Temperature-Controlled Synthesis of Metal-Organic Coordination Polymers: Crystal Structure, Supramolecular Isomerism, and Porous Property

2009 ◽  
Vol 9 (9) ◽  
pp. 4147-4156 ◽  
Author(s):  
Prakash Kanoo ◽  
Gurunatha K. L. ◽  
Tapas Kumar Maji
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Controlled Synthesis ◽  
Supramolecular Isomerism ◽  
Metal Organic ◽  
Temperature Controlled ◽  
Porous Property

scholarly journals Disappeared supramolecular isomer reappears with perylene guest

IUCrJ ◽  
2020 ◽  
Vol 7 (2) ◽  
pp. 324-330
Author(s):  
In-Hyeok Park ◽  
Atanu Dey ◽  
Kenta Sasaki ◽  
Masaaki Ohba ◽  
Shim Sung Lee ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Guest Molecule ◽  
Metal Organic Frameworks ◽  
Guest Molecules ◽  
Supramolecular Isomerism ◽  
The World ◽  
Different Types ◽  
Metal Organic ◽  
The Disappeared ◽  
Kinetic Form

Among different types of polymorphism, disappearing polymorphism deals with the metastable kinetic form which can not be reproduced after its first isolation. In the world of coordination polymers (CPs) and metal–organic frameworks (MOFs), despite the fact that many types of supramolecular isomerism exist, we are unaware of disappearing supramolecular isomerism akin to disappearing polymorphism. This work reports a MOF with dia topology that could not be reproduced, but subsequent synthesis yielded another supramolecular isomer, a double-pillared-layer MOF. When perylene was added in the same reaction, the disappeared dia MOF reappeared with perylene as a guest in the channels. Interestingly, the photoluminescence of the dia MOF with a perylene guest is dominated by the emission of the guest molecule. The influence of guest molecules on the stabilization of the supramolecular isomers of a MOF opens up a strategy to access MOFs with different structures.

Synthesis and Crystal Structure of Cadmium(II) Metal-Organic Coordination Polymers with Octafluorobiphenyl-4,4'-Dicarboxylate

2021 ◽  
Vol 66 (9) ◽  
pp. 1374-1379
Author(s):  
V. S. Gusarov ◽  
A. M. Cheplakova ◽  
D. G. Samsonenko ◽  
A. S. Vinogradov ◽  
V. P. Fedin
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Synthesis And Crystal Structure ◽  
Metal Organic

Hydrothermal synthesis, crystal structure and photoluminescence of two homochiral zinc(II) coordination polymers

2015 ◽  
Vol 71 (7) ◽  
pp. 618-622 ◽  
Author(s):  
Shao-Ming Ying ◽  
Jing-Jing Ru ◽  
Wu-Kui Luo
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Layer Structure ◽  
Metal Organic Frameworks ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Strong Emission ◽  
X Ray ◽  
Elemental Analyses ◽  
Metal Organic

Metal–organic frameworks (MOFs) have potentially useful applications and an intriguing variety of architectures and topologies. Two homochiral coordination polymers have been synthesized by the hydrothermal method, namely poly[(μ-N-benzyl-L-phenylalaninato-κ4O,O′:O,N)(μ-formato-κ2O:O′)zinc(II)], [Zn(C16H16NO2)(HCOO)]n, (1), and poly[(μ-N-benzyl-L-leucinato-κ4O,O′:O,N)(μ-formato-κ2O:O′)zinc(II)], [Zn(C13H18NO2)(HCOO)]n, (2), and studied by single-crystal X-ray diffraction, elemental analyses, IR spectroscopy and fluorescence spectroscopy. Compounds (1) and (2) each have a two-dimensional layer structure, with the benzyl or isobutyl groups of the ligands directed towards the interlayer interface. Photoluminescence investigations show that both (1) and (2) display a strong emission in the blue region.

Metal–organic frameworks based on octafluorobiphenyl-4,4′-dicarboxylate: synthesis, crystal structure, and surface functionality

2018 ◽  
Vol 47 (10) ◽  
pp. 3283-3297 ◽  
Author(s):  
Anastasia M. Cheplakova ◽  
Konstantin A. Kovalenko ◽  
Denis G. Samsonenko ◽  
Vladimir A. Lazarenko ◽  
Victor N. Khrustalev ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Surface Properties ◽  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Surface Functionality ◽  
Metal Organic

Six Zn coordination polymers have been synthesized and investigated in terms of their surface properties.

Crystal Structure of Metal-Organic Coordination Polymers Based on Potassium and Barium Cations with α-Cyclodextrin

2020 ◽  
Vol 61 (3) ◽  
pp. 431-438
Author(s):  
E. I. Koshevoi ◽  
D. G. Samsonenko ◽  
P. V. Dorovatovskii ◽  
V. A. Lazarenko ◽  
V. P. Fedin
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Structure Of Metal ◽  
Metal Organic
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