scholarly journals Cobalt(ii)/nickel(ii) separation from sulfate media by solvent extraction with an undiluted quaternary phosphonium ionic liquid

RSC Advances ◽  
2017 ◽  
Vol 7 (57) ◽  
pp. 35992-35999 ◽  
Author(s):  
Bieke Onghena ◽  
Stijn Valgaeren ◽  
Tom Vander Hoogerstraete ◽  
Koen Binnemans

Co(ii) is separated from Ni(ii) in sulfate media by extraction with the ionic liquid Cyphos IL 101 in its chloride and thiocyanate form.

2015 ◽  
Vol 60 (4) ◽  
pp. 2933-2938 ◽  
Author(s):  
B. Pospiech

This paper presents study on the facilitated transport of cadmium(II), cobalt(II) and nickel(II) ions from aqueous chloride solutions through polymer inclusion membranes (PIMs) with phosphonium ionic liquid. Cyphos IL 101 (trihexyl(tetradecyl) phosphonium chloride) was used as a selective carrier for synthesis of cellulose triacetate membranes containing o-nitrophenyl pentyl ether (ONPPE) as a plasticizer. Effect of different parameters such as hydrochloric acid concentration in the source phase as well as ion carrier concentration in the polymer membrane on metal ions transport has been investigated. Cd(II) was transported preferably from hydrochloric acid solutions containing Co(II) and Ni(II) through PIM containing 18.8 wt.% CTA and 26.0 wt.% Cyphos 101 and 55.1 wt.% ONPPE into 0.5 M HNO3 as the receiving phase. The obtained results suggest that there is a possibility of application of this membrane with Cyphos IL 101 as ion carrier for separation of Cd(II) over Co(II) and Ni(II) from hydrochloric acid solutions.


RSC Advances ◽  
2016 ◽  
Vol 6 (67) ◽  
pp. 62717-62728 ◽  
Author(s):  
Viet Tu Nguyen ◽  
Jae-chun Lee ◽  
Alexandre Chagnes ◽  
Min-seuk Kim ◽  
Jinki Jeong ◽  
...  

An effective solvent extraction-based method has been developed to recover individually platinum group metals (Pd, Pt, and Rh) with high purity from acidic chloride media using phosphonium-based ionic liquid Cyphos IL 101 in aromatic solvent.


RSC Advances ◽  
2020 ◽  
Vol 10 (41) ◽  
pp. 24595-24612 ◽  
Author(s):  
Clio Deferm ◽  
Bieke Onghena ◽  
Viet Tu Nguyen ◽  
Dipanjan Banerjee ◽  
Jan Fransaer ◽  
...  

Speciation studies give insight into the mechanism of non-aqueous solvent extraction of indium from ethylene glycol solution by the ionic liquid Cyphos IL 101.


Author(s):  
Yassine Bencherifi ◽  
Badre Larhrib ◽  
Adnan Sayegh ◽  
Georgios Nikiforidis ◽  
Mérièm Anouti

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