Controlled synthesis of lithium doped tin dioxide nanoparticles by a polymeric precursor method and analysis of the resulting defect structure

2018 ◽  
Vol 6 (15) ◽  
pp. 6299-6308 ◽  
Author(s):  
Félix del Prado ◽  
Ana Cremades ◽  
David Maestre ◽  
Julio Ramírez-Castellanos ◽  
José M. González-Calbet ◽  
...  

Shift of the Fermi level towards the valence band maximum (VBM) of around Φ ∼ 0.2 eV.

1990 ◽  
Vol 04 (18) ◽  
pp. 1133-1136
Author(s):  
S.B. ZHANG

Recent theory predicted that the Ga and B antisites in GaAs are bistable. As the Fermi level is lowered towards the valence-band maximum, a structural change from fourfold to threefold coordination will occur. The Ga antisite will undergo an atomic exchange in the presence of an As interstitial.


2012 ◽  
Vol 86 (24) ◽  
Author(s):  
J. Dahl ◽  
M. Kuzmin ◽  
J. Adell ◽  
T. Balasubramanian ◽  
P. Laukkanen

1987 ◽  
Vol 94 ◽  
Author(s):  
Ming Tang ◽  
David W. Niles ◽  
Isaac Hernández-Calderón ◽  
Hartmut Hóchst

ABSTRACTAngular Resolved Photoemission Spectroscopy with Synchrotron radiation has been used to study the MBE growth of α-Sn on CdTe(110). Sn grows epitaxially and the Fermi level pins at 0.72eV above the CdTe valence band maximum. Outdiffusion or segregation of Cd in the α-Sn layer is not observed. For small Sn coverages the Sn4d core spectra show a second component which may be due to the initial interfacial growth of SnTe.


1992 ◽  
Vol 259 ◽  
Author(s):  
A. Hughes ◽  
T-H. Shen ◽  
C.C. Matthai

ABSTRACTThe electronic density of states (DOS) for the Si(111) (√3×√3)-Sb system has been calculated using the tight binding method in the Extended Hiickel Approximation. We find that there is a gap of about 0.8eV between the valence band maximum (VBM) and a surface state. This is in contrast with the case of the unreconstructed (lxl) surface where the Fermi level lies at the surface state.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Shun-Chang Liu ◽  
Chen-Min Dai ◽  
Yimeng Min ◽  
Yi Hou ◽  
Andrew H. Proppe ◽  
...  

AbstractIn lead–halide perovskites, antibonding states at the valence band maximum (VBM)—the result of Pb 6s-I 5p coupling—enable defect-tolerant properties; however, questions surrounding stability, and a reliance on lead, remain challenges for perovskite solar cells. Here, we report that binary GeSe has a perovskite-like antibonding VBM arising from Ge 4s-Se 4p coupling; and that it exhibits similarly shallow bulk defects combined with high stability. We find that the deep defect density in bulk GeSe is ~1012 cm−3. We devise therefore a surface passivation strategy, and find that the resulting GeSe solar cells achieve a certified power conversion efficiency of 5.2%, 3.7 times higher than the best previously-reported GeSe photovoltaics. Unencapsulated devices show no efficiency loss after 12 months of storage in ambient conditions; 1100 hours under maximum power point tracking; a total ultraviolet irradiation dosage of 15 kWh m−2; and 60 thermal cycles from −40 to 85 °C.


2009 ◽  
Vol 100 (2) ◽  
pp. 537-541 ◽  
Author(s):  
Fabiane Alexsandra Andrade de Jesus ◽  
Ronaldo Santos da Silva ◽  
Zélia Soares Macedo

2008 ◽  
Vol 77 (1) ◽  
pp. 210-216 ◽  
Author(s):  
A DEOLIVEIRA ◽  
J FERREIRA ◽  
M SILVA ◽  
G BRAGA ◽  
L SOLEDADE ◽  
...  

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