[C7H14NO][ClO4]: order–disorder structural change induced sudden switchable dielectric behaviour at room temperature

CrystEngComm ◽  
2018 ◽  
Vol 20 (44) ◽  
pp. 7058-7061 ◽  
Author(s):  
Guang-Meng Fan ◽  
Ji-Xing Gao ◽  
Chao Shi ◽  
Hui Yu ◽  
Le Ye ◽  
...  
Keyword(s):  
Structural Change ◽  
Room Temperature ◽  
Dielectric Behaviour ◽  
Inorganic Hybrid ◽  
Dynamic Transition ◽  
Low Dielectric ◽  
Switch Type

Static-to-dynamic transition in organic–inorganic hybrid [C7H14NO][ClO4] exhibits switch-type characteristics during the dielectric transitions between high- and low-dielectric states.

Above-room-temperature coupling between ferroelastic domains and magnetism in an organic-inorganic hybrid: CsCu(HCOO)2Cl

2021 ◽  
Vol 5 (7) ◽  
Author(s):  
Junyan Zhou ◽  
Shifeng Jin ◽  
Ruijin Sun ◽  
Congcong Chai ◽  
Munan Hao ◽  
...  
Keyword(s):  
Room Temperature ◽  
Inorganic Hybrid ◽  
Ferroelastic Domains

Synthesis, Characterization and Thermooxidative Properties of Hybrid Block Poly(silane-b-arylacetylene)

2014 ◽  
Vol 1004-1005 ◽  
pp. 527-532
Author(s):  
Ying Jie Xu ◽  
Hui Min Qi ◽  
Ya Ping Zhu ◽  
Fan Wang
Keyword(s):  
Weight Loss ◽  
Oxidative Stability ◽  
Lewis Acid ◽  
Grignard Reagent ◽  
Room Temperature ◽  
Condensation Polymerization ◽  
Thermooxidative Stability ◽  
Thermal Cure ◽  
Inorganic Hybrid ◽  
Thermal And Oxidative Stability

Organic-inorganic hybrid block Poly (silane-b-arylacetylene) (PSbA) have been synthesized through condensation polymerization between chloro-terminated polysilane and diethynylbenzene Grignard reagent, and chloro-terminated polysilane was synthesized through condensation polymerization of dichloromethylvinylsilane in the presence of Mg metal and Lewis acid (ZnCl2, LiCl). The structures of PSbAs were characterized by FTIR, 1H, 13C, 29Si NMR, and GPC. The PSbAs are orange viscous liquid and can be soluble in common organic solvents at room temperature. The thermal cure behavior of PSbAs was determined by DSC, and the thermal and oxidative stability of the cured PSbAs were investigated using TGA. The results showed that the cured PSbAs exhibit high thermal and thermooxidative stability. The degradation temperatures at 5% weight loss for the cured PSbAs are 470-533°C under N2 and 378-456°C under air, and the residue yields at 1000°C are 77.9-82.8% under N2 and 40.4-50.5% under air.

scholarly journals Preparation of Room Temperature Curable Organic-inorganic Hybrid Thermal Control Coatings

2018 ◽  
Vol 33 (8) ◽  
pp. 914 ◽  
Author(s):  
LIU Ding ◽  
YU Yang ◽  
MI Le ◽  
YU Yun ◽  
SONG Li-Xin
Keyword(s):  
Room Temperature ◽  
Thermal Control ◽  
Inorganic Hybrid ◽  
Thermal Control Coatings

scholarly journals Dynamic transition of current-driven single-skyrmion motion in a room-temperature chiral-lattice magnet

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Licong Peng ◽  
Kosuke Karube ◽  
Yasujiro Taguchi ◽  
Naoto Nagaosa ◽  
Yoshinori Tokura ◽  
...  
Keyword(s):  
Electric Current ◽  
Motion Tracking ◽  
Room Temperature ◽  
Dynamic Transition ◽  
Spintronic Devices ◽  
Transmission Electron ◽  
Flow Motion ◽  
Lorentz Transmission Electron Microscopy ◽  
And Control

AbstractDriving and controlling single-skyrmion motion promises skyrmion-based spintronic applications. Recently progress has been made in moving skyrmionic bubbles in thin-film heterostructures and low-temperature chiral skyrmions in the FeGe helimagnet by electric current. Here, we report the motion tracking and control of a single skyrmion at room temperature in the chiral-lattice magnet Co9Zn9Mn2 using nanosecond current pulses. We have directly observed that the skyrmion Hall motion reverses its direction upon the reversal of skyrmion topological number using Lorentz transmission electron microscopy. Systematic measurements of the single-skyrmion trace as a function of electric current reveal a dynamic transition from the static pinned state to the linear flow motion via a creep event, in agreement with the theoretical prediction. We have clarified the role of skyrmion pinning and evaluated the intrinsic skyrmion Hall angle and the skyrmion velocity in the course of the dynamic transition. Our results pave a way to skyrmion applications in spintronic devices.

Temperature Sensitive and Reversible Halide Ion Exchange in Inorganic–Organic Hybrid CH3NH3PbI3−xBrx Mixed-Halide Perovskite

2021 ◽  
Vol 16 (4) ◽  
pp. 670-674
Author(s):  
Shuting Cui ◽  
Xun Sun ◽  
SiWen Tao ◽  
Huawei Zhou ◽  
Jie Yin ◽  
...  
Keyword(s):  
High Temperature ◽  
Ion Exchange ◽  
Band Gap ◽  
Room Temperature ◽  
Temperature Sensitive ◽  
Mechanism Study ◽  
Interesting Phenomenon ◽  
Inorganic Hybrid ◽  
Hybrid Perovskite ◽  
Halide Perovskite

Ion exchange of organic-inorganic hybrid perovskite plays a significant role in controlling the performance of materials ant its devices. In this study, an interesting phenomenon was observed that the precipitate in suspension (CH3NH3PbI3−xBrx in γ-butyrolactone) brought out different colors at high and room temperature. The mechanism study appears that the phenomenon is controlled by temperature sensitive and reversible halide ion exchange in organic-inorganic hybrid CH3NH3PbI3−xBrx mixed-halide perovskite. The results of structure phase, element composition morphology and band gap illustrate that high temperature 55 °C is beneficial to the increasing of I content in MAPbI3−xBrx and room temperature or lower is advantageous to increasing of Br content in MAPbI3−xBrx. Compared with MAPbI0.76Br2.24 precipitate acquired at room temperature, MAPbI1.17Br1.83 precipitate got at high temperature illustrate wider lattice spacing, better crystallinity, better morphology and narrower band gap. The results and findings in this study will prompt the interest of readers or experts in the field of organic-inorganic hybrid perovskite materials and related optoelectronic applications.

scholarly journals Direct Room-Temperature Synthesis of Organic-Inorganic Hybrid MCM-48 Nanoparticles

2013 ◽  
Vol 25 (10) ◽  
pp. 5483-5486
Author(s):  
Xu Luo ◽  
Zhonglai Wang ◽  
Guojun Zou ◽  
Xiaolai Wang
Keyword(s):  
Room Temperature ◽  
Temperature Synthesis ◽  
Inorganic Hybrid ◽  
Room Temperature Synthesis

scholarly journals Diffusion Of Indigo Molecules Inside The Palygorskite Clay Channels

2011 ◽  
Vol 1319 ◽  
Author(s):  
Catherine Dejoie ◽  
Pauline Martinetto ◽  
Eric Dooryhée ◽  
Ross Brown ◽  
Sylvie Blanc ◽  
...  
Keyword(s):  
Room Temperature ◽  
Heating Process ◽  
Microscopic Structure ◽  
X Ray Diffraction ◽  
Inorganic Hybrid ◽  
X Ray ◽  
Open Questions ◽  
Maya Blue ◽  
Palygorskite Clay ◽  
Unique Association

ABSTRACTThe search for durable dyes led several past civilizations to develop artificial pigments. Maya Blue (MB), manufactured in pre-Columbian Mesoamerica, is one of the best known examples of an organic-inorganic hybrid material. Its durability is due to the unique association of indigo molecule and palygorskite, a particular fibrous clay occurring in Yucatan. Despite 50 years of sustained interest, the microscopic structure of MB and its relation to the durability remain open questions. Combining new thermogravimetric and synchrotron X-ray diffraction analyses, we show that indigo molecules can diffuse into the channel of the palygorskite during the heating process, replacing zeolitic water and stabilizing the room temperature phases of the clay.

New Carbon-bridged Hybrid Polymers for Low-k Materials

2005 ◽  
Vol 863 ◽  
Author(s):  
Bum-Gyu Choi ◽  
Byung Ro Kim ◽  
Myung-Sun Moon ◽  
Jung-Won Kang ◽  
Min-Jin Ko
Keyword(s):  
Mechanical Properties ◽  
Hybrid Materials ◽  
Chemical Mechanical Planarization ◽  
Sol Gel ◽  
Dielectric Constants ◽  
Metal Line ◽  
Inorganic Hybrid ◽  
Low Dielectric ◽  
Continuous Stiffness Measurement ◽  
Low K

AbstractReducing interline capacitance and line resistance is required to minimize RC delays, reduce power consumption and crosstalk below 100nm node technology. For this purpose, various inorganic- and organic polymers have been tested to reduce dielectric constants in parallel with the use of copper as metal line. Lowering the dielectric constants, in particular, causes the detrimental effect on mechanical properties, and then leads to film damage and/or delamination during chemical-mechanical planarization CMP) or repeated thermal cure cycles. To overcome this issue, new carbon-bridged hybrid materials synthesized by organometallic silane precursors and sol-gel reaction are proposed.In this work, we have developed new organic-inorganic hybrid low-k dielectrics with linear or cyclic carbon bridged structures. The differently bridged carbon structures were formed by a controlled reaction. 1H NMR, 29Si NMR analysis and GC/MSD analysis were conducted for the structural characterization of new hybrid low-k dielectric. The mechanical and dielectric properties of these hybrid materials were characterized by using nanoindentation with continuous stiffness measurement and Al dot MIS techniques. The results indicated that these organic-inorganic hybrid materials were very promising polymers for low-k dielectrics that had low dielectric constants with high thermal and mechanical properties. It has been also demonstrated that electrical and mechanical properties of the hybrid films could be tailored by copolymerization with PMSSQ and through the introduction of porogen.

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