scholarly journals Advances in Magnetic Nanoparticles-Supported Palladium Complexes for Coupling Reactions

Molecules ◽  
2018 ◽  
Vol 23 (10) ◽  
pp. 2532 ◽  
Author(s):  
Mahmoud Nasrollahzadeh
Keyword(s):  
Magnetic Nanoparticles ◽  
Heterogeneous Catalysts ◽  
Catalytic Performance ◽  
Palladium Complexes ◽  
Biologically Active ◽  
Coupling Reactions ◽  
Catalytic Application ◽  
Wide Range ◽  
Supported Palladium ◽  
Metal Catalyzed

Carbon‒carbon (C‒C) and carbon‒heteroatom (C‒X) bonds that form via transition-metal-catalyzed processes have been extensively used in the organic synthesis and preparation of natural products and important compounds such as heterocycles, biologically active molecules, and dendrimers. Among the most significant catalysts, magnetic nanoparticles-supported palladium complexes are very effective, versatile, and heterogeneous catalysts for a wide range of C‒C and C‒X coupling reactions due to their reusability, thermal stability, and excellent catalytic performance. In this review, recent advances to develop magnetic nanoparticles supported palladium complexes, including their preparation, characterization, catalytic application, and reusability in the formation of both C‒C and C‒X bonds, by authors such as Sonogashira, Heck, Suzuki‒Miyaura, and Stille, and a few examples concerning N-arylation, S-arylation, and Csp2-P coupling reactions are discussed.

Monodentate Trialkylphosphines: Privileged Ligands in Metal-catalyzed Crosscoupling Reactions

2020 ◽  
Vol 24 (3) ◽  
pp. 231-264 ◽  
Author(s):  
Kevin H. Shaughnessy
Keyword(s):  
Transition Metal ◽  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Aryl Bromides ◽  
Wide Range ◽  
Sterically Demanding ◽  
Transition Metal Catalyzed ◽  
Catalyzed Reactions ◽  
Metal Catalyzed

Phosphines are widely used ligands in transition metal-catalyzed reactions. Arylphosphines, such as triphenylphosphine, were among the first phosphines to show broad utility in catalysis. Beginning in the late 1990s, sterically demanding and electronrich trialkylphosphines began to receive attention as supporting ligands. These ligands were found to be particularly effective at promoting oxidative addition in cross-coupling of aryl halides. With electron-rich, sterically demanding ligands, such as tri-tertbutylphosphine, coupling of aryl bromides could be achieved at room temperature. More importantly, the less reactive, but more broadly available, aryl chlorides became accessible substrates. Tri-tert-butylphosphine has become a privileged ligand that has found application in a wide range of late transition-metal catalyzed coupling reactions. This success has led to the use of numerous monodentate trialkylphosphines in cross-coupling reactions. This review will discuss the general properties and features of monodentate trialkylphosphines and their application in cross-coupling reactions of C–X and C–H bonds.

Suzuki coupling reactions catalyzed by Schiff base supported palladium complexes bearing the vitamin B6 cofactor

2021 ◽  
Vol 505 ◽  
pp. 111528
Author(s):  
Abdollah Neshat ◽  
Mohammad Gholinejad ◽  
Hafize Özcan ◽  
Faezeh Khosravi ◽  
Ali Mousavizadeh Mobarakeh ◽  
...  
Keyword(s):  
Schiff Base ◽  
Vitamin B6 ◽  
Suzuki Coupling ◽  
Palladium Complexes ◽  
Coupling Reactions ◽  
Supported Palladium

Palladium immobilized on functionalized hypercrosslinked polymers: a highly active and recyclable catalyst for Suzuki–Miyaura coupling reactions in water

2019 ◽  
Vol 43 (31) ◽  
pp. 12206-12210 ◽  
Author(s):  
Xi Liu ◽  
Wei Xu ◽  
Dexuan Xiang ◽  
Zaixing Zhang ◽  
Dizhao Chen ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Palladium Complexes ◽  
Recyclable Catalyst ◽  
Cross Linking ◽  
Coupling Reactions ◽  
Highly Active ◽  
Hypercrosslinked Polymers

Three palladium complexes were synthesized via an external cross-linking reaction and found to be effective heterogeneous catalysts for the Suzuki–Miyaura reaction.

Modern Catalysts in A3- Coupling Reactions

2020 ◽  
Vol 23 (25) ◽  
pp. 2783-2801 ◽  
Author(s):  
Ali Ramazani ◽  
Hamideh Ahankar ◽  
Zahra T. Nafeh ◽  
Sang W. Joo
Keyword(s):  
Transition Metals ◽  
Heterogeneous Catalysts ◽  
Coupling Reaction ◽  
Biologically Active ◽  
Coupling Reactions ◽  
The Past ◽  
Valuable Compounds ◽  
A3 Coupling ◽  
Important Constituent

: Propargylamines are an important constituent of diverse, biologically active and industrially valuable compounds. These useful, convenient and effective compounds can be synthesized via the A3-coupling reactions between an aldehyde, amine, and alkyne in the presence of a catalyst. In the past years, most of the catalysts containing transition metals were applied in these reactions, but today, various heterogeneous catalysts, especially nanocatalysts are used. The purpose of this review was to introduce some modern catalysts for the A3-coupling reaction.

Controlled Synthesis of Hydroxyapatite-Supported Palladium Complexes as Highly Efficient Heterogeneous Catalysts

2002 ◽  
Vol 124 (39) ◽  
pp. 11572-11573 ◽  
Author(s):  
Kohsuke Mori ◽  
Kazuya Yamaguchi ◽  
Takayoshi Hara ◽  
Tomoo Mizugaki ◽  
Kohki Ebitani ◽  
...  
Keyword(s):  
Heterogeneous Catalysts ◽  
Palladium Complexes ◽  
Controlled Synthesis ◽  
Highly Efficient ◽  
Supported Palladium

Transition-Metal-Catalyzed Cross-Coupling Reactions of Grignard Reagents

Synthesis ◽  
2020 ◽  
Author(s):  
Zoltán Hell ◽  
Kinga Juhász ◽  
Ágnes Magyar
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Cross Coupling ◽  
Biologically Active ◽  
Grignard Reagents ◽  
Coupling Reactions ◽  
Nickel Catalysis ◽  
Cross Coupling Reactions ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

AbstractTransition-metal-catalyzed cross-coupling of organo­halides, ethers, sulfides, amines, and alcohols (and derivatives thereof) with Grignard reagents, known as the Kumada–Tamao–Corriu reaction, can be used to prepare important intermediates in the synthesis of numerous­ biologically active compounds. The most frequently used transition metals are nickel, palladium, and iron, but there are several examples for cross-coupling reactions catalyzed by copper, cobalt, manganese, chromium, etc. salts and complexes. The aim of this review is to summarize the most important transition-metal-catalyzed cross-coupling reactions realized in the period 2000 to 2020.1 Introduction2 Nickel Catalysis3 Palladium Catalysis4 Iron Catalysis5 Catalysis by Other Transition Metals5.1 Cobalt Catalysis5.2 Copper Catalysis5.3 Manganese Catalysis5.4 Chromium Catalysis6 Conclusion

Transition-Metal-Catalyzed Annulative Coupling Cascade for the Synthesis of 3-Methyleneisoindolin-1-ones

Synthesis ◽  
2020 ◽  
Vol 52 (06) ◽  
pp. 807-818 ◽  
Author(s):  
So Won Youn
Keyword(s):  
Transition Metal ◽  
Bond Formation ◽  
Short Review ◽  
Coupling Reactions ◽  
Cyclization Reactions ◽  
One Pot ◽  
Bond Forming ◽  
Wide Range ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This short review describes the recent progress made on transition-metal-catalyzed annulative couplings for the synthesis of 3-methyleneisoindolin-1-ones, which are useful intermediates for the synthesis of numerous alkaloids and can be often found in a wide range of natural products and pharmaceuticals. In particular, new one-pot multiple C–C/C–N bond-forming processes for the construction of the 5-methylenepyrrol-2-one nucleus of such compounds are summarized.1 Introduction2 Intramolecular Cyclization Reactions: C3–N or C3–C3a and C–C Bond Formation3 Intermolecular Annulative Coupling Reactions3.1 C3–C3a and C3–N Bond Formation3.2 C1–C7a and C3–N Bond Formation3.3 C1–C7a and C1–N Bond Formation3.4 C1–C7a, C1–N and C3–N Bond Formation3.5 C3–C3a, C1–C7a, C1–N and C3–N Bond Formation: A Pd-Catalyzed One-Pot Sonogashira Coupling–Carbonylation–Amination–Cyclization Cascade4 Conclusion

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