Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

2017 ◽  
Vol 5 (15) ◽  
pp. 3706-3713 ◽  
Author(s):  
Akio Mishima ◽  
Tomomi Koshiyama ◽  
Jose A. Real ◽  
Masaaki Ohba
Keyword(s):  
Coordination Polymer ◽  
Spin State ◽  
Coordination Polymers ◽  
Aqueous Suspension ◽  
State Change ◽  
Porous Coordination Polymers ◽  
Porous Coordination Polymer

Guest-responsivity accompanying spin-state change of a porous coordination polymer was enhanced by mesocrystallization in both solid and aqueous suspension states.

scholarly journals Soft 2D Layer Porous Coordination Polymers with 1,2-Di(4-pyridyl)ethane

2013 ◽  
Vol 66 (4) ◽  
pp. 464 ◽  
Author(s):  
Keisuke Kishida ◽  
Satoshi Horike ◽  
Kanokwan Kongpatpanich ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymer ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Adsorption Isotherms ◽  
Gas Adsorption ◽  
Porous Structures ◽  
Porous Coordination Polymers ◽  
Substituent Group ◽  
Layer Structures ◽  
Porous Coordination Polymer

Porous coordination polymer compounds consisting of Zn2+, 1,2-di(4-pyridyl)ethane, and dicarboxylates were synthesised and their crystal structures were determined. These are doubly interpenetrated 2D layer structures, and the flexibility of porous structures is dependent on the substituent group of the dicarboxylate. From gas adsorption studies, distinct adsorption isotherms were observed for CO2, CH4, C2H4, and C2H6 at 195 K and 273 K, respectively.

scholarly journals Al-Based porous coordination polymer derived nanoporous carbon for immobilization of glucose oxidase and its application in glucose/O2 biofuel cell and biosensor

RSC Advances ◽  
2017 ◽  
Vol 7 (20) ◽  
pp. 11872-11879 ◽  
Author(s):  
Zepeng Kang ◽  
Kailong Jiao ◽  
Ruiyun Peng ◽  
Zongqian Hu ◽  
Shuqiang Jiao
Keyword(s):  
Coordination Polymer ◽  
Glucose Oxidase ◽  
Coordination Polymers ◽  
Nanoporous Carbon ◽  
Biofuel Cell ◽  
Porous Coordination Polymers ◽  
Porous Coordination Polymer

Herein, we report the first example of using the Al-based porous coordination polymers (Al-PCP) as a template for preparation of nanoporous carbon through a two-step carbonized method.

Cerium-based porous coordination polymers with hierarchical superstructures: fabrication, formation mechanism and their thermal conversion to hierarchical CeO2

2015 ◽  
Vol 2 (6) ◽  
pp. 567-575 ◽  
Author(s):  
Yong-Xia Zhao ◽  
Zhi-Wen Nie ◽  
Meng-Meng Shi ◽  
Cheng-Hui Zeng ◽  
Yuan Li ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Formation Mechanism ◽  
Coordination Polymers ◽  
Three Dimensional ◽  
Hierarchical Structures ◽  
Thermal Conversion ◽  
Porous Coordination Polymers ◽  
Polymer Precursors ◽  
Porous Coordination Polymer

Novel three-dimensional (3D) ceria hierarchical structures have been prepared via a thermolysis of the corresponding porous coordination polymer precursors.

Mesoporous Co3O4@carbon composites derived from microporous cobalt-based porous coordination polymers for enhanced electrochemical properties in supercapacitors

RSC Advances ◽  
2016 ◽  
Vol 6 (22) ◽  
pp. 18465-18470 ◽  
Author(s):  
Shuang Wang ◽  
Ting Wang ◽  
Ying Shi ◽  
Guang Liu ◽  
Jinping Li
Keyword(s):  
Coordination Polymer ◽  
Electrochemical Properties ◽  
Coordination Polymers ◽  
Carbon Composites ◽  
Porous Coordination Polymers ◽  
One Step ◽  
Porous Coordination Polymer

In this work, mesoporous Co3O4@carbon composites were prepared through a simple, one-step, carbonization of microporous cobalt-based porous coordination polymer ZSA-1.

scholarly journals Triarylamine-based porous coordination polymers performing both hydrogen atom transfer and photoredox catalysis for regioselective α-amino C(sp3)–H arylation

2021 ◽  
Author(s):  
Hanning Li ◽  
Yang Yang ◽  
Jing Xu ◽  
Cheng He ◽  
Chunying Duan
Keyword(s):  
Organic Chemistry ◽  
Hydrogen Atom ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Hydrogen Atom Transfer ◽  
Atom Transfer ◽  
Photoredox Catalysis ◽  
Porous Coordination Polymers ◽  
Direct Functionalization

Direct functionalization of C(sp3)–H bonds in a predictable, selective and recyclable manner has become a central challenge in modern organic chemistry. Through incorporating different triarylamine-containing ligands into one coordination polymer,...

scholarly journals An Fe(iii)-doped coordination polymer of Mn13-clusters with improved activity for the oxygen reduction reaction

2019 ◽  
Vol 48 (15) ◽  
pp. 4794-4797 ◽  
Author(s):  
Tian Wen ◽  
Wolfgang Schmitt ◽  
Lei Zhang
Keyword(s):  
Composite Materials ◽  
Coordination Polymer ◽  
Oxygen Reduction Reaction ◽  
Oxygen Reduction ◽  
Coordination Polymers ◽  
Reduction Reaction ◽  
Porous Coordination Polymers ◽  
Orr Activity

Homogeneously distributed Fe(iii) dopants were introduced into porous coordination polymers of Mn13-clusters to form composite materials. The resulting Fe@Mn13-polymer exhibited efficient oxygen reduction reaction (ORR) activity.

Preparation and catalytic application of Mn(III)-porphyrin based micro sized porous coordination polymers

2014 ◽  
Vol 18 (07) ◽  
pp. 579-584 ◽  
Author(s):  
Sundol Kim ◽  
Kyung Yeon Lee ◽  
Young Sun Lee ◽  
Ho Gyeom Jang ◽  
Jung Kyoo Lee ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Heterogeneous Catalysts ◽  
Active Catalyst ◽  
Catalyst Stability ◽  
Porous Coordination Polymers ◽  
Adequate Amount ◽  
Polymer Supports ◽  
Catalytic Application ◽  
Wide Range

We developed a series of micro-sized porous coordination polymers from Mn ( III )-porphyrin biscarboxylate and In ( III ) whose morphologies were systematically modulated by the addition of adequate amount of water. Regardless of a wide range of morphology distribution, they are isostructural, confirmed by the identical PXRD patterns. Furthermore, their use as heterogeneous catalysts for the olefin oxidations has been successfully demonstrated. Specially, their catalyst stability, lifetime and re-usability were dramatically improved, suggesting that the incorporation of active catalyst into coordination polymer supports inhibited successfully the degradation of catalysts.

Evidence for surface effects on the intermolecular interactions in Fe(ii) spin crossover coordination polymers

2022 ◽  
Author(s):  
Thilini K. Ekanayaka ◽  
Hannah Kurz ◽  
Kayleigh A. McElveen ◽  
Guanhua Hao ◽  
Esha Mishra ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Intermolecular Interactions ◽  
Spin State ◽  
Coordination Polymers ◽  
Spin Crossover ◽  
State Transition ◽  
Photoemission Spectroscopy ◽  
X Ray ◽  
Spin State Transition ◽  
X Ray Absorption

From X-ray absorption spectroscopy (XAS) and X-ray photoemission spectroscopy (XPS) it is evident that the spin state transition behavior of Fe(ii) spin crossover coordination polymer crystallites at the surface differs from the bulk.

The Influence of Diamagnetic Substrates Absorption on Magnetic Properties of Porous Coordination Polymers

2013 ◽  
Vol 3 (2) ◽  
pp. 144-160 ◽  
Author(s):  
Sergey Kolotilov ◽  
Mikhail Kiskin ◽  
Igor Eremenko ◽  
Vladimir Novotortsev
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Porous Coordination Polymers
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