Visible light induced efficient hydrogen production through semiconductor–conductor–semiconductor (S–C–S) interfaces formed between g-C3N4 and rGO/Fe2O3 core–shell composites

2018 ◽  
Vol 8 (19) ◽  
pp. 5081-5090 ◽  
Author(s):  
Nithya Thangavel ◽  
Sankeerthana Bellamkonda ◽  
Abraham Daniel Arulraj ◽  
G. Ranga Rao ◽  
Bernaurdshaw Neppolian

The type II heterojunction g-C3N4/rGO/Fe2O3 photocatalyst prepared by hydrothermal and wet impregnation methods for H2 production via water splitting.

2020 ◽  
Vol 44 (36) ◽  
pp. 15439-15445 ◽  
Author(s):  
Liang Xu ◽  
Zongle Ma ◽  
Quan Li ◽  
Tong Chen ◽  
Bojun Peng ◽  
...  

2D layered SiC/C2N type-II heterostructure is an effective photocatalyst for hydrogen production from water splitting by visible light.


2016 ◽  
Vol 4 (2) ◽  
pp. 675-683 ◽  
Author(s):  
Daochuan Jiang ◽  
Zijun Sun ◽  
Hongxing Jia ◽  
Dapeng Lu ◽  
Pingwu Du

Highly efficient, visible-light-induced hydrogen (H2) production via water splitting can be achieved without the help of a cocatalyst by using a noble-metal-free core–shell photocatalyst, in which zinc sulfide (ZnS) nanoparticles are anchored on cadmium sulfide nanorods (CdS NRs).


2020 ◽  
Vol 16 ◽  
Author(s):  
Yuxue Wei ◽  
Honglin Qin ◽  
Jinxin Deng ◽  
Xiaomeng Cheng ◽  
Mengdie Cai ◽  
...  

Introduction: Solar-driven photocatalytic hydrogen production from water splitting is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. In this review, recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. In particular, the factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Background: Photocatalytic hydrogen evolution from water splitting using photocatalyst semiconductors is one of the most promising solutions to satisfy the increasing demands of a rapidly developing society. CdS has emerged as a representative semiconductor photocatalyst due to its suitable band gap and band position. However, the poor stability and rapid charge recombination of CdS restrict its application for hydrogen production. The strategy of using a cocatalyst is typically recognized as an effective approach for improving the activity, stability, and selectivity of photocatalysts. Methods: This review summarizes the recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation. Results: Recent developments in CdS cocatalysts for hydrogen production from water splitting under visible-light irradiation are summarized. The factors affecting the photocatalytic performance and new cocatalyst design, as well as the general classification of cocatalysts, are discussed, which includes a single cocatalyst containing noble-metal cocatalysts, non-noble metals, metal-complex cocatalysts, metal-free cocatalysts, and multi-cocatalysts. Finally, future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are described. Conclusion: The state-of-the-art CdS for producing hydrogen from photocatalytic water splitting under visible light is discussed. The future opportunities and challenges with respect to the optimization and theoretical design of cocatalysts toward the CdS photocatalytic hydrogen evolution are also described.


2017 ◽  
Vol 46 (34) ◽  
pp. 11335-11343 ◽  
Author(s):  
Jiali Lv ◽  
Jinfeng Zhang ◽  
Kai Dai ◽  
Changhao Liang ◽  
Guangping Zhu ◽  
...  

Sustainable photocatalytic hydrogen evolution (PHE) of water splitting has been utilized to solve the serious environmental pollution and energy shortage problems over the last decade.


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