Oxidative functionalization of C–H compounds induced by the extremely efficient osmium catalysts (a review)

2018 ◽  
Vol 8 (17) ◽  
pp. 4287-4313 ◽  
Author(s):  
Georgiy B. Shul'pin ◽  
Mikhail M. Vinogradov ◽  
Lidia S. Shul'pina
Keyword(s):  
Hydrogen Peroxide ◽  
Aromatic Hydrocarbons ◽  
Organic Peroxides ◽  
Oxidative Functionalization ◽  
Saturated And Aromatic Hydrocarbons ◽  
Osmium Complexes

In recent years, osmium complexes have found applications not only in thecis-hydroxylation of olefins but also very efficient in the oxygenation of C–H compounds (saturated and aromatic hydrocarbons and alcohols) by hydrogen peroxide as well as organic peroxides.

Decamethylosmocene-catalyzed efficient oxidation of saturated and aromatic hydrocarbons and alcohols with hydrogen peroxide in the presence of pyridine☆

2011 ◽  
Vol 277 (2) ◽  
pp. 164-172 ◽  
Author(s):  
Georgiy B. Shul’pin ◽  
Marina V. Kirillova ◽  
Yuriy N. Kozlov ◽  
Lidia S. Shul’pina ◽  
Alexander R. Kudinov ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Aromatic Hydrocarbons ◽  
Saturated And Aromatic Hydrocarbons

scholarly journals Oxygenation of alkanes with hydrogen peroxide catalysed by osmium complexes

2000 ◽  
pp. 1131-1132 ◽  
Author(s):  
Georgiy B. Shul’pin ◽  
Georg Süss-Fink ◽  
Lidia S. Shul’pina
Keyword(s):  
Hydrogen Peroxide ◽  
Osmium Complexes

Analysis of Acetone Peroxide Premixes for Bleaching and Maturing Flour

1964 ◽  
Vol 47 (2) ◽  
pp. 363-366
Author(s):  
James T Taylor
Keyword(s):  
Hydrogen Peroxide ◽  
Qualitative Method ◽  
Collaborative Study ◽  
Organic Peroxides ◽  
Dilute Sulfuric Acid ◽  
Quantitative Analyses ◽  
Single Determination ◽  
Acetone Peroxide ◽  
Qualitative Analyses

Abstract A quantitative and a qualitative method for the determination of acetone peroxides were subjected to collaborative study. Quantitative analyses are based upon liberation and titration of hydrogen peroxide from acyclic peroxides and hydroperoxides by dilute sulfuric acid and standardized potassium permanganate, respectively. Single determination of 6 samples (varying in per cent levels of peroxide equivalent) each of baking premixes and milling premixes produced very good collaborative results. Qualitative analyses, achieved by comparing infrared spectra of acetone-extracted organic peroxides with acetone-extracted organic peroxides from a reference premix, gave peaks characteristic of the premixes. No interferences were seen from various starch blanks. Both the quantitative and the qualitative methods are recommended for adoption as official, first action.

Sign in / Sign up

Export Citation Format

Share Document