Unexpected ionic transport behavior in hydrophobic and uncharged conical nanopores

2018 ◽  
Vol 210 ◽  
pp. 69-85 ◽  
Author(s):  
Sebastien Balme ◽  
Fabien Picaud ◽  
Mathilde Lepoitevin ◽  
Mikhael Bechelany ◽  
Emmanuel Balanzat ◽  
...  
Keyword(s):  
Ionic Transport ◽  
Liquid Interface ◽  
Transport Behavior ◽  
Conical Nanopores ◽  
Transport Behaviour ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Predominant Effect

We investigated ionic transport behavior in the case of uncharged conical nanopores. We observed unexpected ionic transport behaviour, which is attributed to a predominant effect of slippage due to water organization at the solid/liquid interface.

Competitive transport of cadmium and lead through a natural porous medium: influence of the solid/liquid interface processes

2003 ◽  
Vol 48 (3) ◽  
pp. 9-16 ◽  
Author(s):  
A. Bianchi ◽  
M. Petrangeli Papini ◽  
A. Corsi ◽  
P. Behra ◽  
M. Beccari
Keyword(s):  
Liquid Interface ◽  
Equilibrium Adsorption ◽  
Adsorption Model ◽  
Adsorption Sites ◽  
Advection Dispersion ◽  
Transport Behaviour ◽  
Cadmium And Lead ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Medium Influence

Contaminated groundwater typically contains different metal contaminants which may compete with each other for the same adsorption sites. Understanding the fate of these micro-pollutants is of primary importance for the assessment of the risk associated with their dispersion in the environment and for the evaluation of the most appropriate remediation technology. In this regard, column techniques can be considered as useful tools both to perform transport experiments and to obtain equilibrium adsorption data without any perturbation of the actual solid/liquid interface. Cd and Pb monocomponent step column experiments were used to obtain adsorption isotherms on a natural aquifer material. A General Composite approach was used to define the equilibrium adsorption model characterized by two types of sites (ion-exchange and surface complexation sites). Coupling the adsorption model with the Advection-Dispersion equation (by IMPACT code) allowed us to well represent the monocomponent step experiments. The model was successfully used to predict the competitive Cd and Pb transport behaviour. Cd peaks of concentration due to Pb competition were experimentally observed and simulated by the model. This behaviour can be described only by an accurate modelling of the interaction and cannot be predicted by simple isotherms (such as Langmuir or Freundlich type).

Observation of Femtosecond Acoustic Anomaly in a Solid Liquid Interface

2020 ◽  
Vol 124 (5) ◽  
pp. 2987-2993
Author(s):  
Chi-Kuang Sun ◽  
Yi-Ting Yao ◽  
Chih-Chiang Shen ◽  
Mu-Han Ho ◽  
Tien-Chang Lu ◽  
...  
Keyword(s):  
Liquid Interface ◽  
Acoustic Anomaly ◽  
Solid Liquid Interface ◽  
Solid Liquid

An Organodiselenide Containing Electrolyte Enables Sulfurized Polyacrylonitrile Cathodes with Fast Redox Kinetics in Li-S batteries

2021 ◽  
Author(s):  
Wei Zhang ◽  
Qiang Wu ◽  
Ziqi Zeng ◽  
Chuang Yu ◽  
Shijie Cheng ◽  
...  
Keyword(s):  
Liquid Interface ◽  
Electrolyte Additive ◽  
Redox Kinetics ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Kinetics Of

A soluble organoselenide compound, phenyl diselenide (PDSe), is employed as a soluble electrolyte additive to enhance the kinetics of sulfurized polyacrylonitrile cathode, in which radical exchange in the solid-liquid interface...

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