scholarly journals Investigation of micro- and nanoscale barrier layer capacitance mechanisms of conductivity in CaCu3Ti4O12via scanning probe microscopy technique

RSC Advances ◽  
2017 ◽  
Vol 7 (65) ◽  
pp. 40695-40704 ◽  
Author(s):  
M. S. Ivanov ◽  
F. Amaral ◽  
V. A. Khomchenko ◽  
J. A. Paixão ◽  
L. C. Costa

In this work we disclose micro- and nanoscale origins of the unusually high dielectric constant characteristic of CaCu3Ti4O12 (CCTO) ceramic by using the Scanning Probe Microscopy (SPM) technique.

2018 ◽  
Vol 8 (03) ◽  
pp. 932-937 ◽  
Author(s):  
M.S. Ivanov ◽  
F. Amaral ◽  
V.A. Khomchenko ◽  
L.C. Costa ◽  
J.A. Paixão

Abstract


2019 ◽  
Vol 31 (11) ◽  
pp. 114001 ◽  
Author(s):  
Mahfujur Rahaman ◽  
Christian Wagner ◽  
Ashutosh Mukherjee ◽  
Adan Lopez-Rivera ◽  
Sibylle Gemming ◽  
...  

1989 ◽  
Vol 155 ◽  
Author(s):  
Makoto Kuwabara

ABSTRACTA preliminary experiment was conducted to prepare semiconducting strontium titanate-based internal barrier layer capacitors with ferroelectric Pb(Fe, W)O3 forming insulating layers along the grain boundaries. Processing, microstructure and the dielectric properties of this new type of BL capacitors are described. The idea to obtain this type of BL capacitors with a very high dielectric constant may be realized when the ferroelectric materials can uniformly be diffused along the grain boundaries by using a more sophisticated processing of the second firing.


2012 ◽  
Vol 620 ◽  
pp. 230-235 ◽  
Author(s):  
Muhammad Azwadi Sulaiman ◽  
Sabar Derita Hutagalung ◽  
Zainal Arifin Ahmad ◽  
Mohd Fadzil Ain

CaCu3Ti4O12(CCTO) is a cubical perovskite phase and sintered ceramics exhibit very high dielectric constant at room temperature. The speculated origins of the high dielectric constant are the existence of insulative barrier layer at grain boundaries and domain boundaries which created an internal barrier layer capacitance (IBLC) at the microstructure of CCTO. The relation of grains and domains electrical resistance were studied in this work by using impedance spectroscopy (IS). A series of samples with different heat treatment temperature were tested to investigate their microstructure by using field emission scanning electron microscopy (FESEM). The grains and domains resistance was calculated from a wide frequency range of impedance complex plane measurement (100 Hz to 1 GHz). The FESEM and IS analyses showed the dependency of grains and domains resistance to average grains size of CCTO microstructure.


2020 ◽  
Vol 8 (32) ◽  
pp. 16661-16668
Author(s):  
Huayao Tu ◽  
Shouzhi Wang ◽  
Hehe Jiang ◽  
Zhenyan Liang ◽  
Dong Shi ◽  
...  

The carbon fiber/metal oxide/metal oxynitride layer sandwich structure is constructed in the electrode to form a mini-plate capacitor. High dielectric constant metal oxides act as dielectric to increase their capacitance.


Sign in / Sign up

Export Citation Format

Share Document