Ten-fold boost of catalytic performance in thiol–yne click reaction enabled by a palladium diketonate complex with a hexafluoroacetylacetonate ligand

2018 ◽  
Vol 8 (12) ◽  
pp. 3073-3080 ◽  
Author(s):  
Dmitry B. Eremin ◽  
Daniil A. Boiko ◽  
Eugenia V. Borkovskaya ◽  
Victor N. Khrustalev ◽  
Victor M. Chernyshev ◽  
...  
Keyword(s):  
Click Reaction ◽  
Catalytic Performance ◽  
Palladium Complexes ◽  
Chelating Ligands

Palladium complexes with fluorinated acetylacetonate chelating ligands were studied as catalysts for alkyne hydrothiolation.

Mixed-ligand platinum and palladium complexes based on dinitrogen chelating ligands and a pyridine bearing the nitronylnitroxide radical

2007 ◽  
Vol 10 (11) ◽  
pp. 1355-1359 ◽  
Author(s):  
Ahsan M. Shemsi ◽  
Bassam El Ali ◽  
Khalil A. Ziq ◽  
Mohamed Morsy ◽  
Tony D. Keene ◽  
...  
Keyword(s):  
Palladium Complexes ◽  
Mixed Ligand ◽  
Chelating Ligands ◽  
Platinum And Palladium Complexes

Defect engineering: an effective tool for enhancing the catalytic performance of copper-MOFs for the click reaction and the A3 coupling

2021 ◽  
Author(s):  
Zhiying Fan ◽  
Zheng Wang ◽  
Mirza Cokoja ◽  
Roland A. Fischer
Keyword(s):  
Click Reaction ◽  
Catalytic Performance ◽  
Basic Site ◽  
Defect Engineering ◽  
A3 Coupling

A series of Cu(i)-enriched and Lewis basic site-containing defect-engineering MOFs was investigated for significantly enhanced catalytic performance in the click reaction and the A3 coupling.

scholarly journals Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions

Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2532 ◽  
Author(s):  
Mahmoud Nasrollahzadeh
Keyword(s):  
Magnetic Nanoparticles ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Palladium Complexes ◽  
Biologically Active ◽  
Coupling Reactions ◽  
Catalytic Application ◽  
Wide Range ◽  
Supported Palladium ◽  
Metal Catalyzed

Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.

Chiral Heterocyclic Ligands. VIII. Syntheses and Complexes of New Chelating Ligands Derived From Camphor

1995 ◽  
Vol 48 (9) ◽  
pp. 1549 ◽  
Author(s):  
AA Watson ◽  
DA House ◽  
PJ Steel
Keyword(s):  
Coordination Chemistry ◽  
Transition Metals ◽  
Crystal Structures ◽  
Palladium Complexes ◽  
Chelating Ligands ◽  
Heterocyclic Ligands ◽  
X Ray

The syntheses of 23 new chelating ligands are described. Most of these ligands are derived from the chiral pyrazole (1) which has been linked to a variety of heterocycles , namely pyridine, pyrimidine, pyridazine, isoxazole , benzimidazole, thiophen and furan. In certain cases the parent achiral analogues have also been prepared. Preliminary studies of the coordination chemistry of these ligands with selected transition metals have been carried out. The X-ray crystal structures of palladium complexes of isoxazole- and thiophen-containing ligands have also been determined.

scholarly journals Recent Developments in the Immobilization of Palladium Complexes on Renewable Polysaccharides for Suzuki–Miyaura Cross-Coupling of Halobenzenes and Phenylboronic Acids

Catalysts ◽  
2020 ◽  
Vol 10 (1) ◽  
pp. 136 ◽  
Author(s):  
Adi Wolfson ◽  
Oshrat Levy-Ontman
Keyword(s):  
Phenylboronic Acid ◽  
Cross Coupling ◽  
Catalytic Performance ◽  
Palladium Complexes ◽  
Polymeric Support ◽  
Reaction Conditions ◽  
Natural Sources ◽  
Recent Developments ◽  
Potential Applicability ◽  
Phenylboronic Acids

Polysaccharides derived from natural sources exhibit unique structures and functional groups, which have recently garnered them increased attention for their potential applicability as supports for metal catalysts. Renewable polysaccharide matrices were employed as supports for palladium complexes, with or without previous modification of the support, and were used in Suzuki cross-coupling of halobenzenes and phenylboronic acid derivatives. In this review, recent developments in the immobilization of palladium-based complexes are reported, including descriptions of the preparation procedures and catalytic activity of each system. In addition, the effects of the nature of the polymeric support and of the reaction conditions on catalytic performance are discussed.

An efficient and controlled synthesis of persulfonylated G1 dendrimers via click reaction

RSC Advances ◽  
2016 ◽  
Vol 6 (62) ◽  
pp. 56952-56962 ◽  
Author(s):  
Shaziya Khanam ◽  
Sunil K. Rai ◽  
Deepshikha Verma ◽  
Ranjana S. Khanna ◽  
Ashish K. Tewari
Keyword(s):  
Room Temperature ◽  
Click Reaction ◽  
Controlled Synthesis ◽  
Chelating Ligands

A controlled synthesis for persulfonylated G1 dendrimers has been standardized at room temperature through click reaction using Cu(PPh3)3Br complex in the presence of tridentate chelating ligands.

High catalytic activities in the norbornene polymerization with neutral palladium complexes containing N4-type tetradentate chelating ligands

2009 ◽  
Vol 362 (14) ◽  
pp. 5097-5102 ◽  
Author(s):  
Dong-Hwan Lee ◽  
Jung Hwan Lee ◽  
Byeong Kwon Park ◽  
Eun Young Kim ◽  
Youngmee Kim ◽  
...  
Keyword(s):  
Palladium Complexes ◽  
Chelating Ligands ◽  
Catalytic Activities ◽  
Norbornene Polymerization
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