Hierarchically porous metal–organic frameworks with single-crystal structures and their enhanced catalytic properties

CrystEngComm ◽  
2018 ◽  
Vol 20 (38) ◽  
pp. 5754-5759 ◽  
Author(s):  
Hang Zhang ◽  
Jinhao Huo ◽  
Jinqing Li ◽  
Feier Li ◽  
Chongxiong Duan ◽  
...  
Keyword(s):  
Single Crystal ◽  
Crystal Structures ◽  
Catalytic Properties ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Hydrothermal Conditions ◽  
Hierarchically Porous ◽  
Single Crystal Structures ◽  
Metal Organic

Stable hierarchically porous metal–organic frameworks (HP-MOFs) have been successfully synthesized under hydrothermal conditions using a template strategy.

scholarly journals Amino acids as highly efficient modulators for single crystals of zirconium and hafnium metal–organic frameworks

2016 ◽  
Vol 4 (18) ◽  
pp. 6955-6963 ◽  
Author(s):  
Ross J. Marshall ◽  
Claire L. Hobday ◽  
Colin F. Murphie ◽  
Sarah L. Griffin ◽  
Carole A. Morrison ◽  
...  
Keyword(s):  
Amino Acids ◽  
Single Crystal ◽  
Single Crystals ◽  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Single Crystal Structures ◽  
Highly Efficient ◽  
Metal Organic ◽  
P Addition

Addition of small quantities of amino acids to solvothermal and microwave syntheses of Zr and Hf MOFs drastically improves their crystallinity to the extent that single crystal structures can be obtained.

Polysaccharide templated biomimetic growth of hierarchically porous metal-organic frameworks

2020 ◽  
Vol 306 ◽  
pp. 110429 ◽  
Author(s):  
Nisrine Hammi ◽  
Samir El Hankari ◽  
Nadia Katir ◽  
Nathalie Marcotte ◽  
Khalid Draoui ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Hierarchically Porous ◽  
Metal Organic

Hierarchically porous metal–organic frameworks: rapid synthesis and enhanced gas storage

Soft Matter ◽  
2018 ◽  
Vol 14 (47) ◽  
pp. 9589-9598 ◽  
Author(s):  
Chongxiong Duan ◽  
Hang Zhang ◽  
Feier Li ◽  
Jing Xiao ◽  
Shaojuan Luo ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Gas Storage ◽  
Organic Amine ◽  
Rapid Synthesis ◽  
Hierarchically Porous ◽  
Adsorption Capacities ◽  
Metal Organic ◽  
Diffusion Rates ◽  
Enhanced Adsorption

A simple, rapid and versatile method was developed to increase the pore sizes and pore volumes of microporous MOFs (HKUST-1, ZIF-8, ZIF-67, and ZIF-90) by employing organic amine as the template. The resultant hierarchically porous HKUST-1 exhibited significantly enhanced adsorption capacities and faster diffusion rates for CH4 and CO2 gas storage.

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