Additive-free Li4Ti5O12 thick electrodes for Li-ion batteries with high electrochemical performance

2018 ◽  
Vol 6 (14) ◽  
pp. 5952-5961 ◽  
Author(s):  
M. E. Sotomayor ◽  
C. de la Torre-Gamarra ◽  
W. Bucheli ◽  
J. M. Amarilla ◽  
A. Varez ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Discharge Capacity ◽  
Li Ion Batteries ◽  
Volumetric Discharge ◽  
Li Ion

Additive-free LTO ceramic anodes (thickness ∼500 μm) with high volumetric discharge capacity were prepared by powder extrusion moulding.

scholarly journals Directly Anodized Sulfur-Doped TiO2 Nanotubes as Improved Anodes for Li-ion Batteries

Batteries ◽  
2020 ◽  
Vol 6 (4) ◽  
pp. 51
Author(s):  
Davood Sabaghi ◽  
Mahmoud Madian ◽  
Ahmad Omar ◽  
Steffen Oswald ◽  
Margitta Uhlemann ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Discharge Capacity ◽  
Tio2 Nanotubes ◽  
Rate Capability ◽  
Pure Tio2 ◽  
Electrochemical Anodization ◽  
Li Ion Batteries ◽  
Doped Tio2 ◽  
Li Ion ◽  
Elemental Doping

TiO2 represents one of the promising anode materials for lithium ion batteries due to its high thermal and chemical stability, relatively high theoretical specific capacity and low cost. However, the electrochemical performance, particularly for mesoporous TiO2, is limited and must be further developed. Elemental doping is a viable route to enhance rate capability and discharge capacity of TiO2 anodes in Li-ion batteries. Usually, elemental doping requires elevated temperatures, which represents a challenge, particularly for sulfur as a dopant. In this work, S-doped TiO2 nanotubes were successfully synthesized in situ during the electrochemical anodization of a titanium substrate at room temperature. The electrochemical anodization bath represented an ethylene glycol-based solution containing NH4F along with Na2S2O5 as the sulfur source. The S-doped TiO2 anodes demonstrated a higher areal discharge capacity of 95 µAh·cm−2 at a current rate of 100 µA·cm−2 after 100 cycles, as compared to the pure TiO2 nanotubes (60 µAh·cm−2). S-TiO2 also exhibited a significantly improved rate capability up to 2500 µA·cm−2 as compared to undoped TiO2. The improved electrochemical performance, as compared to pure TiO2 nanotubes, is attributed to a lower impedance in S-doped TiO2 nanotubes (STNTs). Thus, the direct S-doping during the anodization process is a promising and cost-effective route towards improved TiO2 anodes for Li-ion batteries.

Electrochemical Performance of Al2O3-Coated LiNi1/3Co1/3Mn1/3O2 Cathode Materials for Li-Ion Batteries

2007 ◽  
Vol 336-338 ◽  
pp. 459-462
Author(s):  
Jian Gang Li ◽  
Xiang Ming He ◽  
Ru Song Zhao ◽  
Chun Rong Wan ◽  
Shi Chao Zhang
Keyword(s):  
Electrochemical Performance ◽  
Discharge Capacity ◽  
Electrical Performance ◽  
Coated Sample ◽  
Li Ion Batteries ◽  
Al2o3 Coating ◽  
Capacity Retention ◽  
Initial Discharge ◽  
Excellent Electrochemical Performance ◽  
Li Ion

Al2O3-coated LiNi1/3Co1/3Mn1/3O2 powders with excellent electrochemical performance have been synthesized. The electrochemical performance of Al2O3-coated LiNi1/3Co1/3Mn1/3O2 electrodes has been studied as function of the level of Al2O3 coating. Coated LiNi1/3Co1/3Mn1/3O2 samples shows higher discharge capacity and better capacity retention than the base one. Among the coated samples, 1.0mol% coated sample exhibits the best electrical performance. It presents an initial discharge capacity of 174.5 mAh g-1 over 2.5~4.4V, and 84.7% capacity retention after 30 cycles over 2.5~4.6V.

Electrochemical performance of in situ LiFePO4 modified by N-doped graphene for Li-ion batteries

2021 ◽  
Author(s):  
Gui-Yang Luo ◽  
Yi-Jing Gu ◽  
Yuan Liu ◽  
Zi-Liang Chen ◽  
Yong-lin Huo ◽  
...  
Keyword(s):  
Electrochemical Performance ◽  
Li Ion Batteries ◽  
Doped Graphene ◽  
Li Ion

Discharge capacity estimation for Li-ion batteries based on particle filter under multi-operating conditions

Energy ◽  
2015 ◽  
Vol 86 ◽  
pp. 638-648 ◽  
Author(s):  
Junfu Li ◽  
Lixin Wang ◽  
Chao Lyu ◽  
Liqiang Zhang ◽  
Han Wang
Keyword(s):  
Particle Filter ◽  
Discharge Capacity ◽  
Operating Conditions ◽  
Li Ion Batteries ◽  
Capacity Estimation ◽  
Li Ion

Probing the Effect of High Energy Ball Milling on the Structure and Properties of LiNi1/3Mn1/3Co1/3O2 Cathodes for Li-Ion Batteries

2016 ◽  
Vol 13 (3) ◽  
Author(s):  
Malcolm Stein ◽  
Chien-Fan Chen ◽  
Matthew Mullings ◽  
David Jaime ◽  
Audrey Zaleski ◽  
...  
Keyword(s):  
Particle Size ◽  
Electrochemical Performance ◽  
Crystallite Size ◽  
Ball Milling ◽  
Lithium Ion ◽  
High Energy ◽  
Li Ion Batteries ◽  
Structure And Properties ◽  
Transfer Resistance ◽  
Li Ion

Particle size plays an important role in the electrochemical performance of cathodes for lithium-ion (Li-ion) batteries. High energy planetary ball milling of LiNi1/3Mn1/3Co1/3O2 (NMC) cathode materials was investigated as a route to reduce the particle size and improve the electrochemical performance. The effect of ball milling times, milling speeds, and composition on the structure and properties of NMC cathodes was determined. X-ray diffraction analysis showed that ball milling decreased primary particle (crystallite) size by up to 29%, and the crystallite size was correlated with the milling time and milling speed. Using relatively mild milling conditions that provided an intermediate crystallite size, cathodes with higher capacities, improved rate capabilities, and improved capacity retention were obtained within 14 μm-thick electrode configurations. High milling speeds and long milling times not only resulted in smaller crystallite sizes but also lowered electrochemical performance. Beyond reduction in crystallite size, ball milling was found to increase the interfacial charge transfer resistance, lower the electrical conductivity, and produce aggregates that influenced performance. Computations support that electrolyte diffusivity within the cathode and film thickness play a significant role in the electrode performance. This study shows that cathodes with improved performance are obtained through use of mild ball milling conditions and appropriately designed electrodes that optimize the multiple transport phenomena involved in electrochemical charge storage materials.

Enhanced electrochemical properties of a natural graphite anode using a promising crosslinked ionomer binder in Li-ion batteries

2017 ◽  
Vol 41 (20) ◽  
pp. 11759-11765 ◽  
Author(s):  
Shu Huang ◽  
Jianguo Ren ◽  
Rong Liu ◽  
Min Yue ◽  
Youyuan Huang ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Electrochemical Performance ◽  
Electrochemical Properties ◽  
Graphite Anode ◽  
Li Ion Batteries ◽  
Natural Graphite ◽  
Graphite Anodes ◽  
Li Ion ◽  
Enhanced Electrochemical Performance ◽  
Natural Graphite Anode

A crosslinked ionomer binder was prepared and used in graphite anodes for Li-ion batteries. These binder-based anodes exhibit enhanced electrochemical performance due to the formation of hydrogen bonds and the release of conductive Li+.

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