Synthesis, structural characterizations, spectroscopic and magnetic properties of MnII and MnIII complexes with an unprecedented bridging coordination mode of 2-salicylichydrazono-1,3-dithiolane ligand

Polyhedron ◽  
2011 ◽  
Vol 30 (11) ◽  
pp. 1774-1778 ◽  
Author(s):  
Chahra Bouchameni ◽  
Chahrazed Beghidja ◽  
Adel Beghidja ◽  
Pierre Rabu ◽  
Richard Welter
2018 ◽  
Vol 47 (46) ◽  
pp. 16616-16626 ◽  
Author(s):  
Hongshan Ke ◽  
Wen Wei ◽  
Yi-Quan Zhang ◽  
Jun Zhang ◽  
Gang Xie ◽  
...  

We clarify that slight modifications of the synthetic conditions generate two Zn2Dy2 clusters with acetate anion coordination mode variation and different magnetic behaviors.


2016 ◽  
Vol 68 ◽  
pp. 80-84 ◽  
Author(s):  
Zouaoui Setifi ◽  
Abderazzak Addala ◽  
Jun Tao ◽  
Nanthawat Wannarit ◽  
Christopher Glidewell ◽  
...  

2017 ◽  
Vol 130 ◽  
pp. 161-164 ◽  
Author(s):  
R.A.M. Gotardo ◽  
E.F.R. Silva ◽  
D.Z. Montanher ◽  
G.M. Santos ◽  
K.L. Silva ◽  
...  

2021 ◽  
Vol 3 (1) ◽  
pp. 0210102
Author(s):  
Masahiro Mikuriya ◽  
Atsushi Fujita ◽  
Takanori Kotera ◽  
Daisuke Yoshioka ◽  
Hiroshi Sakiyama ◽  
...  

New trinuclear CoII complexes, [{Co(apaet)2}2Co]X2 (apaet– = 2-[(3-aminopropyl)amino]ethanethiolato; X = SCN (1), ClO4 (2), NO3 (3), Cl (4), Br (5), I (6)) and [{Co(apampt)2}2Co]X2 (apampt– = 1-[(3-aminopropyl)amino]-2-methylpropane-2-thiolato; X = NO3(7), ClO4 (8), Cl (9), Br (10), I (11)), and mononuclear CoIII complexes, [Co(apaet)2]X (X = ClO4 (12), NO3 (13)), were synthesized. Single-crystal X-ray crystallography of 1 and 7 confirmed that the trinuclear complexes have a linear arrangement of octahedral CoIIS2N4-tetrahedral CoIIS4-octahedral CoIIS2N4 chromophores where two thiolate ligands are coordinated to each terminal Co atom in a mer coordination mode and the two thiolato S atoms are further bound to the central Co atom, which is consistent with the electronic spectra and antiferromagnetic properties


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