scholarly journals Thermally induced bilayered crystals in a solution-processed polycrystalline thin film of phenylterthiophene-based monoalkyl smectic liquid crystals and their effect on FET mobility

RSC Advances ◽  
2017 ◽  
Vol 7 (89) ◽  
pp. 56586-56593 ◽  
Author(s):  
Hao Wu ◽  
Hiroaki Iino ◽  
Jun-ichi Hanna

Herein, a series of asymmetric monoalkyl terthiophene derivatives, Ph-(Tp)3-Cn, (6 ≤ n ≤ 18), were synthesized to study the phase transition from monolayered crystal to bilayered crystal, leading to a significant increase of OFET mobility.

RSC Advances ◽  
2019 ◽  
Vol 9 (38) ◽  
pp. 21685-21694 ◽  
Author(s):  
Palash Dhara ◽  
Rabibrata Mukherjee

Thermally induced nematic to isotropic (N–I) phase transition and dewetting of 5CB liquid crystal thin films on flat and topographically patterned substrates.


2013 ◽  
Vol 25 (23) ◽  
pp. 3209-3214 ◽  
Author(s):  
Kwang-Ho Lee ◽  
Sang-Mook Kim ◽  
Huisu Jeong ◽  
Yusin Pak ◽  
Hui Song ◽  
...  

Entropy ◽  
2020 ◽  
Vol 22 (11) ◽  
pp. 1232
Author(s):  
V. Thanh Ngo ◽  
Phuong-Thuy Nguyen ◽  
Hung T. Diep

We study the nature of the smectic–isotropic phase transition using a mobile 6-state Potts model. Each Potts state represents a molecular orientation. We show that with the choice of an appropriate microscopic Hamiltonian describing the interaction between individual molecules modeled by a mobile 6-state Potts spins, we observe the smectic phase dynamically formed when we cool the molecules from the isotropic phase to low temperatures (T). In order to elucidate the order of the transition and the low-T properties, we use the high-performance Wang–Landau flat energy-histogram technique. We show that the smectic phase goes to the liquid (isotropic) phase by melting/evaporating layer by layer starting from the film surface with increasing T. At a higher T, the whole remaining layers become orientationally disordered. The melting of each layer is characterized by a peak of the specific heat. Such a succession of partial transitions cannot be seen by the Metropolis algorithm. The successive layer meltings/evaporations at low T are found to have a first-order character by examining the energy histogram. These results are in agreement with experiments performed on some smectic liquid crystals.


2000 ◽  
Vol 62 (6) ◽  
pp. R7599-R7602 ◽  
Author(s):  
Seiji Shibahara ◽  
Jun Yamamoto ◽  
Yoichi Takanishi ◽  
Ken Ishikawa ◽  
Hideo Takezoe

2018 ◽  
Vol 2 (10) ◽  
pp. 1800066 ◽  
Author(s):  
Seung-Won Oh ◽  
Sang-Hyeok Kim ◽  
Tae-Hoon Yoon

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