Facile synthesis of an eco-friendly nitrogen–phosphorus ammonium salt to enhance the durability and flame retardancy of cotton

2017 ◽  
Vol 5 (20) ◽  
pp. 9970-9981 ◽  
Author(s):  
Yaling Jia ◽  
Yi Lu ◽  
Guangxian Zhang ◽  
Yaojia Liang ◽  
Fengxiu Zhang

An eco-friendly AEGDP flame retardant reacted with –OH groups from cotton to enhance the durability and flame retardancy of cotton fibers.

RSC Advances ◽  
2017 ◽  
Vol 7 (50) ◽  
pp. 31298-31309 ◽  
Author(s):  
Xingyou Chen ◽  
Yinghong Chen

A supramolecular complexation method was used to synthesize a nitrogen–phosphorus hydrogen-bonded complex intumescent flame retardant, which can impart a good flame retardancy to LDPE foam.


1977 ◽  
Vol 47 (6) ◽  
pp. 418-422 ◽  
Author(s):  
Leon H. Chance ◽  
Judy D. Timpa

A new flame retardant for cotton, tetramethylol 2,4-diamino-6-(3,3,3-tribromo-1-propyl)-1,3,5-triazine (TM-DABT), was synthesized. TM-DABT was applied to cotton fabrics from a combination of water and dimethylformamide by a pad-dry-cure process. It polymerized rapidly on fabric at 140°C to give excellent flame retardancy. Flannelette and twill with add-ons of 13.3% and 11.3%, respectively, passed the FF3–71 flammability test after 50 laundering, with char lengths of 4.7 and 3.4 inches. There was evidence of cellulose crosslinking because fabrics had improved wrinkle-recovery angles, and cotton fibers were insoluble in cupriethylenediamine hydroxide. The finish was heat-sensitive, as evidenced by noticeable yellowing when white fabrics were cured at 150°C or above, or when they were laundered repeatedly. Various physical properties of the fabrics are presented, as well as oxygen index and thermogravimetric analyses.


RSC Advances ◽  
2018 ◽  
Vol 8 (68) ◽  
pp. 39214-39221 ◽  
Author(s):  
Yilun Shi ◽  
Zhengzhou Wang ◽  
Jian-an Zhou

Melamine phenylphosphate (MPhP) was facilely synthesized and improved the flame retardancy, smoke suppression and water resistance of epoxy resin.


ACS Omega ◽  
2019 ◽  
Vol 4 (18) ◽  
pp. 17791-17797 ◽  
Author(s):  
Hai Vothi ◽  
Congtranh Nguyen ◽  
Lam H. Pham ◽  
DongQuy Hoang ◽  
Jinhwan Kim

2021 ◽  
pp. 096739112110245
Author(s):  
Jiangbo Wang

A novel phosphorus-silicon containing flame-retardant DOPO-V-PA was used to wrap carbon nanotubes (CNTs). The results of FTIR, XPS, TEM and TGA measurements exhibited that DOPO-V-PA has been successfully grafted onto the surfaces of CNTs, and the CNTs-DOPO-V-PA was obtained. The CNTs-DOPO-V-PA was subsequently incorporated into epoxy resin (EP) for improving the flame retardancy and dispersion. Compared with pure EP, the addition of 2 wt% CNTs-DOPO-V-PA into the EP matrix could achieve better flame retardancy of EP nanocomposites, such as a 30.5% reduction in peak heat release rate (PHRR) and 8.1% reduction in total heat release (THR). Furthermore, DMTA results clearly indicated that the dispersion for CNTs-DOPO-V-PA in EP matrix was better than pristine CNTs.


2021 ◽  
Vol 260 ◽  
pp. 117827
Author(s):  
Ying-Jun Xu ◽  
Lian-Yi Qu ◽  
Yun Liu ◽  
Ping Zhu

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