Amide versus amine ligand paradigm in the direct amination of alcohols with Ru-PNP complexes

Dennis Pingen; Jong-Hoo Choi; Henry Allen; George Murray; Prasad Ganji; Piet W. N. M. van Leeuwen; Martin H. G. Prechtl; Dieter Vogt

doi:10.1039/c8cy00869h

Amide versus amine ligand paradigm in the direct amination of alcohols with Ru-PNP complexes

Catalysis Science & Technology ◽

10.1039/c8cy00869h ◽

2018 ◽

Vol 8 (15) ◽

pp. 3969-3976 ◽

Cited By ~ 9

Author(s):

Dennis Pingen ◽

Jong-Hoo Choi ◽

Henry Allen ◽

George Murray ◽

Prasad Ganji ◽

...

Keyword(s):

Ruthenium Complexes ◽

Secondary Amines ◽

Tertiary Amines ◽

Direct Amination ◽

Amine Ligand ◽

Amide Versus

Ruthenium complexes of PNP-ligands bearing secondary amines were found to be inactive in the alcohol amination with NH3, while all complexes of homologous ligands bearing tertiary amines gave active catalysts!

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Reaction of arylmethylenemalonaldehydes with some nucleophiles

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19872699 ◽

1987 ◽

Vol 52 (11) ◽

pp. 2699-2709 ◽

Cited By ~ 3

Author(s):

Dalimil Dvořák ◽

Zdeněk Arnold

Keyword(s):

Inorganic Anions ◽

Secondary Amines ◽

Tertiary Amines ◽

Primary And Secondary Amines ◽

Dipolar Structure

Reaction of arylmethylenemalonaldehydes with tributylphosphine and tertiary amines affords compounds of dipolar structure whereas reaction with primary and secondary amines leads to 1,4-addition products. Salts of nucleophilic inorganic anions add to arylmethylenemalonaldehydes under formation of salts of substituted malonaldehydes.

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Everything you ever wanted to know about primary amines, secondary amines, tertiary amines, diamines, quaternary ammonium chlorides, amine acetates, nitrites, amides, ethoxylated amines, amine oxides, specialty chemicals, fatty acid esters and fatty acids.

Chemical & Engineering News ◽

10.1021/cen-v055n010.ibc ◽

1977 ◽

Vol 55 (10) ◽

pp. ibc

Keyword(s):

Fatty Acids ◽

Fatty Acid ◽

Quaternary Ammonium ◽

Fatty Acid Esters ◽

Secondary Amines ◽

Primary Amines ◽

Tertiary Amines ◽

Amine Oxides ◽

Specialty Chemicals ◽

Acid Esters

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Ruthenium-catalyzed direct amination of alcohols with tertiary amines

Tetrahedron Letters ◽

10.1016/j.tetlet.2011.03.084 ◽

2011 ◽

Vol 52 (21) ◽

pp. 2706-2709 ◽

Cited By ~ 31

Author(s):

Jiaying Luo ◽

Mingyue Wu ◽

Fuhong Xiao ◽

Guojun Deng

Keyword(s):

Tertiary Amines ◽

Direct Amination

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The Chemistry ofN-Substituted Benzotriazoles; Part II.1The Preparation of Tertiary Amines Containing Tertiary-Alkyl Groups from Ketones, Secondary Amines, and Organometallic Reagents

Synthesis ◽

10.1055/s-1989-27156 ◽

1989 ◽

Vol 1989 (01) ◽

pp. 66-69 ◽

Cited By ~ 19

Author(s):

Alan R. Katritzky ◽

Zbigniew Najzarek ◽

Zofia Dega-Szafran

Keyword(s):

Secondary Amines ◽

Tertiary Amines ◽

Organometallic Reagents ◽

Alkyl Groups ◽

Tertiary Alkyl

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ChemInform Abstract:nBu4NI-Catalyzed Direct Amination of Benzoxazoles with Tertiary Amines Using TBHP as Oxidant under Microwave Irradiation.

ChemInform ◽

10.1002/chin.201631161 ◽

2016 ◽

Vol 47 (31) ◽

Author(s):

Jin-Wei Yuan ◽

Ming Jin ◽

Qiu-Yue Yin ◽

Pu Mao ◽

Ling-Bo Qu

Keyword(s):

Microwave Irradiation ◽

Tertiary Amines ◽

Direct Amination

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ChemInform Abstract: Highly Efficient and Eco-Friendly Synthesis of Tertiary Amines by Reductive Alkylation of Aldehydes with Secondary Amines over a Pt Nanowires Catalyst.

ChemInform ◽

10.1002/chin.201606061 ◽

2016 ◽

Vol 47 (6) ◽

pp. no-no

Author(s):

Junjie Wu ◽

Shuanglong Lu ◽

Danhua Ge ◽

Hongwei Gu

Keyword(s):

Secondary Amines ◽

Tertiary Amines ◽

Reductive Alkylation ◽

Highly Efficient ◽

Pt Nanowires

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ChemInform Abstract: Ruthenium-Catalyzed Rearrangements of Azobenzenes. Part 1. The Preparation of l-Phenylbenzimidazoles from Azobenzene Derivates and Tertiary Amines Catalyzed by Ruthenium Complexes.

Chemischer Informationsdienst ◽

10.1002/chin.198611214 ◽

1986 ◽

Vol 17 (11) ◽

Author(s):

A. SPENCER

Keyword(s):

Ruthenium Complexes ◽

Tertiary Amines

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Everything you ever wanted to know about primary amines, secondary amines, tertiary amines, diamines, quaternary ammonium chlorides, amine acetates, nitrites, amides, ethoxylated amines, amine oxides, specialty chemicals, fatty acid esters and fatty acids.

Chemical & Engineering News ◽

10.1021/cen-v054n046.ibc ◽

1976 ◽

Vol 54 (46) ◽

pp. ibc

Keyword(s):

Fatty Acids ◽

Fatty Acid ◽

Quaternary Ammonium ◽

Fatty Acid Esters ◽

Secondary Amines ◽

Primary Amines ◽

Tertiary Amines ◽

Amine Oxides ◽

Specialty Chemicals ◽

Acid Esters

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Determination of tertiary amines after formylation of primary and secondary amines with acetic-formic mixed anhydride

Fresenius Zeitschrift für Analytische Chemie ◽

10.1007/bf00424792 ◽

1970 ◽

Vol 251 (5) ◽

pp. 303-304 ◽

Cited By ~ 2

Author(s):

S. G�r�g ◽

G. Szepesi

Keyword(s):

Secondary Amines ◽

Tertiary Amines ◽

Mixed Anhydride ◽

Primary And Secondary Amines

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A Convenient Synthesis of Tertiary Amines by Alkylation of Secondary Amines with Alkyl Halides in the Presence of Potassium Hydride and Triethylamine.

Chemical and Pharmaceutical Bulletin ◽

10.1248/cpb.43.159 ◽

1995 ◽

Vol 43 (1) ◽

pp. 159-161 ◽

Cited By ~ 22

Author(s):

Kunihiko MOHRI ◽

Kazumi SUZUKI ◽

Masumi USUI ◽

Kimiaki ISOBE ◽

Yoshisuke TSUDA

Keyword(s):

Alkyl Halides ◽

Secondary Amines ◽

Tertiary Amines ◽

Convenient Synthesis ◽

Potassium Hydride

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