Double layer zinc–UDP coordination polymers: structure and properties

2018 ◽  
Vol 47 (40) ◽  
pp. 14174-14178
Author(s):  
Qi-ming Qiu ◽  
Leilei Gu ◽  
Hongwei Ma ◽  
Li Yan ◽  
Minghua Liu ◽  
...  

Double layer Zn–UDP coordination polymers with potentially open sites can be used for heterogeneous fluorescent sensors of amino acids.

2018 ◽  
Vol 6 (46) ◽  
pp. 12623-12630 ◽  
Author(s):  
Xiu-Du Zhang ◽  
Ji-Ai Hua ◽  
Jin-Han Guo ◽  
Yue Zhao ◽  
Wei-Yin Sun

Three novel coordination polymers have been synthesized based on Cd(ii) and 2-(4-((E)-2-(pyridine-2-yl)vinyl)styryl)pyridine by employing different carboxylic acids as auxiliary ligands. All of them can function as fluorescent sensors for TNP with high sensitivity, selectivity and recyclability.


Molecules ◽  
2019 ◽  
Vol 24 (18) ◽  
pp. 3252 ◽  
Author(s):  
Paula Ossowicz ◽  
Joanna Klebeko ◽  
Barbara Roman ◽  
Ewa Janus ◽  
Zbigniew Rozwadowski

Ionic liquids based on different l-amino acids (glycine, l-valine, l-leucine, l-isoleucine, l-histidine, l-methionine, l-tyrosine, l-tryptophan, l-arginine, and l-threonine) and different cations (tetrabutylammonium (TBA), tributylmethylammonium (tBMA), didecyldimethylammonium (DDA), (2-hydroxyethyl)trimethylammonium (choline) (Chol), alkyl(C12-C14) dimethylbenzylammonium (benzalkonium) (BA), dodecyltrimethylammonium (DDTMA), hexadecyltrimethylammonium (HDTMA), octadecyltrimethylammonium (ODTMA) and 1-ethyl-3-methylimidazolium (EMIM)) have been synthesized and characterized by NMR and FTIR. Viscosity, specific rotation, surface activity, thermal stability (TG), and phase transformations (DSC) have been determined and compared with available data. Furthermore, benzalkonium, didecyldimethylammonium, dodecyltrimethylammonium, hexadecyltrimethylammonium, and octadecyltrimethylammonium amino acid ionic liquids have been shown to exhibit surface activity. The dissolution of cellulose in amino acid ionic liquids (AAILs) composed of various cations was also investigated. Cellulose was only dissolved in EMIM salts of amino acids. In particular, the influence of the cation type on selected physicochemical and spectroscopic properties were discussed. The article is a mini review on amino acid ionic liquids.


2013 ◽  
Vol 69 (a1) ◽  
pp. s158-s158
Author(s):  
Simona Galli ◽  
Angelo Maspero ◽  
Carlotta Giacobbe ◽  
Norberto Masciocchi ◽  
Angiolina Comotti

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