scholarly journals Shape-dependent effective diffusivity in packings of hard cubes and cuboids compared with spheres and ellipsoids

Soft Matter ◽  
2017 ◽  
Vol 13 (46) ◽  
pp. 8864-8870 ◽  
Author(s):  
Magnus Röding

We performed computational screening of effective diffusivity in cube and cuboid systems, elucidating the impact of shape on the granular material design.

2021 ◽  
Vol 503 (3) ◽  
pp. 3460-3471
Author(s):  
Naomi Murdoch ◽  
Melanie Drilleau ◽  
Cecily Sunday ◽  
Florian Thuillet ◽  
Arnaud Wilhelm ◽  
...  

ABSTRACT With the flourishing number of small body missions that involve surface interactions, understanding the mechanics of spacecraft – surface interactions is crucial for improving our knowledge about the landing phases of space missions, for preparing spacecraft operations, and for interpreting the results of measurements made during the surface interactions. Given their regolith-covered surfaces, the process of landing on a small body can be considered as an impact at low-velocity on to a granular material in reduced-gravity. In order to study the influence of the surface material, projectile shape, and gravity on the collision dynamics, we used two experimental configurations (one for terrestrial gravity experiments and one for reduced-gravity experiments) to perform low-velocity collisions into different types of granular materials: quartz sand, and two different sizes of glass beads (1.5 and 5 mm diameter). Both a spherical and a cubic projectile (with varying impact orientation) were used. The experimental data support a drag model for the impact dynamics composed of both a hydrodynamic drag force and quasi-static resistance force. The hydrodynamic and quasi-static contributions are related to the material frictional properties, the projectile geometry, and the gravity. The transition from a quasi-static to a hydrodynamical regime is shown to occur at lower impact velocities in reduced-gravity trials than in terrestrial gravity trials, indicating that regolith has a more fluid-like behaviour in low-gravity. The reduced quasi-static regime of a granular material under low-gravity conditions leads to a reduction in the strength, resulting in a decreased resistance to penetration and larger penetration depths.


Author(s):  
Agate Martin ◽  
Patrick Trinke ◽  
Markus Stähler ◽  
Andrea Stähler ◽  
Fabian Scheepers ◽  
...  

Abstract Hydrogen crossover poses a crucial issue for polymer electrolyte membrane (PEM) water electrolysers in terms of safe operation and efficiency losses, especially at increased hydrogen pressures. Besides the impact of external operating conditions, the structural properties of the materials also influence the mass transport within the cell. In this study, we provide an analysis of the effect of elevated cathode pressures (up to 15 bar) in addition to increased compression of the membrane electrode assembly on hydrogen crossover and the cell performance, using thin Nafion 212 membranes and current densities up to 3.6 A cm-2. It is shown that a higher compression leads to increased mass transport overpotentials, although the overall cell performance is improved due to the decreased ohmic losses. The mass transport limitations also become visible in enhanced anodic hydrogen contents with increasing compression at high current densities. Moreover, increases in cathode pressure are amplifying the compression effect on hydrogen crossover and mass transport losses. The results indicate that the cell voltage should not be the only criterion for optimizing the system design, but that the material design has to be considered for the reduction of hydrogen crossover in PEM water electrolysis.


2018 ◽  
Vol 5 (3) ◽  
pp. 71 ◽  
Author(s):  
Atsushi Sakamoto ◽  
Hiroyuki Jinnouchi ◽  
Sho Torii ◽  
Renu Virmani ◽  
Aloke Finn

The technology of percutaneous coronary intervention (PCI) is constantly being refined in order to overcome the shortcomings of present day technologies. Even though current generation metallic drug-eluting stents (DES) perform very well in the short-term, concerns still exist about their long-term efficacy. Late clinical complications including late stent thrombosis (ST), restenosis, and neoatherosclerosis still exist and many of these events may be attributed to either the metallic platform and/or the drug and polymer left behind in the arterial wall. To overcome this limitation, the concept of totally bioresorbable vascular scaffolds (BRS) was invented with the idea that by eliminating long-term exposure of the vessel wall to the metal backbone, drug, and polymer, late outcomes would improve. The Absorb-bioabsorbable vascular scaffold (Absorb-BVS) represented the most advanced attempt to make such a device, with thicker struts, greater vessel surface area coverage and less radial force versus contemporary DES. Unfortunately, almost one year after its initial approval by the U.S. Food and Drug Administration, this scaffold was withdrawn from the market due to declining devise utilization driven by the concerns about scaffold thrombosis (ScT) seen in both early and late time points. Additionally, the specific causes of ScT have not yet been fully elucidated. In this review, we discuss the platform, vascular response, and clinical data of past and current metallic coronary stents with the Absorb-BVS and newer generation BRS, concentrating on their material/design and the mechanisms of thrombotic complications from the pre-clinical, pathologic, and clinical viewpoints.


Author(s):  
Tso-Liang Teng ◽  
Cho-Chung Liang ◽  
Van-Hai Nguyen

Helmets reduce the frequency and severity of head and brain injuries resulting from bicycle crashes. To ensure that all bicycle helmets provide a certain level of effectiveness, helmets are required to satisfy certain standards of construction and material design before they can be sold in the market. Impact protection is the primary consideration of nearly every helmet standard. The general terms for a test for assessing impact protection involve shock absorption. A helmeted headform is dropped onto an anvil and the headform acceleration is measured. However, the test procedures of the existing standards do not properly assess the protection level of helmets against oblique impacts. To investigate bicycle helmets in a real accident scenario, this study simulated the full body of a bicyclist when free falling onto a road. This study considered the normal velocity (VN) of 5.66 m/s and tangential velocity (VT) values of 0, 5, and 10 m/s. Finite element analyses of helmet impact tests were conducted using LS-DYNA software. Moreover, the impact responses obtained using full-body and detached-headform models were compared under identical impact conditions. The analysis results obtained herein can be useful for evaluating helmet quality and guiding future developments in helmet innovation.


2012 ◽  
Vol 704 ◽  
pp. 1-4 ◽  
Author(s):  
John R. de Bruyn

AbstractA flowing granular material can behave like a collection of individual interacting grains or like a continuum fluid, depending in large part on the energy imparted to the grains. As yet, however, we have no general understanding of how or under what conditions the fluid limit is reached. Marston, Li & Thoroddsen (J. Fluid Mech., this issue, vol. 704, 2012, pp. 5–36) use high-speed imaging to investigate the ejection of grains from a granular bed due to the impact of a spherical projectile. Their high temporal resolution allows them to study the very fast processes that take place immediately following the impact. They demonstrate that for very fine grains and high impact energies, the dynamics of the ejecta is both qualitatively and quantitatively similar to what is seen in analogous experiments with fluid targets.


2012 ◽  
Vol 1 (1) ◽  
pp. 24 ◽  
Author(s):  
I. Kamal ◽  
A. Gelicus ◽  
K. Allaf

<p>The present work is directed towards the impacts of Détente InstantanéeContrôléeDIC (French, for instant controlled pressure-drop) in terms of decaffeination and drying of Ethiopian green coffee beans (GCBs).DICconsisted in subjecting the product to a high-pressure saturated steam during some seconds and ended with an abrupt pressure drop towards a vacuum. A conventional aqueous extraction and a hot air-drying took place after DIC treatment. Inthis study, Response Surface Method (RSM) was used withDIC saturated steam pressure P, thermal treatment time t, and initial moisture content W asthe independent variables. Both direct DICextract recovered from the vacuum tank and the aqueous extracts wereanalyzed and quantified using the reversed phase-HPLC. With decaffeination ratiosas dependent variables, P and Wwere the most significant operating parameters; whilet was much weaker.Total decaffeination ratio could reach 99.5% after DIC treatment at specificconditions of W=11.00% db, P=0.1 MPa, and t=35swhile it was only 58% when achieved with untreated raw material.</p> The effective diffusivity  and the starting accessibility  were calculated from the diffusion/surface interaction kinetic model of hotair drying after DIC treatment. They dramatically increased with P and t while W had a weak impact.Thus, at the optimized DICconditions, and  increased from 0.33 to 12.60 10<sup>-10</sup>m² s<sup>-1</sup>and from 0.75 to 11.53 g/100 g db, respectively. Drying time needed to reach 5% db became 60 min instead of 528 min for untreated raw material. <p>RSM analysis showed that the DIC saturated steam pressure P and the initial moisture content W were the most significant variables both affecting the decaffeination ratio; the impact of the total thermal processing time t was much weaker. Total decaffeination ratio could reach 99.5% after DIC treatment at specific conditions of W=11.00% db, P=0.1 MPa, and t=35 s while it was only 58% when achieved with untreated raw material.</p> <p>Using diffusion/surface interaction model of hot-air drying kinetics just after DIC treatment, we could observe that DIC expansion dramatically improved the drying kinetic parameters, with P and t as the most significant DIC operating parameters while the impact of W was much weaker. Thus, the optimized DIC treatment allowed the effective diffusivity  and the starting accessibility to increase from 0.33 10<sup>-10</sup> m² s<sup>-1</sup> and 0.75 g/100 g db to 12.60 10<sup>-10</sup> m² s<sup>-1</sup> and 11.53 g/100 g db, respectively. Drying time needed to reach 5% db became 60 min instead of 528 min for untreated raw material.</p>


2021 ◽  
Vol 932 ◽  
Author(s):  
L.C. Auton ◽  
S. Pramanik ◽  
M.P. Dalwadi ◽  
C.W. MacMinn ◽  
I.M. Griffiths

A major challenge in flow through porous media is to better understand the link between microstructure and macroscale flow and transport. For idealised microstructures, the mathematical framework of homogenisation theory can be used for this purpose. Here, we consider a two-dimensional microstructure comprising an array of obstacles of smooth but arbitrary shape, the size and spacing of which can vary along the length of the porous medium. We use homogenisation via the method of multiple scales to systematically upscale a novel problem involving cells of varying area to obtain effective continuum equations for macroscale flow and transport. The equations are characterised by the local porosity, a local anisotropic flow permeability, an effective local anisotropic solute diffusivity and an effective local adsorption rate. These macroscale properties depend non-trivially on the two degrees of microstructural geometric freedom in our problem: obstacle size and obstacle spacing. We exploit this dependence to construct and compare scenarios where the same porosity profile results from different combinations of obstacle size and spacing. We focus on a simple example geometry comprising circular obstacles on a rectangular lattice, for which we numerically determine the macroscale permeability and effective diffusivity. We investigate scenarios where the porosity is spatially uniform but the permeability and diffusivity are not. Our results may be useful in the design of filters or for studying the impact of deformation on transport in soft porous media.


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