Octahedral RuII Complexes with [PNO] Hydrazonic Ligands: Synthesis, Structure, Reactivity and Catalytic Activity in the Addition of Benzoic Acid to Alkynes

2006 ◽  
Vol 2006 (12) ◽  
pp. 2422-2436 ◽  
Author(s):  
Paolo Pelagatti ◽  
Alessia Bacchi ◽  
Marcella Balordi ◽  
Sandra Bolaño ◽  
Francesca Calbiani ◽  
...  
2011 ◽  
Vol 81 (9) ◽  
pp. 1839-1844 ◽  
Author(s):  
L. Shteinberg ◽  
V. V. Marshalova ◽  
V. M. Dibrova ◽  
S. M. Shein

2011 ◽  
Vol 40 (7) ◽  
pp. 1535 ◽  
Author(s):  
D. V. Aleksanyan ◽  
V. A. Kozlov ◽  
Y. V. Nelyubina ◽  
K. A. Lyssenko ◽  
L. N. Puntus ◽  
...  

2006 ◽  
Vol 9 (8) ◽  
pp. 836-838 ◽  
Author(s):  
Anirban Karmakar ◽  
Kaustavmoni Deka ◽  
Rupam J. Sarma ◽  
Jubaraj B. Baruah

2012 ◽  
Vol 383 ◽  
pp. 105-111 ◽  
Author(s):  
Dimitrios Tzimopoulos ◽  
Stefano Brenna ◽  
Agnieszka Czapik ◽  
Maria Gdaniec ◽  
Attilio Ardizzoia ◽  
...  

1994 ◽  
Vol 59 (9) ◽  
pp. 2095-2102
Author(s):  
Pavol Hrnčiar ◽  
Peter Černák ◽  
Vladimír Gajda ◽  
Štefan Toma

Selectivity of complexation of substituted phenyl benzoates is very low. In most cases, comparable yields of both regioisomeric complexes are isolated. Exception is 4-chlorophenyl ester, where benzoic acid moiety is complexed nearly exclusively. Very high regioselectivity of complexation was observed with substituted phenyl phenylacetates. The substituent of substituted phenols has not any effect on the complexation, and only phenylacetic acid moiety is complexed. This observation supports the recently proposed mechanism of the catalytic activity of the esters at arene complexation.


2017 ◽  
Vol 21 (01) ◽  
pp. 37-47 ◽  
Author(s):  
Artur Vashurin ◽  
Vladimir Maizlish ◽  
Ilya Kuzmin ◽  
Serafima Znoyko ◽  
Anastasiya Morozova ◽  
...  

Difunctional and symmetric phthalonitriles were synthesized by nucleophilic substitution of brome and nitro-group in 4-bromo-5-nitro-phthalonitrile for residues 4-amino-, 4-hydroxyl- and 4-sulfanyl benzoic acid. Symmetrical and difunctional substituted cobalt phthalocyanines were obtained by template synthesis based on mentioned phthalonitriles. Their spectral properties and catalytic activity in aerobic oxidation of sodium [Formula: see text],[Formula: see text]-carbomoditiolate were investigated.


RSC Advances ◽  
2018 ◽  
Vol 8 (18) ◽  
pp. 9731-9740 ◽  
Author(s):  
J. X. Liu ◽  
N. He ◽  
C. Y. Liu ◽  
G. R. Wang ◽  
Q. Xin ◽  
...  

Mild HNO3 treated nano-sized H-Beta zeolite showed outstanding catalytic activity, selectivity and reusability, compared with a commercial oleum catalyst.


Author(s):  
J. C. Wheatley ◽  
J. M. Cowley

Rare-earth phosphates are of particular interest because of their catalytic properties associated with the hydrolysis of many aromatic chlorides in the petroleum industry. Lanthanum phosphates (LaPO4) which have been doped with small amounts of copper have shown increased catalytic activity (1). However the physical and chemical characteristics of the samples leading to good catalytic activity are not known.Many catalysts are amorphous and thus do not easily lend themselves to methods of investigation which would include electron microscopy. However, the LaPO4, crystals are quite suitable samples for high resolution techniques.The samples used were obtained from William L. Kehl of Gulf Research and Development Company. The electron microscopy was carried out on a JEOL JEM-100B which had been modified for high resolution microscopy (2). Standard high resolution techniques were employed. Three different sample types were observed: 669A-1-5-7 (poor catalyst), H-L-2 (good catalyst) and 27-011 (good catalyst).


Author(s):  
W. E. Lee

An optical waveguide consists of a several-micron wide channel with a slightly different index of refraction than the host substrate; light can be trapped in the channel by total internal reflection.Optical waveguides can be formed from single-crystal LiNbO3 using the proton exhange technique. In this technique, polished specimens are masked with polycrystal1ine chromium in such a way as to leave 3-13 μm wide channels. These are held in benzoic acid at 249°C for 5 minutes allowing protons to exchange for lithium ions within the channels causing an increase in the refractive index of the channel and creating the waveguide. Unfortunately, optical measurements often reveal a loss in waveguiding ability up to several weeks after exchange.


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