scholarly journals Catalytic reactivity of an iridium complex with a proton responsive N-donor ligand in CO2 hydrogenation to formate

RSC Advances ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 1346-1350 ◽  
Author(s):  
Gunniya Hariyanandam Gunasekar ◽  
Yeahsel Yoon ◽  
Il-hyun Baek ◽  
Sungho Yoon
Keyword(s):  
Structural Instability ◽  
Co2 Hydrogenation ◽  
Catalytic Cycle ◽  
Iridium Complex ◽  
Donor Ligand ◽  
Excellent Activity ◽  
Catalytic Reactivity ◽  
Half Sandwich

A bibenzimidazole ligated half-sandwich Ir complex [Cp*Ir(BiBzImH2)Cl]Cl shows superior activity than that of its bipyridine counterpart. Owing to the structural instability, the initial excellent activity of [Cp*Ir(BiBzImH2)Cl]Cl was reduced when catalytic cycle proceeds.

Dual Catalytic Cycle of H2 and H2O Oxidations by a Half-Sandwich Iridium Complex: A Theoretical Study

2019 ◽  
Vol 58 (11) ◽  
pp. 7274-7284 ◽  
Author(s):  
Kei Ikeda ◽  
Yuta Hori ◽  
Muhammad Haris Mahyuddin ◽  
Yoshihito Shiota ◽  
Aleksandar Staykov ◽  
...  
Keyword(s):  
Theoretical Study ◽  
Catalytic Cycle ◽  
Iridium Complex ◽  
Half Sandwich

scholarly journals Metallkomplexe mit biologisch wichtigen Liganden, LXXII [1]. Halbsandwichkomplexe von Iridium(III) und Ruthenium(II) mit Dianionen von 2-Hydroxyiminocarbonsäuren / Metal Complexes of Biologically Important Ligands, LXXII [1]. Half Sandwich Iridium(III) and Ruthenium(II) Complexes with Dianions of 2-Hydroxyiminocarboxylic Acids

1994 ◽  
Vol 49 (4) ◽  
pp. 483-488 ◽  
Author(s):  
Ralph Bergs ◽  
Rostislav Lampeka ◽  
Christian Robl ◽  
Wolfgang Beck
Keyword(s):  
Metal Complexes ◽  
X Ray Diffraction ◽  
Chelate Complexes ◽  
Donor Ligand ◽  
X Ray ◽  
Half Sandwich

Chiral chelate complexes with dianions of 2-hydroxyiminocarboxylic acids (1) und (2) are obtained by deprotonation of the compounds and in the presence of a donor ligand (Do=PR3, P(OMe)3, py). The structure of has been determined by X-ray diffraction.

Oxygen Atom Transfer to a Half-Sandwich Iridium Complex: Clean Oxidation Yielding a Molecular Product

2014 ◽  
Vol 136 (10) ◽  
pp. 3981-3994 ◽  
Author(s):  
Christopher R. Turlington ◽  
Peter S. White ◽  
Maurice Brookhart ◽  
Joseph L. Templeton
Keyword(s):  
Oxygen Atom ◽  
Iridium Complex ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Molecular Product ◽  
Half Sandwich

Sequential Nitrene Transfers to an Organometallic Half-Sandwich Iridium Complex

2015 ◽  
Vol 34 (20) ◽  
pp. 4810-4812 ◽  
Author(s):  
Christopher R. Turlington ◽  
Peter S. White ◽  
Maurice Brookhart ◽  
Joseph L. Templeton
Keyword(s):  
Iridium Complex ◽  
Half Sandwich

Chemoselective and efficient catalytic hydrogenation of furfural by iridium and ruthenium half-sandwich complexes

2020 ◽  
Vol 44 (22) ◽  
pp. 9382-9390 ◽  
Author(s):  
Novisi K. Oklu ◽  
Banothile C. E. Makhubela
Keyword(s):  
Catalytic Hydrogenation ◽  
Furfuryl Alcohol ◽  
Hydrogen Gas ◽  
Iridium Complex ◽  
Selective Synthesis ◽  
Sandwich Complexes ◽  
Half Sandwich

A recyclable homogeneous iridium complex for the selective synthesis of furfuryl alcohol from furfural without additional solvent and hydrogen gas.

Theoretical Investigation of a Parallel Catalytic Cycle in CO2 Hydrogenation by (PNP)IrH3

2015 ◽  
Vol 34 (20) ◽  
pp. 4932-4940 ◽  
Author(s):  
Irina Osadchuk ◽  
Toomas Tamm ◽  
Mårten S. G. Ahlquist
Keyword(s):  
Theoretical Investigation ◽  
Co2 Hydrogenation ◽  
Catalytic Cycle

Synthesis, Structure, and Reversible Deprotonation of a Half-sandwich Iridium Complex Bearing a Chelating Oxime Ligand

2010 ◽  
Vol 39 (7) ◽  
pp. 758-759 ◽  
Author(s):  
Megumi Watanabe ◽  
Yohei Kashiwame ◽  
Shigeki Kuwata ◽  
Takao Ikariya
Keyword(s):  
Iridium Complex ◽  
Half Sandwich ◽  
Oxime Ligand
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