scholarly journals Bifunctional CO oxidation over Mn-mullite anchored Pt sub-nanoclustersviaatomic layer deposition

2018 ◽  
Vol 9 (9) ◽  
pp. 2469-2473 ◽  
Author(s):  
Xiao Liu ◽  
Yuanting Tang ◽  
Meiqing Shen ◽  
Wei Li ◽  
Shengqi Chu ◽  
...  

Highly dispersed Pt sub-nanoclusters are anchored on SmMn2O5mullitesviaatomic layer deposition, and show excellent low-temperature CO oxidation activity.

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Xiao Liu ◽  
Shuangfeng Jia ◽  
Ming Yang ◽  
Yuanting Tang ◽  
Yanwei Wen ◽  
...  

AbstractImproving the low-temperature activity (below 100 °C) and noble-metal efficiency of automotive exhaust catalysts has been a continuous effort to eliminate cold-start emissions, yet great challenges remain. Here we report a strategy to activate the low-temperature performance of Pt catalysts on Cu-modified CeO2 supports based on redox-coupled atomic layer deposition. The interfacial reducibility and structure of composite catalysts have been precisely tuned by oxide doping and accurate control of Pt size. Cu-modified CeO2-supported Pt sub-nanoclusters demonstrate a remarkable performance with an onset of CO oxidation reactivity below room temperature, which is one order of magnitude more active than atomically-dispersed Pt catalysts. The Cu-O-Ce site with activated lattice oxygen anchors deposited Pt sub-nanoclusters, leading to a moderate CO adsorption strength at the interface that facilitates the low-temperature CO oxidation performance.


2015 ◽  
Vol 345 ◽  
pp. 319-328 ◽  
Author(s):  
V. Johánek ◽  
M. Václavů ◽  
I. Matolínová ◽  
I. Khalakhan ◽  
S. Haviar ◽  
...  

2015 ◽  
Vol 33 (4) ◽  
pp. 041512 ◽  
Author(s):  
Morteza Aghaee ◽  
Philipp S. Maydannik ◽  
Petri Johansson ◽  
Jurkka Kuusipalo ◽  
Mariadriana Creatore ◽  
...  

2012 ◽  
Vol 24 (19) ◽  
pp. 3732-3737 ◽  
Author(s):  
Mariona Coll ◽  
Jaume Gazquez ◽  
Anna Palau ◽  
Maria Varela ◽  
Xavier Obradors ◽  
...  

2011 ◽  
Vol 519 (22) ◽  
pp. 7723-7726 ◽  
Author(s):  
J. Shen ◽  
C.Y. Zhang ◽  
T.T. Xu ◽  
A.N. Jiang ◽  
Z.Y. Zhang ◽  
...  

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