ◽  
xumei Tao ◽  
Chen Yang ◽  
Yuanyuan Han

Abstract In this paper, NiAlCe hydrotalcite was prepared by co-precipitation method and hydrothermal method in different volume fractions of ethylene glycol-water mixed solvent and polyethylene glycol-water mixed solvent, and the effect of photocatalytic degradation of methyl orange under ultraviolet light was studied. Samples were characterized by XRD, XPS, UV-Vis and FT-IR in order to find the reasons for the improvement of photocatalytic performance under co-solvent system. NiAlCe-10%EG(h) and NiAlCe-15%PEG(h) had smaller particle size, which was beneficial to photocatalytic performance. The degradation rate of methyl orange could reach up to 100% in 42 min using NiAlCe hydrotalcite with 10% volume fraction of EG and in 48 min using NiAlCe hydrotalcite with 15% volume fraction of PEG. The photocatalytic effect of NiAlCe hydrotalcite samples prepared by hydrothermal method were better than that prepared by co-precipitation method. This provided a new type of catalyst for the degradation of dyes: preparing with ethylene glycol-water mixed solvent.


Sign in / Sign up

Export Citation Format

Share Document