Influence of alcoholic solvent and acetate anion coordination mode variations on structures and magnetic properties of heterometallic Zn2Dy2 tetranuclear clusters

2018 ◽  
Vol 47 (46) ◽  
pp. 16616-16626 ◽  
Author(s):  
Hongshan Ke ◽  
Wen Wei ◽  
Yi-Quan Zhang ◽  
Jun Zhang ◽  
Gang Xie ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Mode ◽  
Acetate Anion ◽  
Anion Coordination ◽  
Tetranuclear Clusters

We clarify that slight modifications of the synthetic conditions generate two Zn2Dy2 clusters with acetate anion coordination mode variation and different magnetic behaviors.

Anion coordination selective [Mn3] and [Mn4] assemblies: synthesis, structural diversity, magnetic properties and catechol oxidase activity

2015 ◽  
Vol 44 (26) ◽  
pp. 11741-11754 ◽  
Author(s):  
Moumita Pait ◽  
Michael Shatruk ◽  
Debashis Ray
Keyword(s):  
Magnetic Properties ◽  
Magnetic Property ◽  
Schiff Base ◽  
Schiff Base Ligand ◽  
Structural Diversity ◽  
Manganese Complexes ◽  
Catechol Oxidase ◽  
Oxidation Study ◽  
Anion Coordination ◽  
Catechol Oxidation

The present manuscript reports the detail synthesis, characterization, magnetic property and catechol oxidation study of a family of mixed valent (MnIIMnIII) and trivalent (MnIII) manganese complexes from a Schiff base ligand.

Tetranuclear Clusters Containing a CrIII-Doped MnIII4O2Core: Syntheses, Structures, and Magnetic Properties

2008 ◽  
Vol 47 (11) ◽  
pp. 4536-4544 ◽  
Author(s):  
Yun-Sheng Ma ◽  
Yi-Zhi Li ◽  
You Song ◽  
Li-Min Zheng
Keyword(s):  
Magnetic Properties ◽  
Tetranuclear Clusters

Anion induced diversification from heptanuclear to tetranuclear clusters: Syntheses, structures and magnetic properties

2011 ◽  
Vol 40 (43) ◽  
pp. 11402 ◽  
Author(s):  
Shu-Hua Zhang ◽  
Lu-Fang Ma ◽  
Hua-Hong Zou ◽  
Yin Guang Wang ◽  
Hong Liang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Tetranuclear Clusters

scholarly journals Synthesis, Crystal Structures, Electronic Spectra, and Magnetic Properties of Thiolato-Bridged Trinuclear Cobalt(II) Complexes with N, N, S-Tridentate Thiolate Ligands

2021 ◽  
Vol 3 (1) ◽  
pp. 0210102
Author(s):  
Masahiro Mikuriya ◽  
Atsushi Fujita ◽  
Takanori Kotera ◽  
Daisuke Yoshioka ◽  
Hiroshi Sakiyama ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Electronic Spectra ◽  
Coordination Mode ◽  
Linear Arrangement ◽  
X Ray ◽  
X Ray Crystallography ◽  
Thiolate Ligands ◽  
Trinuclear Complexes ◽  
I 11

New trinuclear CoII complexes, [{Co(apaet)2}2Co]X2 (apaet– = 2-[(3-aminopropyl)amino]ethanethiolato; X = SCN (1), ClO4 (2), NO3 (3), Cl (4), Br (5), I (6)) and [{Co(apampt)2}2Co]X2 (apampt– = 1-[(3-aminopropyl)amino]-2-methylpropane-2-thiolato; X = NO3(7), ClO4 (8), Cl (9), Br (10), I (11)), and mononuclear CoIII complexes, [Co(apaet)2]X (X = ClO4 (12), NO3 (13)), were synthesized. Single-crystal X-ray crystallography of 1 and 7 confirmed that the trinuclear complexes have a linear arrangement of octahedral CoIIS2N4-tetrahedral CoIIS4-octahedral CoIIS2N4 chromophores where two thiolate ligands are coordinated to each terminal Co atom in a mer coordination mode and the two thiolato S atoms are further bound to the central Co atom, which is consistent with the electronic spectra and antiferromagnetic properties

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