Engineering borate modified NiFe layer double hydroxide nanoarrays as “hydroxyl ions hungry” electrocatalysts for enhanced oxygen evolution

2019 ◽  
Vol 55 (9) ◽  
pp. 1334-1337 ◽  
Author(s):  
Zemin Sun ◽  
Yutong Wang ◽  
Liu Lin ◽  
Mengwei Yuan ◽  
Heyun Jiang ◽  
...  

A simple and facile “hydroxyl ions hungry” electrode structure was prepared by a two-step hydrothermal reaction to obtain BA-NiFe-LDHs/CP. It exhibited excellent OER catalytic activity.

2021 ◽  
Vol 60 (3) ◽  
pp. 2023-2036
Author(s):  
Arun Karmakar ◽  
Kannimuthu Karthick ◽  
Sangeetha Kumaravel ◽  
Selvasundarasekar Sam Sankar ◽  
Subrata Kundu

2021 ◽  
Author(s):  
Huixia Hu ◽  
xiang lei ◽  
Shumei Li ◽  
Ruzhen PENG ◽  
Jinliang Wang

NiFe layered-double-hydroxide (NiFe-LDH) and the NiFe metal–organic framework (NiFe-MOF) demonstrates the best catalytic activity among NiFe-based materials for the oxygen evolution reaction (OER), which is important for efficient hydrogen production....


2020 ◽  
Vol 8 (48) ◽  
pp. 26130-26138
Author(s):  
Zhenxing Xu ◽  
Yiran Ying ◽  
Guoge Zhang ◽  
Kongzhe Li ◽  
Yan Liu ◽  
...  

The electronic structure of NiFe layered double hydroxide was engineered by valence control and intermediate stabilization for enhanced catalytic activity.


2019 ◽  
Vol 55 (80) ◽  
pp. 12076-12079 ◽  
Author(s):  
Xiang Chen ◽  
Haonan Wang ◽  
Bin Xia ◽  
Ruru Meng

Noncovalent phosphorylation of CoCr layered double hydroxide (LDH) was prepared by using P2O5 dissolved in isopropanol as a precursor, which showed improved catalytic activity for oxygen evolution reaction compared with pristine CoCr LDH.


2020 ◽  
Author(s):  
Ding Yuan ◽  
Yuhai Dou ◽  
Chun-Ting He ◽  
Linping Yu ◽  
Li Xu ◽  
...  

2021 ◽  
Vol 5 (1) ◽  
Author(s):  
Daire Tyndall ◽  
Sonia Jaskaniec ◽  
Brian Shortall ◽  
Ahin Roy ◽  
Lee Gannon ◽  
...  

AbstractNickel–iron-layered double hydroxide (NiFe LDH) platelets with high morphological regularity and submicrometre lateral dimensions were synthesized using a homogeneous precipitation technique for highly efficient catalysis of the oxygen evolution reaction (OER). Considering edge sites are the point of activity, efforts were made to control platelet size within the synthesized dispersions. The goal is to controllably isolate and characterize size-reduced NiFe LDH particles. Synthetic approaches for size control of NiFe LDH platelets have not been transferable based on published work with other LDH materials and for that reason, we instead use postsynthetic treatment techniques to improve edge-site density. In the end, size-reduced NiFe LDH/single-wall carbon nanotube (SWCNT) composites allowed to further reduce the OER overpotential to 237 ± 7 mV (<L> = 0.16 ± 0.01 μm, 20 wt% SWCNT), which is one of the best values reported to date. This approach as well improved the long-term activity of the catalyst in operating conditions.


2021 ◽  
Author(s):  
Zihao Liu ◽  
Shifeng Li ◽  
Fangfang Wang ◽  
Mingxia Li ◽  
Yonghong Ni

FeNi-layered double hydroxide (LDH) is thought to be an excellent electrocatalyst for oxygen evolution reaction (OER), but it always shows extremely poor electrocatalytic activity toward hydrogen evolution reaction (HER) in...


2010 ◽  
Vol 136 ◽  
pp. 43-47
Author(s):  
Rui Dong Xu ◽  
Jun Li Wang ◽  
Jian Feng Zhou

This research is to fabricate a Pb/WC-ZrO2 inert electrode used in zinc electrodeposition. First, the potential-pH diagram of Pb-H2O system was constructed and the thermodynamic stable region was calibrated in the diagram. On the basis, the co-deposition of Pb, WC and ZrO2 particles from fluorboric acid solutions was realized on the surface of Pb-4wt%Sb substrate. The results show that deposition amounts of ZrO2 and WC particles in the inert electrodes increase with increasing ZrO2 concentrations in the bath, WC particle is easier to deposit into the inert electrodes than ZrO2 particle. The distribution of WC and ZrO2 particles as the second phase within metal matrix Pb is very uniform. Compared with Pb-1wt%Ag alloy electrode, Pb/9.91wt%WC-3.62wt%ZrO2 inert electrode possesses better catalytic activity of oxygen evolution.


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