scholarly journals Redox and photocatalytic properties of a NiII complex with a macrocyclic biquinazoline (Mabiq) ligand

2018 ◽  
Vol 9 (13) ◽  
pp. 3313-3317 ◽  
Author(s):  
Michael Grübel ◽  
Irene Bosque ◽  
Philipp J. Altmann ◽  
Thorsten Bach ◽  
Corinna R. Hess

Upon irradiation with visible light, the NiII complex 1 is converted to the reduced form 2 in the presence of NEt3. The Ni-based photosensitizer catalyzes the cyclization of a bromoalkyl-substituted indole.

2014 ◽  
Vol 4 (2) ◽  
pp. 125-134 ◽  
Author(s):  
Chockalingam Karunakaran ◽  
Selvaraj Kalaivani ◽  
Pazhamalai Vinayagamoorthy

RSC Advances ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 4935-4941
Author(s):  
Riza Ariyani Nur Khasanah ◽  
Hui-Ching Lin ◽  
Hsiang-Yun Ho ◽  
Yen-Ping Peng ◽  
Tsong-Shin Lim ◽  
...  

Cu2O/TNA/Ti photoanode showed spectral response outperformed Cu2O/Ti and Cu2O/FTO photocathodes. Cu2O/TNA/Ti showed better spectral response than that of TNA/Ti, ascribed to UV-visible light absorption of Cu2O, not to charge separation enhancement.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Aadil Ahmad Bhat ◽  
Shakeel Ahmad Khandy ◽  
Ishtihadah Islam ◽  
Radha Tomar

AbstractThe present manuscript aims at the synthesis of cesium based halide perovskite nanostructures and the effect of cobalt doping on the structural, optical, lumnisent, charge storage and photocatalytic properties. In a very first attempt, we report the solvothermal synthesis of Co doped CsPbCl3 nanostructures under subcritical conditions. The structural features were demonstrated by X-ray diffraction (XRD) Surface morphology determined cubic shape of the synthesized particles. Doping is an excellent way to modify the properties of host material in particular to the electronic structure or optical properties. Incorporation of Co2+ ions in the perovskite structure tunes the optical properties of the nanostructures making this perovskite a visible light active material (Eg = 1.6 eV). This modification in the optical behaviour is the result of size effect, the crystallite size of the doped nanostructures increases with cobalt doping concentration. Photolumniscance (PL) study indicated that CsPbCl3 exhibited Blue emission. Thermogravametric analysis (TGA) revealed that the nanostructures are quite stable at elavated temperatures. The electrochemical performance depicts the pseudocapacative nature of the synthesized nanostructures and can used for charge storage devices. The charge storage capability showed direct proportionality with cobalt ion concentration. And Finally the photocatalytic performance of synthesized material shows superior catalytic ability degrading 90% of methylene blue (MB) dye in 180 min under visible light conditions.


2016 ◽  
Vol 40 (12) ◽  
pp. 10219-10226 ◽  
Author(s):  
Sheng-Ping Guo ◽  
Yang Chi ◽  
Jian-Ping Zou ◽  
Huai-Guo Xue

Novel crystalline α-EuZrS3 shows Eu2+ photoluminescence and is photocatalytically active towards the decomposition of methylene blue under visible light or simulated sunlight irradiation.


2013 ◽  
Vol 1 (3) ◽  
pp. 823-829 ◽  
Author(s):  
Zhuoxuan Li ◽  
Yang Shen ◽  
Cheng Yang ◽  
Yuechuan Lei ◽  
Yuhan Guan ◽  
...  

2015 ◽  
Vol 43 ◽  
pp. 59-62 ◽  
Author(s):  
Junfeng Chao ◽  
Degong Duan ◽  
Shumin Xing ◽  
Yuliang Zhao ◽  
Xiutai Zhang ◽  
...  

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