Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination

2018 ◽  
Vol 47 (25) ◽  
pp. 8476-8482 ◽  
Author(s):  
P. R. Nimax ◽  
D. Reimann ◽  
K. Sünkel
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvent Effects ◽  
Supramolecular Isomerism

Recrystallization of Silver pentacyanocyclopentadienide from methanol, ethanol or acetonitrile yields coordination polymers of different dimensionality.

Two-dimensional lanthanide(III) coordination polymers: solvothermal synthesis, crystal structure, and stability

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Runmei Ding ◽  
Zixin He ◽  
Meilin Wang ◽  
Danian Tian ◽  
Peipei Cen
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Analysis Data ◽  
Water Stability ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
X Ray ◽  
Solvothermal Conditions

AbstractBased on 2-(4-pyridyl)-terephthalate (H2pta) and oxalate ligands, two new lanthanide-containing coordination polymers (CPs), [Tb(pta)(C2O4)0.5(H2O)2)]·2H2O (1) and [Sm(pta)(C2O4)0.5(H2O)2)]·2H2O (2), have been synthesized under solvothermal conditions. The structures of both 1 and 2 have been determined by single-crystal X-ray diffraction. Infrared, elemental analysis, powder X-ray diffraction and thermogravimetric analysis data are also presented. The crystals of 1 and 2 exhibit isostructural layer-like networks, crystallizing in the triclinic space group P$‾{1}$. The layers are further stabilized and associated into 3D architectures through hydrogen bonding. Remarkably, the CPs 1 and 2 exhibit excellent water stability and remarkable thermostability with thermal decomposition temperatures of more than 420 °C.

Syntheses, structures and gas sorption properties of two coordination polymers with a unique type of supramolecular isomerism

2015 ◽  
Vol 2 (2) ◽  
pp. 136-140 ◽  
Author(s):  
Xiao-Lin Qi ◽  
Jia-Wen Ye ◽  
Rui-Biao Lin ◽  
Pei-Qin Liao ◽  
Si-Yang Liu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Structural Difference ◽  
Sorption Properties ◽  
Gas Sorption ◽  
Unique Type ◽  
Supramolecular Isomerism ◽  
Porous Properties

Two genuine supramolecular isomers with a unique type of structural difference and completely different porous properties have been synthesized and characterized.

Synthesis, crystal structure and luminescence of Ag(I) coordination polymers based on a new sulfonate functionalized terpyridine derivative ligand

Polyhedron ◽  
2015 ◽  
Vol 91 ◽  
pp. 52-58 ◽  
Author(s):  
Sa-Sa Shen ◽  
Xiaofang Wang ◽  
Huai-Ming Hu ◽  
Fei Yuan ◽  
Fa-Xin Dong ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers

Solvent effects on the assembly of Ni/Na coordination polymers from reactions of [Ni(acac)2(H2O)2] with sodium dicyanamide

CrystEngComm ◽  
2010 ◽  
Vol 12 (5) ◽  
pp. 1610 ◽  
Author(s):  
Xi Chen ◽  
Shan-Bao Qiao ◽  
Dong Liu ◽  
Jian-Ping Lang ◽  
Yong Zhang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Solvent Effects
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