scholarly journals Structure and properties of fluorinated and non‐fluorinated Ba‐coordination polymers – the position of fluorine makes the difference

2021 ◽  
Author(s):  
Steffen Zänker ◽  
Gudrun Scholz ◽  
Wenlei Xu ◽  
Nicola Pinna ◽  
Franziska Emmerling ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structure And Properties ◽  
The Difference

scholarly journals Isotypic one-dimensional coordination polymers:catena-poly[[dichloridocadmium]-μ-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ2N5:N6] andcatena-poly[[dichloridomercury(II)]-μ-5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylato-κ2N5:N6]

2016 ◽  
Vol 72 (8) ◽  
pp. 1214-1218 ◽  
Author(s):  
Montserrat Alfonso ◽  
Helen Stoeckli-Evans
Keyword(s):  
Hydrogen Bonds ◽  
Metal Ions ◽  
Coordination Polymers ◽  
Rotation Axis ◽  
Dimethyl Ester ◽  
Polymer Chains ◽  
Coordination Geometry ◽  
One Dimensional ◽  
The Difference ◽  
Title One

The isotypic title one-dimensional coordination polymers, [CdCl2(C18H14N4O4)]n, (I), and [HgCl2(C18H14N4O4)]n, (II), are, respectively, the cadmium(II) and mercury(II) complexes of the dimethyl ester of 5,6-bis(pyridin-2-yl)pyrazine-2,3-dicarboxylic acid. In both compounds, the metal ions are located on a twofold rotation axis and a second such axis bisects the Car—Carbonds of the pyrazine ring. The metal ions are bridged by binding to the N atoms of the two pyridine rings and have anMN2Cl2bisphenoidal coordination geometry. The metal–Npyrazinedistances are much longer than the metal–Npyridinedistances; the difference is 0.389 (2) Å for the Cd—N bonds but only 0.286 (5) Å for the Hg—N bond lengths. In the crystals of both compounds, the polymer chains are linkedviapairs of C—H...Cl hydrogen bonds, forming corrugated slabs parallel to theacplane.

Double layer zinc–UDP coordination polymers: structure and properties

2018 ◽  
Vol 47 (40) ◽  
pp. 14174-14178
Author(s):  
Qi-ming Qiu ◽  
Leilei Gu ◽  
Hongwei Ma ◽  
Li Yan ◽  
Minghua Liu ◽  
...  
Keyword(s):  
Amino Acids ◽  
Double Layer ◽  
Coordination Polymers ◽  
Fluorescent Sensors ◽  
Structure And Properties

Double layer Zn–UDP coordination polymers with potentially open sites can be used for heterogeneous fluorescent sensors of amino acids.

scholarly journals Structure and properties of robust bipyrazolato-based coordination polymers

2013 ◽  
Vol 69 (a1) ◽  
pp. s158-s158
Author(s):  
Simona Galli ◽  
Angelo Maspero ◽  
Carlotta Giacobbe ◽  
Norberto Masciocchi ◽  
Angiolina Comotti
Keyword(s):  
Coordination Polymers ◽  
Structure And Properties

Synthesis, Structure, and Visible Phosphorescence Emission of Novel CuI Coordination Polymers Based on 4,4′-Bis(3-pyridyl)-2,2′-bis(hydroxylmethyl) Biphenyl

2015 ◽  
Vol 68 (2) ◽  
pp. 307 ◽  
Author(s):  
Guo-Xia Jin ◽  
Jian-Ping Ma ◽  
Chuan-Zhi Sun ◽  
Yu-Bin Dong
Keyword(s):  
Coordination Polymers ◽  
Density Functional ◽  
Room Temperature ◽  
Emission Spectra ◽  
Density Functional Theory Calculations ◽  
X Ray Diffraction ◽  
Ligand Charge Transfer ◽  
Yellow Orange ◽  
The Difference ◽  
1D Chains

Four new CuI coordination polymers, [(CuCl)L]n (1), {[(CuCl)2L2]·(H2O)}n (2), [(CuBr)L]n (3), and {[(CuBr)2L2]·(H2O)}n (4), were obtained from a new ligand 4,4′-bis(3-pyridyl)-2,2′-bis(hydroxylmethyl) biphenyl (L) and characterized by single-crystal X-ray diffraction. In 1 and 3, the rhombic [Cu2(μ-X)2] units are connected to each other by the bidentate linkers to form an infinite 1D double chain (X = Cl, Br). Such 1D chains are arranged into a 2D sheet through inter-chain π···π interactions. In 2 and 4, there are similar 1D double chains, but different inter-chain arrangement. Such 1D chains are connected into a 2D layer and further arranged in an ABAB fashion through O–H···X hydrogen bonds. The emission spectra and lifetimes in the microsecond range were measured at room temperature and at 77 K. Complexes 1 and 3 exhibit strong orange and yellow–orange emission in the solid state at room temperature, and were assigned to X-and M-to-ligand charge transfer excited states based on density functional theory calculations. The emission property of 2 and 4 was distinctly different from that of 1 and 3, probably due to the difference in coordination environments of the CuI centres as well as the dissimilar intermolecular arrangement.

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