Proton-coupled electron transfer is the dominant mechanism of reduction of haloacetates by the α-hydroxyethyl radical in aqueous media

2018 ◽  
Vol 20 (30) ◽  
pp. 19829-19840 ◽  
Author(s):  
Iva Džeba ◽  
Marija Bonifačić ◽  
Ivana Nikšić-Franjić ◽  
Ivan Ljubić

Reactions of α-hydroxyethyl radical with four haloacetates in non-buffered and buffered aqueous solutions preferably follow the proton-coupled electron transfer pathway.

2005 ◽  
Vol 44 (21) ◽  
pp. 7624-7633 ◽  
Author(s):  
David Sarauli ◽  
Roland Meier ◽  
Gao-Feng Liu ◽  
Ivana Ivanović-Burmazović ◽  
Rudi van Eldik

Author(s):  
Igor Sviben ◽  
Iva Džeba ◽  
Marija Bonifačić ◽  
Ivan Ljubić

The calculations unravel the role of buffers in the kinetics of the proton-coupled electron transfer reaction between α-hydroxyethyl radical and bromoacetate.


2000 ◽  
Vol 2 (7) ◽  
pp. 1531-1535 ◽  
Author(s):  
Vladimir A. Kuzmin ◽  
Alexander Dourandin ◽  
Vladimir Shafirovich ◽  
Nicholas E. Geacintov

2013 ◽  
Vol 4 (2) ◽  
pp. 734-738 ◽  
Author(s):  
Derek J. Wasylenko ◽  
Heidi M. Tatlock ◽  
Luvdeep S. Bhandari ◽  
James R. Gardinier ◽  
Curtis P. Berlinguette

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