Highly dispersed Mo-doped graphite carbon nitride: potential application as oxidation catalyst with hydrogen peroxide

2018 ◽  
Vol 42 (8) ◽  
pp. 5720-5727 ◽  
Author(s):  
Diogo A. F. Gonçalves ◽  
Raquel P. R. Alvim ◽  
Hudson A. Bicalho ◽  
Anderson M. Peres ◽  
Ildefonso Binatti ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Potential Application ◽  
Carbon Nitride ◽  
High Efficiency ◽  
Oxidation Catalyst ◽  
Organic Substrates ◽  
Highly Dispersed

A novel Mo-doped g-C3N4 catalyst exhibits high efficiency for selective oxidation of organic substrates with H2O2 or TBHP.

scholarly journals Chemiluminescent Nanomicelles for Imaging Hydrogen Peroxide and Self-Therapy in Photodynamic Therapy

2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
Rui Chen ◽  
Luzhong Zhang ◽  
Jian Gao ◽  
Wei Wu ◽  
Yong Hu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Photodynamic Therapy ◽  
Potential Application ◽  
Normal Tissue ◽  
Tumor Tissue ◽  
High Efficiency ◽  
Fluorescent Dyes ◽  
Laser Light ◽  
High Sensitivity ◽  
Signal Molecule

Hydrogen peroxide is a signal molecule of the tumor, and its overproduction makes a higher concentration in tumor tissue compared to normal tissue. Based on the fact that peroxalates can make chemiluminescence with a high efficiency in the presence of hydrogen peroxide, we developed nanomicelles composed of peroxalate ester oligomers and fluorescent dyes, called peroxalate nanomicelles (POMs), which could image hydrogen peroxide with high sensitivity and stability. The potential application of the POMs in photodynamic therapy (PDT) for cancer was also investigated. It was found that the PDT-drug-loaded POMs were sensitive to hydrogen peroxide, and the PDT drug could be stimulated by the chemiluminescence from the reaction between POMs and hydrogen peroxide, which carried on a self-therapy of the tumor without the additional laser light resource.

Interlayer confinement synthesis of Ir nanodots/dual carbon as an electrocatalyst for overall water splitting

2020 ◽  
Author(s):  
Yaru Li ◽  
Yu-Quan Zhu ◽  
Weili Xin ◽  
Song Hong ◽  
Xiaoying Zhao ◽  
...  
Keyword(s):  
Water Splitting ◽  
Noble Metal ◽  
High Efficiency ◽  
Overall Water Splitting ◽  
Highly Dispersed

Rationally designing low-content and high-efficiency noble metal nanodots offers opportunities to enhance electrocatalytic performances for water splitting. However, the preparation of highly dispersed nanodots electrocatalysts remains a challenge. Herein, we...

Carbon-nitride-based micromotor driven by chromate-hydrogen peroxide redox system: Application for removal of sulfamethaxazole

2021 ◽  
Vol 597 ◽  
pp. 94-103
Author(s):  
Manoj P. Rayaroth ◽  
Dasom Oh ◽  
Chung-Seop Lee ◽  
Nitee Kumari ◽  
In Su Lee ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
System Application ◽  
Carbon Nitride ◽  
Redox System

scholarly journals Kinetic resolution of indolines by asymmetric hydroxylamine formation

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Gang Wang ◽  
Ran Lu ◽  
Chuangchuang He ◽  
Lei Liu
Keyword(s):  
Hydrogen Peroxide ◽  
Chemical Synthesis ◽  
Late Stage ◽  
Kinetic Resolution ◽  
High Efficiency ◽  
Bond Formation ◽  
Bioactive Molecules ◽  
Environmentally Benign ◽  
Secondary Amines

AbstractCatalytic kinetic resolution of amines represents a longstanding challenge in chemical synthesis. Here, we described a kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation. The economic and practical titanium-catalyzed asymmetric oxygenation with environmentally benign hydrogen peroxide as oxidant is applicable to a range of racemic indolines with multiple stereocenters and diverse substituent patterns in high efficiency with efficient chemoselectivity and enantio-discrimination. Late-stage asymmetric oxygenation of bioactive molecules that are otherwise difficult to synthesize was also explored.

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

A covalently cross-linked reduced functionalized graphene oxide/polyurethane composite based on Diels–Alder chemistry and its potential application in healable flexible electronics

2017 ◽  
Vol 5 (1) ◽  
pp. 220-228 ◽  
Author(s):  
Jinhui Li ◽  
Guoping Zhang ◽  
Rong Sun ◽  
Ching-Ping Wong
Keyword(s):  
Graphene Oxide ◽  
Flexible Electronics ◽  
Potential Application ◽  
High Efficiency ◽  
Diels Alder ◽  
Functionalized Graphene ◽  
Functionalized Graphene Oxide ◽  
Polyurethane Composite

A novel composite of reduced functionalized graphene oxide/polyurethane based on Diels–Alder chemistry was developed which could be healed microwaves with high efficiency and applied in healable flexible electronics.

Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide

2021 ◽  
Vol 4 (5) ◽  
pp. 374-384 ◽  
Author(s):  
Zhenyuan Teng ◽  
Qitao Zhang ◽  
Hongbin Yang ◽  
Kosaku Kato ◽  
Wenjuan Yang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Carbon Nitride ◽  
Artificial Photosynthesis

Janus amphiphilic carbon nanotubes as Pickering interfacial catalysts for the treatment of oily wastewater by selective oxidation with hydrogen peroxide

2020 ◽  
Vol 356 ◽  
pp. 205-215 ◽  
Author(s):  
Jose L. Diaz de Tuesta ◽  
Bruno F. Machado ◽  
Philippe Serp ◽  
Adrián M. T. Silva ◽  
Joaquim L. Faria ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Hydrogen Peroxide ◽  
Selective Oxidation ◽  
Oily Wastewater
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