A new series of Co, Ni, Zn, and Cd metal–organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties

2018 ◽  
Vol 47 (22) ◽  
pp. 7431-7444 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Yan Cai ◽  
Zi-Yue Qian ◽  
Min Wen ◽  
Zi-Fa Shi ◽  
...  
Keyword(s):  
Building Block ◽  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Main Building ◽  
Metal Organic

Twelve new Zn(ii), Ni(ii), Co(ii), and Cd(ii) coordination compounds with diverse dimensionalities were assembled using 3′-nitro-biphenyl-2,4,4′-tricarboxylic acid as a main building block.

H-Bonded and metal(ii)–organic architectures assembled from an unexplored aromatic tricarboxylic acid: structural variety and functional properties

2020 ◽  
Vol 49 (21) ◽  
pp. 7197-7209 ◽  
Author(s):  
Jin-Zhong Gu ◽  
Shi-Mao Wan ◽  
Marina V. Kirillova ◽  
Alexander M. Kirillov
Keyword(s):  
Nicotinic Acid ◽  
Functional Properties ◽  
Building Block ◽  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Structural Variety

2,5-Di(4-carboxylphenyl)nicotinic acid was explored as a novel building block for assembling nine metal(ii) coordination compounds; these were fully characterized and their structural features and functional properties were investigated.

A variety of metal–organic and supramolecular networks constructed from a new flexible multifunctional building block bearing picolinate and terephthalate functionalities: hydrothermal self-assembly, structural features, magnetic and luminescent properties

RSC Advances ◽  
2015 ◽  
Vol 5 (106) ◽  
pp. 87484-87495 ◽  
Author(s):  
Yong-Liang Shao ◽  
Yan-Hui Cui ◽  
Jin-Zhong Gu ◽  
Alexander M. Kirillov ◽  
Jiang Wu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Block ◽  
Coordination Compounds ◽  
Luminescent Properties ◽  
Structural Features ◽  
Metal Organic ◽  
Supramolecular Networks

A novel multifunctional building block was designed and applied for the synthesis of diverse coordination compounds.

Exploring biphenyl-2,4,4′-tricarboxylic acid as a flexible building block for the hydrothermal self-assembly of diverse metal–organic and supramolecular networks

CrystEngComm ◽  
2016 ◽  
Vol 18 (5) ◽  
pp. 765-778 ◽  
Author(s):  
Yong-Liang Shao ◽  
Yan-Hui Cui ◽  
Jin-Zhong Gu ◽  
Jiang Wu ◽  
Ya-Wen Wang ◽  
...  
Keyword(s):  
Thermal Stability ◽  
Magnetic Properties ◽  
Self Assembly ◽  
Building Block ◽  
Coordination Compounds ◽  
Tricarboxylic Acid ◽  
Topological Features ◽  
Metal Organic ◽  
Supramolecular Networks

This contribution reports the hydrothermal self-assembly synthesis, characterization, thermal stability, structural and topological features, and luminescence or magnetic properties of a new series of nine coordination compounds.

Hydrothermal generation, structural versatility and properties of metal(ii)-organic architectures driven by a pyridine-tricarboxylic acid

2019 ◽  
Vol 48 (23) ◽  
pp. 8361-8374 ◽  
Author(s):  
Na Zhao ◽  
Yu Li ◽  
Jin-Zhong Gu ◽  
Marina V. Kirillova ◽  
Alexander M. Kirillov
Keyword(s):  
Coordination Compounds ◽  
Structural Features ◽  
Tricarboxylic Acid ◽  
Photocatalytic Properties ◽  
Structural Versatility

A new series of metal(ii) coordination compounds driven by a pyridine-tricarboxylate block was generated, their structural features, magnetic, luminescent or photocatalytic properties were explored.

Metal–organic architectures driven by a multifunctional 6-aminouracil spacer: structures, noncovalent interactions, and conductivity

CrystEngComm ◽  
2020 ◽  
Vol 22 (4) ◽  
pp. 829-840 ◽  
Author(s):  
Atanu Purkayastha ◽  
Sourab Dhar ◽  
Suvra Prakash Mondal ◽  
Antonio Franconetti ◽  
Antonio Frontera ◽  
...  
Keyword(s):  
Functional Properties ◽  
Coordination Polymers ◽  
Building Block ◽  
Noncovalent Interactions ◽  
Structural Features ◽  
Metal Organic

Three new coordination polymers were assembled from a multifunctional 6-aminouracil building block and their structural features & functional properties were investigated.

Exploring 5-fluoronicotinic acid as a versatile building block for the generation of topologically diverse metal–organic and supramolecular Ni, Co, and Cd networks

RSC Advances ◽  
2015 ◽  
Vol 5 (14) ◽  
pp. 10400-10411 ◽  
Author(s):  
Yan-Hui Cui ◽  
Jiang Wu ◽  
Alexander M. Kirillov ◽  
Jin-Zhong Gu ◽  
Wei Dou
Keyword(s):  
Building Block ◽  
Coordination Compounds ◽  
Metal Organic ◽  
Self Assembled

Five new coordination compounds driven by 5-fluoronicotinic acid were self-assembled and structurally characterized, revealing metal–organic or H-bonded networks with distinct topologies, including rare or unreported examples.

Phase selectivity and tunable photophysical nature of rare earth metal–organic frameworks of EuxY1−x-PTC (H3PTC = 2,4,6-pyridine tricarboxylic acid; x = 0–1)

2020 ◽  
Vol 49 (42) ◽  
pp. 14985-14994
Author(s):  
Xu-Sheng Gao ◽  
Mei-Juan Ding ◽  
Jin Zhang ◽  
Li-Duo Zhao ◽  
Xiao-Ming Ren
Keyword(s):  
Rare Earth ◽  
Solid Solutions ◽  
Rare Earth Metal ◽  
Metal Organic Frameworks ◽  
Earth Metal ◽  
Tricarboxylic Acid ◽  
Excitation Wavelength ◽  
Metal Organic ◽  
Phase Selectivity

All solid solutions (EuxY1−x-PTC, x = 0.013–0.82) are isomorphic to Eu-PTC, but different from Y-PTC, and show phase selectivity as well as excitation wavelength dependent emission.

scholarly journals Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3358
Author(s):  
Sadaf Rauf ◽  
Agata Trzesowska-Kruszynska ◽  
Tomasz Sierański ◽  
Marcin Świątkowski
Keyword(s):  
Coordination Polymer ◽  
Coordination Compounds ◽  
Structural Diversity ◽  
Structural Features ◽  
Mononuclear Complex ◽  
Molar Ratio ◽  
One Dimensional ◽  
1D Coordination Polymer ◽  
Copper Coordination ◽  
Stretching Vibrations

Three new copper coordination compounds derived from 2,2-bis(hydroxymethyl)propionic acid (dmpa) and hexamethylenetetramine (hmta) were obtained and their crystal structures were determined. The stoichiometry of the reagents applied in the syntheses reflects the metal to ligand molar ratio in the formed solid products. Due to the multiple coordination modes of the used ligands, wide structural diversity was achieved among synthesized compounds, i.e., mononuclear [Cu(dmp)2(hmta)2(H2O)] (1), dinuclear [Cu2(dmp)4(hmta)2] (2), and 1D coordination polymer [Cu2(dmp)4(hmta)]n (3). Their supramolecular structures are governed by O—H•••O and O—H•••N hydrogen bonds. The compounds were characterized in terms of absorption (UV-Vis and IR) and thermal properties. The relationships between structural features and properties were discussed in detail. Owing to discrepancies in the coordination mode of a dmp ligand, bidentate chelating in 1, and bidentate bridging in 2 and 3, there is a noticeable change in the position of the bands corresponding to the stretching vibrations of the carboxylate group in the IR spectra. The differences in the structures of the compounds are also reflected in the nature and position of the UV-Vis absorption maxima, which are located at lower wavelengths for 1.

Recent progress in the design and synthesis of zeolite-like metal–organic frameworks (ZMOFs)

2021 ◽  
Author(s):  
Xinyao Liu ◽  
Yunling Liu
Keyword(s):  
Building Block ◽  
High Stability ◽  
Recent Progress ◽  
Metal Organic Frameworks ◽  
Excellent Performance ◽  
Design And Synthesis ◽  
Molecular Building Block ◽  
Secondary Building Units ◽  
Metal Organic

ZMOFs are a subset of MOFs that exhibit zeolite-like topologies. Using molecular building block strategy, many ZMOFs with high stability and excellent performance can be rationally designed and synthesized using different secondary building units.

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