scholarly journals Engineering the porosity and acidity of H-Beta zeolite by dealumination for the production of 2-ethylanthraquinone via 2-(4′-ethylbenzoyl)benzoic acid dehydration

RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 9731-9740 ◽  
Author(s):  
J. X. Liu ◽  
N. He ◽  
C. Y. Liu ◽  
G. R. Wang ◽  
Q. Xin ◽  
...  

Mild HNO3 treated nano-sized H-Beta zeolite showed outstanding catalytic activity, selectivity and reusability, compared with a commercial oleum catalyst.

RSC Advances ◽  
2017 ◽  
Vol 7 (16) ◽  
pp. 9551-9561 ◽  
Author(s):  
An Li ◽  
Chen Huang ◽  
Cai-Wu Luo ◽  
Wen-Jun Yi ◽  
Zi-Sheng Chao

Quinoline was synthesized via the typical Skraup approach with a vapor-phase process. The mesoporous Ni/beta zeolite catalyst exhibited high-efficiency catalytic activity and an enhanced ability of anti-deactivation.


2019 ◽  
Vol 278 ◽  
pp. 1-13 ◽  
Author(s):  
M. Rutkowska ◽  
M. Duda ◽  
D. Macina ◽  
S. Górecka ◽  
R. Dębek ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Su-Un Lee ◽  
You-Jin Lee ◽  
Soo-Jin Kwon ◽  
Jeong-Rang Kim ◽  
Soon-Yong Jeong

With the growing global propylene demand, propane dehydrogenation (PDH) has attracted great attention for on-purpose propylene production. However, its industrial application is limited because catalysts suffer from rapid deactivation due to coke deposition and metal catalyst sintering. To enhance metal catalyst dispersion and coke resistance, Pt-based catalysts have been widely investigated with various porous supports. In particular, zeolite can benefit from large surface area and acid sites, which favors high metal dispersion and promoting catalytic activity. In this work, we investigated the PDH catalytic properties of Beta zeolites as a support for Pt-Sn based catalysts. In comparison with Pt-Sn supported over θ-Al2O3 and amorphous silica (Q6), Beta zeolite-supported Pt-Sn catalysts exhibited a different reaction trend, achieving the best propylene selectivity after a proper period of reaction time. The different PDH catalytic behavior over Beta zeolite-supported Pt-Sn catalysts has been attributed to their physicochemical properties and reaction mechanism. Although Pt-Sn catalyst supported over Beta zeolite with low acidity showed low Pt dispersion, it formed a relatively lower amount of coke on PDH reaction and maintained a high surface area and active Pt surfaces, resulting in enhanced stability for PDH reaction. This work can provide a better understanding of zeolite-supported Pt-Sn catalysts to improve PDH catalytic activity with high selectivity and low coke formation.


2011 ◽  
Vol 81 (9) ◽  
pp. 1839-1844 ◽  
Author(s):  
L. Shteinberg ◽  
V. V. Marshalova ◽  
V. M. Dibrova ◽  
S. M. Shein

2006 ◽  
Vol 2006 (12) ◽  
pp. 2422-2436 ◽  
Author(s):  
Paolo Pelagatti ◽  
Alessia Bacchi ◽  
Marcella Balordi ◽  
Sandra Bolaño ◽  
Francesca Calbiani ◽  
...  

2011 ◽  
Vol 40 (7) ◽  
pp. 1535 ◽  
Author(s):  
D. V. Aleksanyan ◽  
V. A. Kozlov ◽  
Y. V. Nelyubina ◽  
K. A. Lyssenko ◽  
L. N. Puntus ◽  
...  

2006 ◽  
Vol 9 (8) ◽  
pp. 836-838 ◽  
Author(s):  
Anirban Karmakar ◽  
Kaustavmoni Deka ◽  
Rupam J. Sarma ◽  
Jubaraj B. Baruah

2018 ◽  
Vol 304 ◽  
pp. 89-96 ◽  
Author(s):  
J.M. Escola ◽  
D.P. Serrano ◽  
R. Sanz ◽  
R.A. Garcia ◽  
A. Peral ◽  
...  

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