Proton-coupled electron transfer at a [Co-OHx]zunit in aqueous media: evidence for a concerted mechanism

2013 ◽  
Vol 4 (2) ◽  
pp. 734-738 ◽  
Author(s):  
Derek J. Wasylenko ◽  
Heidi M. Tatlock ◽  
Luvdeep S. Bhandari ◽  
James R. Gardinier ◽  
Curtis P. Berlinguette
Keyword(s):  
Electron Transfer ◽  
Aqueous Media ◽  
Concerted Mechanism ◽  
Proton Coupled Electron Transfer

Proton Coupled Electron Transfer in the Reaction of Hydroxybenzenes with Hydrazyl Radical in Aqueous Media

2020 ◽  
Vol 90 (1) ◽  
pp. 23-31
Author(s):  
N. I. Belaya ◽  
A. V. Belyi ◽  
O. M. Zarechnaya ◽  
I. N. Shcherbakov ◽  
V. S. Doroshkevich
Keyword(s):  
Electron Transfer ◽  
Aqueous Media ◽  
Proton Coupled Electron Transfer ◽  
Hydrazyl Radical

Proton-coupled electron transfer is the dominant mechanism of reduction of haloacetates by the α-hydroxyethyl radical in aqueous media

2018 ◽  
Vol 20 (30) ◽  
pp. 19829-19840 ◽  
Author(s):  
Iva Džeba ◽  
Marija Bonifačić ◽  
Ivana Nikšić-Franjić ◽  
Ivan Ljubić
Keyword(s):  
Electron Transfer ◽  
Aqueous Solutions ◽  
Aqueous Media ◽  
Dominant Mechanism ◽  
Electron Transfer Pathway ◽  
Proton Coupled Electron Transfer

Reactions of α-hydroxyethyl radical with four haloacetates in non-buffered and buffered aqueous solutions preferably follow the proton-coupled electron transfer pathway.

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