Linking design and properties of purine-based donor–acceptor chromophores as optoelectronic materials

2017 ◽  
Vol 5 (27) ◽  
pp. 6891-6898 ◽  
Author(s):  
Graham S. Collier ◽  
Lauren A. Brown ◽  
Evan S. Boone ◽  
Meesha Kaushal ◽  
M. Nance Ericson ◽  
...  

Creating new building blocks for donor–acceptor conjugated systems is an important task for continued development of materials for organic electronics.

2011 ◽  
Vol 13 (7) ◽  
pp. 1762-1765 ◽  
Author(s):  
Noémie Hergué ◽  
Charlotte Mallet ◽  
Gurunathan Savitha ◽  
Magali Allain ◽  
Pierre Frère ◽  
...  

2016 ◽  
Vol 4 (26) ◽  
pp. 6200-6214 ◽  
Author(s):  
Yang Wang ◽  
Tsuyoshi Michinobu

Electron-deficient building blocks based on benzothiadiazole and its π-extended, heteroannulated derivatives for constructing high-performance semiconducting polymers are described.


2014 ◽  
Vol 80 (2) ◽  
pp. 980-987 ◽  
Author(s):  
Rukiya Matsidik ◽  
Johannes Martin ◽  
Simon Schmidt ◽  
Johannes Obermayer ◽  
Florian Lombeck ◽  
...  

ChemInform ◽  
2011 ◽  
Vol 42 (27) ◽  
pp. no-no
Author(s):  
Noemie Hergue ◽  
Charlotte Mallet ◽  
Gurunathan Savitha ◽  
Magali Allain ◽  
Pierre Frere ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (66) ◽  
pp. 38407-38413 ◽  
Author(s):  
Koray T. Ilhan ◽  
Sebahat Topal ◽  
Mehmet S. Eroglu ◽  
Turan Ozturk

Four step synthesis of 3-alkylthieno[3,2-b]thiophenes in the literature was reduced to two steps in good yields, through the preparation of the mono ketone, i.e. 1-(thiophene-3-ylthio)alkan-2-one, from 3-bromothiophene and ring formation reaction.


Author(s):  
Jenna L Sartucci ◽  
Arindam Maity ◽  
Manikandan Mohanan ◽  
Jeffery A. Bertke ◽  
Miklos Kertesz ◽  
...  

Understanding the doping mechanism in organic semiconductors and generating molecular design rules to control the doping process is crucial to improve the performance of organic electronics. Even though controlling the...


2021 ◽  
Author(s):  
Francesca D'Anna ◽  
Fabiana Pandolfi ◽  
Daniele Rocco ◽  
Salvatore Marullo ◽  
Marta Feroci ◽  
...  

Oligothiophene derivatives play a central role in the formulation of materials used in devices in the field of organic electronics. In this work we report the results of the study...


2018 ◽  
Vol 42 (10) ◽  
pp. 531-534 ◽  
Author(s):  
Yangyang Wang ◽  
Mengna Li ◽  
Yufei Song ◽  
Ming Qin ◽  
Xuehui Li ◽  
...  

Two novel donor–π–acceptor-type dithienylethene derivatives, in which the triphenylamine group acts as electron donor and the formyl group functions as electron acceptor, have been developed. Their structures were confirmed by 1H NMR, 13C NMR and HRMS (ESI). Investigation of their photochromic properties indicated that they had good photochromic behaviour and excellent fatigue resistance on irradiation with UV or visible light. DFT calculations further validated these experimental results for photochromic behaviour. Moreover, these compounds can be utilised as versatile building blocks to construct novel near-infrared photochromic materials.


2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Ying Qin ◽  
Hui Chen ◽  
Jia Yao ◽  
Yue Zhou ◽  
Yongjoon Cho ◽  
...  

AbstractIn organic electronics, an aromatic fused ring is a basic unit that provides π-electrons to construct semiconductors and governs the device performance. The main challenge in developing new π-skeletons for tuning the material properties is the limitation of the available chemical approach. Herein, we successfully synthesize two pentacyclic siloxy-bridged π-conjugated isomers to investigate the synergistic effects of Si and O atoms on the geometric and electronic influence of π-units in organic electronics. Notably, the synthesis routes for both isomers possess several advantages over the previous approaches for delivering conventional aromatic fused-rings, such as environmentally benign tin-free synthesis and few synthetic steps. To explore their potential application as photovoltaic materials, two isomeric acceptor–donor–acceptor type acceptors based on these two isomers were developed, showing a decent device efficiency of 10%, which indicates the great potential of this SiO-bridged ladder-type unit for the development of new high-performance semiconductor materials.


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