In situ control of photochromic behavior through dual photo-isomerization using cobaloxime complexes with a spiropyran derivative and 2-cyanoethyl ligands

CrystEngComm ◽  
2018 ◽  
Vol 20 (39) ◽  
pp. 6061-6069 ◽  
Author(s):  
Akiko Sekine ◽  
Masato Tanaka ◽  
Hidehiro Uekusa ◽  
Nobuhiro Yasuda
Keyword(s):  
Visible Light ◽  
Photochromic Behavior ◽  
In Situ Control ◽  
Cyanoethyl Group

The lifetime of colored species of spiropyran derivatives increased significantly after the 2-cyanoethyl group was photoisomerized to the 1-cyanoethyl group on exposure to visible light.

scholarly journals Control of Photochromism in Crystalline-State in Dual Photoisomeric Complexes

2014 ◽  
Vol 70 (a1) ◽  
pp. C920-C920
Author(s):  
Akiko Sekine ◽  
Yuta Yamazaki ◽  
Kohei Johmoto ◽  
Hidehiro Uekusa
Keyword(s):  
Visible Light ◽  
Alkyl Group ◽  
Crystalline State ◽  
Structural Changes ◽  
Dynamic Control ◽  
Crystal Form ◽  
Photochromic Property ◽  
In Situ Control ◽  
Photochromic Materials

Photochromic materials have attracted attention in recent years, however, in situ control of the photochromic reactivities still challenging. In order to realize dynamic control of photochromic property in crystal, we designed and created new dual photoisomeric type cobaloxime complexes, in which the reactivity of photochromic ligand changes by contact with surrounding photoreactive ligands. In this study, salicylideneaniline derivatives (SAP) are used as photochromic ligands, and the relationships between their photochromic reactivity and structural changes induced by crystalline-state photoisomerization of alkyl group of cobaloxime complex were investigated. As a salicylideneaniline (SAP) type cobaloxime complex, (3-cyanopropyl)(N-(3,5-di-tert-butylsalicylidene)-3-aminopyridine)cobaloxime was successfully synthesized. In the crystal, the SAP moiety which had a twisted conformation (dihedral angle of rings, 30.0(6)0)showed the photochromism upon UV irradiation. Also the 3-1 photoisomerization of the 3-cyanopropyl group in the cobaloxime moiety occurred with retention of the single-crystal form upon visible light irradiation. After crystalline-state 3-1 photoisomerization of the alkyl group by visible light, the photochromic property was examined to show the lifetime of colored species became significantly longer than before the reaction. It would be explained that the reaction cavity around the SAP moiety was modified by solid-state photoisomerization of alkyl group of the surrounding cobaloxime complexes, which successfully enabled the control of the photochromism. Moreover, other several derivatives are investigated similarly and their results were discussed together.

In-situ synthesis of a hybrid Fe (Co)/MXene/ZSM-5 catalyst for phenol abatement

2021 ◽  
Author(s):  
Changquan Zhang ◽  
Chaolin Li ◽  
Gang Chen ◽  
Fei Ji ◽  
Yiyong Shen ◽  
...  
Keyword(s):  
Visible Light ◽  
Organic Pollutants ◽  
In Situ Synthesis ◽  
Sulfate Radical

Sulfate radical based photocatalysis is recognized as an effective approach for the photodegradation of organic pollutants in wastewater. To overcome the defects of weak visible light absorptivity and low catalytic...

scholarly journals Electrochemical bubble generation via hydrazine oxidation for the in situ control of an electrodeposited conducting polymer micro/-nanostructure

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 11020-11025
Author(s):  
David Possetto ◽  
Luciana Fernández ◽  
Gabriela Marzari ◽  
Fernando Fungo
Keyword(s):  
Conducting Polymer ◽  
Electrochemical Method ◽  
Bubble Generation ◽  
Hydrazine Oxidation ◽  
In Situ Control

An electrochemical method to manipulate the size and density of electrodeposited polypyrrole structures at the micro-nanoscale by the discharge of hydrazine.

Photocatalytic degradation of tetracycline under visible light using TiO2@sulfur doped carbon nitride nanocomposite synthesized via in-situ method

2021 ◽  
Vol 9 (4) ◽  
pp. 105560
Author(s):  
Krishnan Divakaran ◽  
Amanulla Baishnisha ◽  
Vellaichamy Balakumar ◽  
Krishnan Nattamai Perumal ◽  
Chandran Meenakshi ◽  
...  
Keyword(s):  
Visible Light ◽  
Photocatalytic Degradation ◽  
Carbon Nitride ◽  
In Situ Method

In situ construction of WO3/g-C3N4 composite photocatalyst with 2D–2D heterostructure for enhanced visible light photocatalytic performance

2019 ◽  
Vol 43 (44) ◽  
pp. 17416-17422 ◽  
Author(s):  
Huaqiang Zhuang ◽  
Zhenping Cai ◽  
Wentao Xu ◽  
Mianli Huang ◽  
Xiaobin Liu
Keyword(s):  
Visible Light ◽  
Photocatalytic Performance ◽  
Composite Photocatalyst ◽  
Preparation Strategy ◽  
Visible Light Photocatalytic

A WO3/g-C3N4 composite photocatalyst with 2D–2D heterostructure was designed and constructed by an in situ preparation strategy.

Sign in / Sign up

Export Citation Format

Share Document